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A new fringe method for characterization of ROUGHNESS of inner layrs in semiconductor crystals and dielectric thin layrs

Research Project

Project/Area Number 04555006
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Applied materials
Research InstitutionDepartment of Physics, Gakushuin University

Principal Investigator

OGAWA Tomoya  Gakushuin Univ., Dept.of Phys., Professor, 理学部, 教授 (50080437)

Co-Investigator(Kenkyū-buntansha) MA Minya  Gakushuin Univ., Dept.of Phys., Guest Researcher, 理学部, 客員研究員 (60255263)
NARAOKA Kiyoiki  Gakushuin Univ., Dept.of Phys., Guest Researcher, 理学部, 客員研究員
OYAMA Yasunao  Gakushuin Univ., Dept.of Phys., Assistant, 理学部, 助手 (20265573)
南郷 脩史  ラトック, システム・エンジニャリング, 社長
坂井 一文  学習院大学, 理学部, 助手 (40205703)
Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥17,900,000 (Direct Cost: ¥17,900,000)
Fiscal Year 1994: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 1993: ¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 1992: ¥8,300,000 (Direct Cost: ¥8,300,000)
KeywordsSi wafer / SIMOX / denuded zone / Cz-Si / intrinsic gettering / GaAs wafer / multi-quantum layr / diffraction of light / Interference Fringes / Diffraction / Surface Roughness / Integrated Circuits / Liquid Crystal Display / Device Technology / 干渉縞 / 超薄膜干渉縞 / 固体表面状態 / SIMOX / 半導体レーザー / チタン・サファイャー・レーザ
Research Abstract

A new fringe method was developed for characterization of "roughness" of inner layrs and interfaces in semiconductor devices because the roughness are very important for semiconductor technologies. Here, brightness and clearness, or visibility, of the fringe pattern are determined by scattering from the objects to be surveyed, because size and density of dots and spots which compose the fringes are proportional to size and density of particles and grains located at the interfaces or roughness on the layrs while their scattered intensities are dependent upon refractive index difference between matrix and the objects.
(1) A SIMOX wafer is prepared by proper heat treatments from a silicon wafer showered by heavy but homogeneous implantation of oxygen ions, and thus a thin and flat oxide layr is generated in the wafer. The layr is made of fine oxide particles which efficiently act as light scatterers. The fringe patterns obtained by SIMOX wafers are usually bright and clear with fine dots w … More hich inform us the layr is a homogeneous assemble of fine oxide particles.
(2) when denuded zone and oxide particles for intrinsic gettering (IG) are generated in a CZ-Si wafer after application of proper heat treatments to the wafer, an interface between the zone and the IG region is clearly observed by this fringe method. Oxide particles located near the interface are quantitatively measured, which is very important for planar circuits on the wafer.
(3) Optical quality of multi-layrs with quantum well structure was comprehensively checked by this fringe method because this fringe pattern will be observed only when any optical inhomogeneity is present in the layrs grown on substrate.
(4) Since etch pits and steps on crystal faces indicate crystallographic anisotropy, the light intensities scattered by the pits and steps are dependent upon the direction of incident light against their crystallographic orientations, which has been clearly observed by some GaAs wafers.
To measure "roughness" of inner layrs or interfaces which are unable to measure before this fringe method, a new method has been developed here, which is, of course, governed by an electronic system. Less

Report

(4 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (43 results)

All Other

All Publications (43 results)

  • [Publications] 小川智哉: "Piled up dislocations in vapour phase grown ZnSe crystals" Philosophical Magazine. (in press). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Defects in β-BaB203 (BBO) crystals observed by laser scanning tomography" J. Crystal Growth. 141. 393-398 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Effect of human blood addition on dendritic growth of cupric chloride crystals in aqueous solutions" J. Crystal Growth. 142. 147-155 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Characterization of GdBa2Cu307 superconducting thin films by a new optical interference fringe method" J. Materials Science. 29. 3702-3704 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Crystal perfection and detection of defects just under wafer surfaces of semiconducting and insulating materials" Institute of Physics, Conference Series. 135. 127-130 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Characterization of interface and surface structures by ultra-thin film interference fringes" Institute of Physics, Conference Series. 135. 267-270 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Materials and Process Characterization for VLSI '94" Asia-Pacific Microanalysis Association, 583 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ma & Ogawa: ""Piled-up dislocation in a vapor phase grown ZnSe crystals observed by light scattering tomography"" Phil.Mag. in press. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa: ""Detection of defects near a wafer surface by Brewster angle illumination"" Materials and Process Characterization for VLSI,1994 ed. by X.F.Zong, M.K.Balaz & J.J.Wang, Asia-Pacific Microanalysis Associaton, Shanghai, China. 34-38 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Shibata & Ogawa: "Effect of human blood addition on dendritic growth of cupric chloride crystals in aqueous solutions" J.Crystal Growth. 142. 147-155 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Mai & Ogawa: "Characterization of GdBa2Cu307 superconducting thin films by a new optical interference fringe method" J.Materials Science. 29. 3702-3704 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Tan & Ogawa: "Defects in beta-BBO(beta barium borate) crystals observed by laser scanningtomography" J.Crystal Growth. 141. 393-398 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Nango & Ogawa: "Crystal perfection and detection of defects just under wafer surfaces of semiconducting and insulating materials" Inst.Phys.Conf.Ser. No. 135. 127-130 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Lu & Ogawa: "Characterization of interface and surface structures by ultra-thin film interference fringes" Inst.Phys.Conf.Ser. No.135. 267-270 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Lu & Ogawa: "Effect of surface structure upon ultra-thin interference fringes" J.Materials Research. 8. 2315-2318 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa: "Characterization of dielectric crystals by light scattering tomography" Ferroelectronics. 142. 19-29 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa: "Light scattering tomography to evaluate and characterize crystals" From Galileo's OCCHIALINO to Optoelectronics ed.by P.Mazzoldi, World Science, Singapore. 578-585 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ataka & Ogawa: "Nucleation and growth of oxide precopitates in CZ-Si wafers" J.Materials Research. 8. 2889-2892 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ogawa: "Optical characterization of silicon wafers for ULSI" Materials Sci. & Eng. B 20. 172-174 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Sakai & Ogawa: "A study on IR light intensities scattered from defects in an In-doped LEC CaAs crystalsas functions of wava-length andintensity of bias light superposed on the defects" Jpn.J.Appl.Phys. 31. 2945-2948 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Sakai, Kondo & Ogawa: "Raman scattering tomography studies on semi-conductors" Semicond.Sci. Technol. 7. A279-A282 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 小川智哉: "Piled up dislocations in vapour phase grown ZnSe crystals" Philosophical Magazine. (in press). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Defects in β-BaB203(BB0)crystals observed by laser scanning tomography" J.Crystal Growth. 141. 393-398 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Effect of human blood addition on dendritic growth of cupric chloride crystals in aqueous solutions" J.Crystal Growth. 142. 147-155 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Characterization of GdBa2Cu307 superconducting thin films by a new optical interference fringe method" J.Materials Science. 29. 3702-3704 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Crystal perfection and detection of defects just under wafer surfaces of semiconducting and insulating materials" Institute of Physice,Conference Series. 135. 127-130 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Characterization of interface and sumface structures by ultra-thin film interference fringes" Institute of Physics,Conference Series. 135. 267-270 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Materials and Process Characterization for VLSI′94" Asia-Pacific Microanalysis Association, 583 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小川智哉: "Effect of surface structures upon ulta-thin interference fringes" J.Materials Reearch. 8. 2315-2318 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小川智哉: "Characterization of dielectric crystals by light scattering tomography" Ferroelectronics. 142. 19-29 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小川智哉: "Nucleation and growth oxide precopitates in CZ-Si wafers" J.Materials Research. 8. 2889-2892 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小川智哉: "A phenomenological study on crystal growth from aqueous solution" Progress in Crystal Growth and Characterization of Materials. 25. 51-101 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小川智哉: "Optical characterization of silicon wafers for ULSI" Materials Science & Engineering B. 25. 172-174 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小川智哉: "Charaterization of extremely thin epitaxial layers and films by new interference fringes" J.Materials Research. 7. 2182-2185 (1992)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小川智哉 編著: "朝倉書店" 結晶評価技術ハンドブック. 1092 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Lu Taijin et al and T.OGAWA: "Characterization of extremely thin epitaxial layers and films by new interference fringes" Journal of Materials Research. 7. 2182-2185 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] K.Sakai et al and T.OGAWA: "IR light intensities scattered from defects in an In-doped LEC GaAs crystals as functions of wavelength and intensity of bias light superposed on the defects" Japanese J.Applied Physics. 31. 2945-2948 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 陸太 進・他 小川 智哉: "超薄膜干渉縞およびそれによる半導体薄膜の評価" レーザー科学. 14. 70-73 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.OGAWA et al: "Optical characterization of Si wafers" Materials Science and Engineering. 14. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Li Lian et al and T.OGAWA: "In situ observation of subcritical crystalline particles and their behavior on growthg of KDP crystals from aqueous solution by light scattering technique" Journal of Materials Research. 12. 3275-3279 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.OGAWA: "A phenomenological study on crystal growth from aqueous solutions" Progress in Crystal Growth and Characterization of Materials. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 小川 智哉 編集主任分担執筆: "結晶評価技術ハンドブック" 朝倉書店, (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] 小川 智哉 分担執筆: "結晶成長ハンドブック" 共立出版社, (1993)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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