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Establishment of "in situ" Measurement Method for mass and Viscoelasticity Changes at Interfaces between Electrode and Solution

Research Project

Project/Area Number 04555194
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

OYAMA Noboru  Tokyo Univ.of Agri.and Tech., Faculty of Technolgy, Professor, 工学部, 教授 (40134845)

Co-Investigator(Kenkyū-buntansha) FUJIMOTO Eiji  Technical Center, Technical Manager, 取締役技師長
直井 勝彦  東京農工大学, 工学部, 講師 (70192664)
Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥17,100,000 (Direct Cost: ¥17,100,000)
Fiscal Year 1993: ¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1992: ¥12,100,000 (Direct Cost: ¥12,100,000)
KeywordsQuarts Crystal / Microbalance / Mass Change / Viscoelasticity / Impedance-Frequency / Network Analyzer / Oscillating / Mass Transfer
Research Abstract

Analytical techniques using the quartz crystal electrodes are most suitable for examining the electrode reaction dynamics. The techniques can be divided into active method and passive method. In the active method, which is known as quartz crystal microbalance(QCM) technique, a quartz crystal itself is made to oscillate spontaneously and an oscillation frequency is counted using a frequency counter. On the other hand, in the passive method, which we call quartz crystal impedance(QCI) method herein, ac voltage is applied to a quartz crystal and an impedance-frequency spectrum is obtained. In this research, the in situ measurement systems of the both methods have been established. From the piezoelectric admittance measurements, it was found that the electrical equivalent circuit parameters(i.e., resistance R, inductance L and capacitance C components) on electrode surfaces can be evaluated and mean the mass, viscoelasticity and/or mechanical stress changes of thin films on electrodes during the redox reactions. The measurement method of the equivalent circuit parameters and the series resonant frequency of the electrode-separated piezoelectric quartz crystal was also established. It was demonstrated that this device can be a powerful tool for detecting changes in liquid properties.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (34 results)

All Other

All Publications (34 results)

  • [Publications] K.Takada,T.Tatsuma and N.Oyama: "Impedance and Frequency Characteristics of Electrode-Separated Piezoelectric Quartz Crystals in Liquids." J.Electroanal.Chem.(印刷中). (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Oyama,S.Ikeda,O.Hatozaki,M.Shimomura,K.Mishima,and S.Nakamura: "“In-situ" Quartz Crystal Microbalance Responses and Electrochemistry Regarding Langmuir-Blodgett Film of Viologen Polyion Complex on the Electrode Surface." Bull.Chem.Soc.Jpn.66. 1091-1097 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Okajima,H.Sakurai,N.Oyama,K.Tokuda and Takeo Ohsaka: "Electrical Equivalent Circuit Parameters for Montmorillonite Clay Film-Coated Quartz Crystal Oscillators in Contact with Air,Moisture and Electrolyte Solutions." Electrochimica Acta. 38. 747-756 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Tatsuma,S.Kikuyama,and N.Oyama: "Electrochemical Microgravimetry of C_<60> Films." J.Phy.Chem.97. 12067-12072 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] N.Oyama,T.Tatsuma,and K.Takahashi: "Electrochemical Characterization of a Thermoresponsive N-Isopropylacrylamide-Vinylferrocene Copolymer Film by the Use of Quartz Crystal Oscillators." J.Phy.Chem.97. 10504-10508 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] S.Ikeda and N.Oyama: "Investigation of Electrochemical Behavior and Mass-Transfer Process of Ferrocene-Siloxane Polymer Film Using Quartz Crystal Electrode Method." Anal.Chem.65. 1910-1915 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Shuichiro Yamaguchi, Takeshi Shimomura, Tetsu Tatsuma and Noboru Oyama: "Adsorption, Immobilization, and Hybridization of DNA Studied by the Use of Quartz Crystal Oscillators" Anal.Chem.65(14). 1925-1927 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Shin Ikeda and Noboru Oyama: "Investigation of Electrochemical Behavior and Mass-Transfer Process of Ferrocene-Siloxane Polymer Film Using Quartz Crystal Electrode Method" Anal.Chem.65(14). 1910-1915 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Noboru Oyama, Tetsu Tatsuma, and Katsuhiko Takahashi: "Electrochemical Characterization of a Thermoresponsive N-Isopropylacrylamide-Vinylferrocene Copolymer Film by the Use of Quartz Crystal Oscillators" J.Phy.Chem.97(40). 10504-10508 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tetsu Tatsuma, Susumu Kikuyama, and Noboru Oyama: "Electrochemical Microgravimetry of C_<60> Films" J.Phy.Chem.97(46). 12067-12072 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Takeyoshi Okajima, Hidetaka Sakurai, Noboru Oyama: "Piezoelectric Admittance Measurements of Montmorillonite/Poly-(vinyl alcohol) Composite Film-Coated Quartz Crystal Oscillators" Bull.Chem.Soc.Jpn.65(7). 1884-1890 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Takeyoshi Okajima, Hidetaka Sakurai, Noboru Oyama, Koichi Tokuda and Takeo Ohsaka: "Electrical Equivalent Circuit Parameters for Montmorillonite Clay Film-Coated Quartz Crystal Oscillators in Contact with Air, Moisture and Electrolyte Solutions" Electrochimica Acta. 38(6). 747-756 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Noboru Oyama, Kazutake Takada, Tetsu Tatsuma and Katsuhiko Naoi: "Piezoelectric Admittance-Based Sensing of Electrolyte Solutions by Montmorillonite Clay Film-Coated Quartz-Crystal Oscillators" Sensors and Actuators B. 13-14. 372-375 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Noboru Oyama, Shin Ikeda, Osamu Hatozaki, Masatsugu Shimomura, Kumi Mishima, and Sadako Nakamura: ""In-situ" Quartz Crystal Microbalance Responses and Electrochemistry Regarding Langmuir-Blodgett Film of Viologen Polyion Complex on the Electrode Surface" Bull.Chem.Soc.Jpn.66(4). 1091-1097 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Takeyoshi Okajima, Hidetaka Sakurai, Noboru Oyama, Koichi Tokuda and Takeo Ohsaka: "In situ Electrochemical Quartz Crystal Microbalance Studies on Ion and Solvent Transport Accompanying Redox Reactions of Fe(CN)_6^<3-/4-> Complex Confined Electrostatically in Poly(N, N-Dimethylaniline) Polyelectrolyte Films" Denki Kagaku. 60(12). 1082-1090 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Katsuhiko Naoi, Yujiro Nagatomi and Noboru Oyama: "QCM Analysis on Electropolymerization of Electroactive Polyaniline Film from Non-Aqueous Media" Denki Kagaku. 60(12). 1091-1096 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Hiroshi Inaba, Masahiro Iwaku, Tetsu Tatsuma and Noboru Oyama: "In Situ Quartz Cryst Analysis of Mass Transport Processes at a WO_3 Thin Film during Redox Reaction" Denki Kagaku. 61(7). 783-785 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Nobushige Yamamoto, Hiroshi Hirasawa, Hidenobu Ishida, Tetsu Tatsuma and Noboru Oyama: "Electrochemical Deposition and Dissolution Processes of Lithium Compound on Gold from Propylene Carbonate" Bull.Chem.Soc.Jpn.(in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Yasuo Ninomiya, Shohei Oda and Noboru Oyama: "Flow Injection Type Electrogravimetric Analysis System Incorporated with Quartz Crystal Microbalance Method" Bunseki Kagaku. 42. T93-T97 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kazutaka Takada, Tetsu Tatsuma and Noboru Oyama: "Impedance and Frequency Characteristics of Electrode-Separated Piezoelectric Quartz Crystals in Liquids" (in press). (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 高田 主岳: "Impedance and Frequency characteristics of Electrode-Separated Piezoelectric Quartz Crystal in Liquids" Journal of Electroanalytical Chemistry. (印刷中). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小山 昇: "Electrochemical Characterization of a Thermoresponsive N-Isopropylacrylamide-Vinylferrocene Copolymer Film by the Use of Quartz Crystal Oscillators" The Journal of Physical Chemistry. 97. 10504-10508 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 立間 徹: "Electrochemical Microgravimetry of C_<60> Films" The Journal of Physical Chemistry. 97. 12067-12072 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 池田 信: "Investigation of Electrochemical Behavior and Mass-Transfer Process of Ferrocene-Siloxane Polymer Film Using Quartz Crystal Electrode Method" Analytical Chemistry. 65. 1910-1915 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 山口 秀一郎: "Adsorption,Immobilization,and Hybridization of DNA Studied by the Use of Quartz Crystal Oscillators" Analytical Chemistry. 65. 1925-1927 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小山 昇: "Piezoelectric Admi Hance-Based Sensing of Electrolyte Solutions by Montmorillonite clay Film-Coated Quartz Crystal Oscillators" Sensors and Actuators B. 13-14. 372-375 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Shin IKEDA: "Investigation of Electrochemical Behavior and Mass Transfer Process of Ferrocene-Siloxane Polymer Film Using Quartz Crystal Electrode Method" Anal.Chem.(1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Kimiya TAKESHITA: "Electrochemical Quartz Crystal Microbalance Investigations of Poly(pyrrole)/Sulfated Poly(Beta-Hydroxyethers)Composites" J.Electrochem.Soc.(1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Takeyoshi OKAJIMA: "Piezoelectric Admittance Measurements of Montmorillonite/Poly-(vinylalcohol)Composite Film-Coated Quartz Crystal Oscillators" Bull.Chem.Soc.Jpn.65(7). 1884-1990 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Takeyoshi OKAJIMA: "In Situ Electrochemical Quartz Crystal Microbalance Studies on lon and Solvent Transport Accompanying Redox Reactions of Fe(CN)_6^<3-/4-> Complex Confined Electrostatically in Poly(N,N-Dimethylaniline) Polyelectrolyte Films" Denki Kagaku. 60(12). 1082-1090 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Katsuhiko NAOI: "QCM Analysis on Electropolymerization of Electroactive Polyamiline Film from Non-Aqueous Media" 60(12). 1091-1096 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Takeyoshi OKAJIMA: "Electrical Equivalent Circuit Paramters for Montmorillonite Clay Film-Coated Quartz Crystal Oscillators in Contact with Air,Moesture and Electrolyte Solutions" Electrochim.Acta. (1993)

    • Related Report
      1992 Annual Research Report
  • [Publications] Noboru OYAMA: "Molecular Desihn of Electrode Surfaces" John Wiley, 70 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 小山 昇: "ニューマテリアルハンドブック" 昭晃堂, 15 (1993)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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