| Project/Area Number |
04453150
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | University of Tokyo |
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Principal Investigator |
SHIBASAKI Masakatsu University of Tokyo, Faculty of Pharmaceutical Sciences, Professor, 薬学部, 教授 (30112767)
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| Co-Investigator(Kenkyū-buntansha) |
SODEOKA Mikiko University of Tokyo, Faculty of Pharmaceutical Sciences, Research Associat, 薬学部, 助手 (60192142)
SASAI Hiroaki University of Tokyo, Faculty of Pharmaceutical Sciences, Lecturer, 薬学部, 講師 (90205831)
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| Project Period (FY) |
1992 – 1993
|
| Project Status |
Completed (Fiscal Year 1993)
|
| Budget Amount *help |
¥7,200,000 (Direct Cost: ¥7,200,000)
Fiscal Year 1993: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1992: ¥3,700,000 (Direct Cost: ¥3,700,000)
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| Keywords | Rare Earth Metal / Optically Active Complex / Catalytic Asymmetric Synthesis / Nitroaldol / beta-Blocker / ピンドロール / 光学活性希土類錯体 / 不斉ニトロアルドール反応 / 塩基性触媒 |
|---|
| Research Abstract |
The structure of the optically active rare earth metal complex 1 has been unequivocally determined. The use of 1 has made possible a catalytic asymmetric synthesis of pindolol.
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