| Project/Area Number |
04453083
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
工業物理化学・複合材料
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| Research Institution | Waseda University. |
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Principal Investigator |
KIKUCHI Eiichi Waseda Univ., Applied Chemistry, Professor, 理工学部, 教授 (90063734)
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| Co-Investigator(Kenkyū-buntansha) |
YOGO Katsunori Waseda Univ., Applied Chemistry, Research Associate., 理工学部, 助手 (40257217)
MATSUDA Takeshi Waseda Univ., Applied Chemistry, Assistant Professor., 理工学部, 助教授 (10199804)
上宮 成之 成蹊大学, 工学部, 助手 (60221800)
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| Project Period (FY) |
1992 – 1993
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| Project Status |
Completed (Fiscal Year 1993)
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| Budget Amount *help |
¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 1993: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1992: ¥6,300,000 (Direct Cost: ¥6,300,000)
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| Keywords | Nitric oxide / Nitrogen dioxide / Selective reduction / Zeolite / Gallium / Iudium / Methane / Reaction mechanism / 炭化水素 / エタン / プロパン |
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| Research Abstract |
Selective reduction of No by CH_4 on zeolite catalysts has been studied. After investigation on the catalytic features of various cation-exchaged zeolites, we found that Ga-ZSM-5 and In-ZSM-5 were highly active and selective for NO reduction by CH_4. We also showed that this reaction was moderately promoted even by H-form ZSM-5, mordenite, and ferrierite. From the catalytic performance of Ga-and In-ZSM-5in NO-CH_4-O_2, NO_2-CH_4-O_2, and NO-O_2 reactions, it is conuluded that the selective reduction of NO on these catalysts proceeds in two stages : (1) NO is oxidized to NO_2 on zeolite acid sites, (2) NO_2 and CH_4 react on gallium or indium sites. The highly selective features of Ga and In in zeolite for NO_2-CH_4 reaction seem to be attributed to the coordinatively unsaturated nature of these sites which adsorb both of these reactants on the same site. Effect of water vapor on NO conversion was also investigated. It was found that Ga-ZSM-5 was strongly inhibited by steam, while In-ZSM-5 was fairly active even in the presence of 10% steam.
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