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Development of Low Temperature Deposition Process of Silicon Oxide Film by Low Frequency Plasma CVD (TEOS+O_2)

Research Project

Project/Area Number 04555018
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 応用物理学一般(含航海学)
Research InstitutionHokkaido University

Principal Investigator

DATE Hiroyuki (1993)  College of Medical Technology, Hokkaido University, Instructor, 医療技術短期大学部, 助手 (10197600)

下妻 光夫 (1992)  北海道大学, 医療技術短期大学部, 助教授 (70041960)

Co-Investigator(Kenkyū-buntansha) SHIMOZUMA Mitsuo  College of Medical Technology, Hokkaido University, Assistant Professor *April 1, 医療技術短期大学部, 助教授 (70041960)
OHNO Hideo  Faculty of Engineering, Hokkaido University, Assistant Professor, 工学部, 助教授 (00152215)
TAGASHIRA Hiroaki  Faculty of Engineering, Hokkaido University, Professor, 工学部, 教授 (10001174)
伊達 広行  北海道大学, 医療技術短期大学部, 助手 (10197600)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1993: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1992: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsPlasma (CVD) / Silicon oxide film / Low frequency plasma / TEOS / Thin film deposition / Low temperature process / Integrated circuit process / Unequilibrium plasma / 50HzプラズマCVD法 / TEOS+O_2 / ドライプロセス / 層間絶縁膜 / 表面保護膜
Research Abstract

Silicon oxide films have been used in the fabrication of integrated circuits as the insulation layr of metal-oxide-semiconductor structures or as a passivation layr. In the beginning, silicon oxide films used in integrated circuits were prepared by thermal oxidation of silicon substrates or thermal chemical vapor deposition (CVD). Recently, many kinds of methods to prepare the films, such as low pressure CVD, plasma oxidation, sputtering, and plasma CVD have been developed. Among these methods, plasma CVD can deposit high quality silicon oxide films at comparatively low substrate temperatures. Moreover, silicon oxide films with good step coverage are deposited by plasma CVD using TEOS (Tetraethoxysilane). In this work, the silicon oxide films was deposited using TEOS as a silicon source by using a low frequency (50Hz) plasma CVD.It is found in the present work that the substrate heating at deposition is required to obtain acceptable electrical properties when silicon oxide films are deposited from a TEOS and oxygen mixture, even by low frequency (50Hz) plasma CVD.The films deposited at 200。C from the plasma of a 3% TEOS mixture were found to be high quality insulating films ; the resistivity was 10^<16>OMEGA cm and the breakdown strength 7X10^6 V/cm. Moreover, Auger electron spectrum analysis revealed that carbon atoms were not detected from the films in spite of the presence of carbon atoms in the TEOS molecule. With optical emission spectrum analysis of the TEOS and oxygen mixture plasma, strong emissions from the CO and CO_2 molecules were observed.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] M.Ishikawa: "Deposition of silicon oxide film on polymer using 50Hz plasma CVD" Proc.of 10th Symp.on Plasma Processing. XVI-3. 467-470 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] G.Tochitani: "Deposition of silicon oxide films from TEOS by low frequency plasma chemical deposition" J.Vac.Technol.A. Vol.11. 400-405 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Shimozuma: "DEPOSITION OF SILICON OXIDE FILM ON POLYMER WITHOUT HEATING USING 50Hz PLASMA CVD" Proc.of 11th International Symp.on Plasma Chem.Vol.3. 829-833 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Shimozuma: "DIAGNOSTICS OF N_2O AND Ar MIXTURE 50Hz PLASMA" Proc.of 21th International Conference on Phenomena in Ionized Gases. Vol.III. 474-477 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Hashizume: "Annealing Behavior of HF-Treated GaAs Capped with SiO_2 Films Prepared by 50Hz Plasma-Assisted CVD" Jpn.J.Appl.Phys.Vol.31. 3794-3800 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] G.Tochitani: "Properties of hidrogenated amorphous silicon films prepared by low-frequency(50Hz) plasma-enhanced chemical-vapor deposition" J.Applied Physics. Vol.72. 234-238 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Ishikawa, G.Tochitani, M.Shimozuma and H.Tagashira: "Deposition of silicon oxide film on polymer using 50Hz plasma CVD" Proc.of 10th Symp.on Plasma Processing. Vol.XVI-3. 467-470 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] G.Tochitani, M.Shimozuma and H.Tagashira: "Deposition of silicon oxide films from TEOS by low frequency plasma chemical deposition" J.Vac.Sic.Technol.A. Vol.11. 400-405 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Shimozuma, M.Ishikawa and H.Tagashira: "DEPOSITION OF SILICON OXIDE FILM ON POLYMER WITHOUT HEATING USING 50Hz PLASMA CVD" Proc.of 11th Intern. Symp.on Plasma Chemistry. Vol.3. 829-833 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Shimozuma, H.Fujikawa and H.Tagashira: "DIAGNOSTICS OF N2 and Ar MIXTURE" Proc.of 21th Intern. Conference on Phenomena in Ionized Gases. Vol.III. 474-477 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Hashizume, H.Hasegawa, G.Tochitani and M.Shimozuma: "Annealing Behavior of HF-Treated GasAs Capped with SiO2 Films Prepared by 50Hz Plasma-Assisted Chemical Vapor Deposition" Jpn.J.Appl.Phys.Vol.31. 3794-3800 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] G.Tochitani, M.Shimozuma and H.Tagashira: "Properties of hydrogenated amorphous silicon films prepared by low-frequency (50Hz) plasma-enhanced chemical-vapor deposition" J.Applied Physics. Vol.72. 234-238 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] M.Ishikawa,G.Tochitani,M.Shimozuma & H.Tagashira: "Deposition of silicon oxide film on polymer using 50Hz plasma CVD" Proc.of 10th Symp.On Plasma Processing. XVI-3. 467-470 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] G.Tochitani,M.Shimozuma & H.Tagashira: "Deposition of silicon oxide films from TEOS by low frequency plasma chemical deposition" J.Vac.Sic.Technol.A. Vol.11. 400-405 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Shimozuma,H.Fujikawa & H.Tagashira: "DIAGNOSTICS OF N_2O AND Ar MIXTURE 50Hz PLASMA" Proc.of 21th International Conference on Phenomena in Ionized Gases. Vol.III. 474-477 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Shimozuma,M.Ishikawa & H.Tagashira: "DEPOSITION OF SILICON OXIDE FILM ON POLYMER WITHOUT HEATING USING 50Hz PLASMA CVD" Proc.of 11th International Symp.on Plasma Chemistry. Vol.3. 829-833 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 中島、下妻、田頭: "プローブ法によるDCグロー放電プラズマの電子エネルギー測定" 電気学会放電研究会資料. ED-93-199 HV-93-107. 9-17 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Hashizume,H.Hasegawa,G.Tochitani & M.Shimozuma: "Annealing Behavior of HF-Treated GaAs Capped with SiO_2 Films Prepared by 50-Hz Plasma-Assisted Chemical Vapor Deposition" Jpn.J.Appl.Phys.Vol.31. 3794-3800 (1992)

    • Related Report
      1993 Annual Research Report
  • [Publications] G.Tochitani: "Deposition of silicon oxide films from TEOS by low frequency plasma chemical vapor deposition" J.Vac.Sci.Technol.A,. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Ishikawa: "DEPOSITION OF SILICON OXIDE FILMS ON POLYMER USING %)HZ PLASMA CVD" Proc.of the 10th symposium on plasma processing. Vol.10. 467-470 (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] T.Hashizume: "Annealing Behavior of HF-Treated GaAs Capped with SiO_2 Films Prepared by 50Hz Plasma Assisted Chemical Vapor Deposition" Jpn.J.Appl.Phys.Vol.31. 3794-3800 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Shimozuma: "Deposition of Silicon Oxide Film on Polymer Substrate Using 50Hz Olasma CVD Method" Annual Reports if The College of Medical Technology,Hokkaido University. No.5. 27-33 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] G.Tochitani: "Properties of hydrogenated amorphous silicon films prepared by low-frequency(50Hz)plasma-enhanced chemical-vapor deposition" J.Applied Physics. Vol.72. 234-238 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Shimozuma: "Optical emission diagnostics of H_2+CH_4 50Hz-13.56MHz plasmas for chemical vapor deposition" J.Applied Physics. Vol.70. 645-648 (1991)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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