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STUDY ON DEVELOPMENT OF ATOMIC LAYER CONTROLLED CVD APPARATUS FOR FABRICATION PROCESS OF EXTREMELY LARGE SCALE INTEGRATED CIRCUITS

Research Project

Project/Area Number 04555064
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 電子材料工学
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

MUROTA Junnichi  TOHOKU UNIVERSITY,RESEARCH INSTITUTE OF ELECTRICAL COMMUNICATION,PROFESSOR, 電気通信研究所, 教授 (70182144)

Co-Investigator(Kenkyū-buntansha) SATO Taketoshi  KOKUSAI ELECTRIC Co.Ltd., TOYAMA FACTORY,TOYAMA PROCESS TECHNOLOGY CENTER,RESEAR, 富山工場・富山プロセス技術センター, 研究員
NAKAMURA Naoto  KOKUSAI ELECTRIC Co.Ltd., TOYAMA FACTORY,TOYAMA PROCESS TECHNOLOGY CENTER,RESEAR, 富山工場・富山プロセス技術センター, 研究員
KUROKAWA Harushige  KOKUSAI ELECTRIC Co.Ltd., TOYAMA FACTORY,FACTORY SUPERINTENDENT, 富山工場, 工場長取締役
MATSUURA Takashi  TOHOKU UNIVERSITY,RESEARCH INSTITUTE OF ELECTRICAL COMMUNICATION,ASSOCIATE PROFE, 電気通信研究所, 助教授 (60181690)
ONO Shoichi  TOHOKU UNIVERSITY,EMERITUS PROFESSOR, 電気通信研究所, 名誉教授 (00005232)
Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥16,700,000 (Direct Cost: ¥16,700,000)
Fiscal Year 1994: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1993: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1992: ¥11,000,000 (Direct Cost: ¥11,000,000)
KeywordsAtomic Layr Epitaxy / Chemical Vapor Deposition / Flash Heating / SiH_4 / GeH_4 / Si / Resonant Tunneling / シリコン / ゲルマニウム / ヘテロ構造 / 集積回路 / エピタキシャル成長
Research Abstract

Purpose of this study is to develop and to estabish novel CVD apparatus as an atomic layr epitaxy technology widely applied to Si extremely large scale integrated circuits. In this CVD,simple hydride gases, i.e.SiH_4 and GeH_4, are used as a reactant gas. In higher partial pressure range of the reactant gases (around a few Pa or a few hundreds Pa), adsorbed layr of the gases are formed, and then flash heating by the flash light shot results in the reaction of adsorbed molecules and single atomic layr epitaxy of Si and Ge. So far, we have developed flash heating CVD apparatus and have been realized the separation between adsorption and reaction of reactant gases. In this year, as the last year of the term, we have realized atomic layr growth of Si and Ge and an atomic layr superlattice structure of Si_1Ge_1. Finally, we have fabricated a double barrier resonant tunneling diode, and current peaks due to resonant tunneling effect were clearly observed in the current-voltage characteristic … More .
Concretely itemizing,
(1) concerning to control the crystal structure of the initial surface for atomic layr epitaxy, a dimer structure on Si (100) was clearly observed after exposing the surface to the air,
(2) single atomic layr epitaxy of Ge on Si surface was realized by using flash heating CVD at 275゚C,
(3) single atomic layr epitaxy of Si on Ge surface was realized by self-limiting thermal reaction of SiH_4 at 200-300゚C,
(4) we have fabricated resonant tunneling diode with single Ge quantum well sandwiched by double Si_1 Ge_1 superlattice barriers, which were formed by alternately depositing the single atomic layrs of Si and Ge as stated in (2) and (3). All the process during/after growth of the double barrier structure were done below 300゚C.Negative resistance characteristic, in which clear current peaks appeared at the bias voltages of -0.6 V and 0.7 V approximately assigned to the predicted value, was observed.
The success of this project supplies a key to atomic layr controlled process applied to device fabrication and we summarized this project. Less

Report

(4 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (33 results)

All Other

All Publications (33 results)

  • [Publications] M.Sakuraba: "Stability of the Dimer Structure Formed on Si(100) by Ultraclean Low-Pressure Chemical Vapor Deposition" Journal of Applied Physics. 75. 3701-3703 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] J.Murota: "Low-Temperature Epitaxial Groth of Si/Si_<1-x>Ge_x/Si Hetero structure by Chemical Vapor Deposition" Japanese Joarnal of Applied Physics. 33. 2290-2299 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba: "Atomic-Layer Epitaxy Control of Ge and Si in Flash-Heating CVD using GeH_4 and SiH_4 Gases" The 3rd International Symposium on Atomic Layer Epitaxy and Related Surface Process (ALE-3). 204-205 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba: "Initial Growth Stages of Si on Ge and Ge on Si for Atomic-Layer Epitaxy Control Using GeH4 and SiH4Gases" Extended Abstracts of the 1994 International Conference on Solid State Devices and Materials. 757-759 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba: "Atomic-Layer Epitaxy Control of Ge and Si in Flash-Heating CVD Using GeH_4 and SiH_4 Gases" Applied Surface Science. 82-83. 354-358 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] J.Murota: "Atomic-Layer-by-Layer Epitaxy of Silicon and Germanium Using Flash Heating in CVD" Journal de Physigae N. (発表予定). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba, J.Murota and S.Ono: ""Stability of the Dimer Structure Formed on Si(100) by Ultraclean Low-Pressure Chemical Vapor Deposition"" Journal of Applied Physics. Vol.75, No.7. 3701-3703 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] J.Murota and S.Ono: ""Low-Temperature Epitaxial Growth of Si/Si_<1-x>Ge_x/Si Heterostructure by Chemical Vapor Deposition"" Japanese Journal of Applied Physics. Vol.33, Prt1, No.4B. 2290-2299 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba, J.Murota, T.Watanabe, Y.Sawada and S.Ono: ""Atomic-Layr Epitaxy Control of Ge and Si in Flash-Heating CVD Using GeH_4 and SiH_4 Gases"" The 3rd Int.Symp.on Atomic Layr Epitaxy and Related Surface Processes (ALE-3). 204-205 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba, J.Murota, T.Watanabe and Y.Sawada: ""Initial Growth Stages of Si on Ge and Ge on Si for Atomic-Layr Epitaxy Control Using SiH_4 and GeH_4 Gases"" Ext.Abstr.Int.Conf.on Solid State Devices and Materials. 757-759 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba, J.Murota, T.Watanabe, Y.Sawada and S.Ono: ""Atomic-Layr Epitaxy Control of Ge and Si in Flash-Heating CVD Using GeH_4 and SiH_4 Gases"" Applied Surface Science. Vol.82/83. 354-358 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] J.Murota, M.Sakuraba, T.Watanabe and Y.Sawada: ""Atomic Layr-by-Layr Epitaxy of Silicon and Germanium Using Flash Heating in CVD"" Journal de Physigue. IV (to be published). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Sakuraba: "Stability of the Dimer Structure Formed on Si(100) by Ultraclean Low-Pressure Chemical Vapor Deposition" Journal of Applied Physics. 75. 3701-3703 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] J.Murota: "Low-Temperature Epitaxial Growth of Si/Si_<1-x>Gex/Si Heterostructure by Chemical Vapor Deposition" Japanese Journal of Applied Physics.33. 2290-2299 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Sakuraba: "Atomic-Layer Epitaxy Control of Ge and Si in Flash-Heating CVD Using GeH_4 and SiH_4 Gases" The 3rd International Symposium on Atomic Layer Epitaxy and Related Surface Processes(ALE-3). 204-205 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Sakuraba: "Initial Growth Stages of Si on Ge and Ge on Si for Atomic-Layer Epitaxy Control Using GeH_4 and SiH_4 Guses" Extended Abstracts of the 1994 International Conference on Solid State Devices and Materials. 757-759 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Sakuraba: "Atomic-Layer Epitaxy Control of Ge and Si in Flash-Heating CVD Using GeH_4 and SiH_4 Gases" Applied Surface Science. 82-83. 354-358 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] J.Murota: "Atomic Layer-by-Layer Epitaxy of Silicon and Germanium Using Flash Heating in CVD" Journal of de Physique IV. (発表予定). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Junichi Murota: "Silicon atomic layer growth controlled by flash heating in chemical vapor deposition using SiH_4 gas" Applied Physics Letters. 62. 2353-2355 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masao Sakuraba: "Atomic layer growth of Si in flash heating CVD using SiH_4 gas" Proceedings of the 12th International Conference on Chemical Vapor Deposition. 93-2. 110-116 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masao Sakuraba: "Silicon atomic layer growth using flash Heating in CVD" Journal de Physique IV. 3. C3-449-C3-456 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Junichi Murota: "Low-temperature epitaxial growth of Si/Si_<1-X>Ge_X/Si heterostructure by CVD(Invited)" Extended Abstracts of the 1993 International Conference on Solid State Devices and Materials. 240-242 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masao Sakuraba: "Stability of the Si(100) surface epitaxially grown by CVD" Extended Abstracts of the 1993 International Conference on Solid State Devices and Materials. 273-275 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 櫻庭政夫: "Si(100)表面ダイマー構造の大気中での安定性" 電子情報通信学会技術報告. ED93-105. 1-6 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Junichi Murota: "Ultraclean low-pressure CVD for Si/Si_<1-X>Ge_X/Si heterostructure growth(Invited)" Proceedings of the International Conference on Advanced Microelectronic Devices and Processing. 221-228 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masao Sakuraba: "Stability of the dimer structure on the Si film epitaxially grown on Si(100) by ultraclean low-pressure chemical vapor deposition" Proceedings of the International Conference on Advanced Microelectronic Devices and Processing. 445-448 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Junichi Murota: "Low-temperature epitaxial growth of Si/Si_<1-X>Ge_X/Si heterostructure by chemical vapor deposition" Japanese Journal of Applied Physics. 33(発表予定). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masao Sakuraba: "Stability of the dimer structure formed on Si(100) surface by ultraclean low-pressure chemical vapor deposition" Journal of Applied Physics. (発表予定). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 室田 淳一: "フラッシュランプ光照射によるSi-Ge系の原子層成長制御" 1992年電気化学協会秋季大会講演要旨集シンポジゥム「IV族半導体の原子層制御成長技術」. 232- (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 室田 淳一: "CVDシリコンエピタキシー技術" 応用物理学会結晶工学分科会第19回講習会テキスト. 71-85 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Masao Sakuraba: "Atomic layer growth of Si in flash heating CVD using SiH_4 gas" Proceedings of 12th International Conference on Chemical Vapor Deposition. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Masao Sakuraba: "Silicon atomic layer growth using flash heating in CVD" EURO CVD. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Junichi Murota: "Low-temperature epitaxial growth of Si/SiGe/Si heterostructure by CVD(Invited)" Extended Abstracts of the 1993 International Conferenee on Solid State Devices and Materials. (1993)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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