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Impurity Effect and Size Effect on Itinerant-Electron Ferromagnets

Research Project

Project/Area Number 04640353
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionTokyo Denki University

Principal Investigator

OGAWA Shinji  Tokyo Denki Univ., Dept. of Engin., Professor, 工学部, 教授 (90160754)

Project Period (FY) 1992 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1994: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1993: ¥500,000 (Direct Cost: ¥500,000)
KeywordsItinerant-electron ferromagnetism / Itinerant-electron metamagnetism / Magnetic impurity effect / Zirconium-zinc ferromagnetic compound / Yttrium-nickel ferromagnetic alloy / Cobalt disulphide-diselenide / 遍歴電子強磁性 / パイライト型コバルト化合物 / 磁気熱膨張 / 強磁性体の不純物効果 / イットリウム・ニッケル合金
Research Abstract

Effect of doping gadlinium atoms into weak itinerant-electron ferromagnets or substituting a part of constituent metal atoms for different transition-metal atoms in weak itinerant-electron ferromagnets have been studied experimentally for ZrZn_2, YNi_3, Y_2Ni_7 ferromagnets. Effect of substituting anions in CoS_2 ferromagnet on its magnetic property has also been examined. Measuremnts have been made of magnetization curves in a very strong magnetic field. The temperature variation of magnetization in the Gd-doped weak itinerant-electron ferromagnets can be explained by taking into consideration of the induced magnetic moment in itinerant-electrons due to localized spins, on the basis of the mean field approximation. However, the magnetic field dependence of magnetization shows an inadequacy of the mean field approximation and suggests the effect of field on spin fluctuations to suppress and also an effect of anisotropy. The substitution by transition-metal atoms appears to shift a Fermi level as a first order approximation, but some complicated band structure effet seems to dominate the variaton of magnetization. The substitution of selenium for sulphur results in a drastic change of magnetic states in the itinerant-electron ferromagnet CoS_2. It appears a change from a ferromagnet to an itinerant-electron metamagnet, and further to a paramagnet by the substitution. Especially, in the 10 % substituted sample, it has been observed a clear first order phase transiton from ferromagnetic state to a metamagnetic state and a second order phase transiton from a metamagnetic state to a paramagnetic state by increasing a temperature. This is due to a quite homogeneous state of our samples. This transiton can be qulitatively analyzed by the Landau's theory of phase transiton. A possible size effect in the very weak itinerant-electron ferromagnets has been examined experimentally, but no appreciable change has been observed.

Report

(4 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • 1992 Annual Research Report
  • Research Products

    (2 results)

All Other

All Publications (2 results)

  • [Publications] 小川 信二: "Magnetic measurement at ultra-low tempearture and in high magnetic field" Japanese Journal of Applied Physics Series. 8. 220-222 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] S.Ogawa: "Magnetic measurement at ultra-low temperature and in high magnetic field" Jpn. J.Appl. Phys. Series. vol.8. 220-222 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary

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Published: 1993-04-01   Modified: 2020-05-15  

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