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Study of Ferroelastic Substances with Commensurate / Incommensurate Twin Boundaries by means of ESR-CT and STM Adopting Apparatuses Applying Heat and Uniaxial Stress

Research Project

Project/Area Number 04640356
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 固体物性
Research InstitutionHokuriku University

Principal Investigator

KOBAYASHI Tadashi  Hokuriku University, Faculty of Pharmaceutical Science, Professor, 薬学部, 教授 (30100936)

Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1993: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1992: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsESR Imaging / STM / AFM / Ferroelasticity / Domain / Twin boundary / Commensurate-Incommensurate / C_<60> fullerene / MRI / ESRイメージング(ESR Imaging) / 強弾性体(Ferroelastic) / 双晶面(twin bowndary) / 分域(domain)
Research Abstract

1.(1) Development of the Zupancic magnetic resonance imaging coil and the electron spin resonance imaging (ESRI) apparatus adopting dielectric resonator.
(2) By using these apparatus, the observation of the ferroelasstic domain structure has been studied.
2.(1) Development of apparatuses, applying heat and uniaxial stress, for STM and AFM.
(2) By using this apparatuses, the temperature dependence of ferroelastic domain and domain boundary structure of EuP_5O_<14> and GdP_5O_<14> obtained by STM and AFM and X-ray diffraction was observed. We observed the temperature dependence of monoclinic beta angles and analyzed the width (about 0.6 mu m) and zigzag structure of ferroelastic domain boundary.
(3) According to Sapriel's ferroelastic theory which doesn't take into consideration the width of the domain boundary, LaNbO_4 should have incomennsurate (W') twin boundaries, but W' boundaries cannot be detected through our close analysis of neutron and X-ray diffractions. Therefore if the incommensurate twin boundaries are suposed to exist, they are thought to be dissolved in the domain boundary regions.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] Masahiko Suhara: "Phase Transitions and Modulated Structure of the Incommensurate Phase in Mg[H_2O]_6SiF_6 Crystal" Phase Transitions. 37. 111-119 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 小林 正: "ESRイメージングプレートによる放射線計測システムの開発" ESR応用計測. 8. 9-13 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 小林 正: "走査型トンネル顕微鏡(STM)及び原子間力顕微鏡(AFM)等走査型プローブ顕微鏡(SPM)の今後の発展の動向" ESR応用計測. 9. 5-12 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 小林 正: "ESR及びESRイメージングを用いて生体物質の研究" 月刊アイオニクス. 20(2). 9-14 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Kobayashi: "Observation of the Ferroelastic Domain Structure of MP_5O_<14>(M:La-Tb)by means of Scanning Tunneling Microscope,Electron Spin Resonance and X-ray-Diffraction" Jpn.J.Appl.Phys.Part2,Letters. 33No5A. (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Iwao Takei: "AFM Observation of the Ferroelastic Domain Boundary of GdP_5O_<14>" J.Phys.Soc.Jpn.(Submitted).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 小林正(第2部、第3部、第4部の一部を分担): "「走査型トンネル顕微鏡/原子間力顕微鏡利用技術集成」・上弾性体の分域構造のSTM観察(第2部)・STM、AFMメーカーの総論(第3部)・STM、AFMの周辺機器の開発と走査型プローグ顕微鏡の今後の発展動向(第4部)" 出版者:(株)ティー・アイ・シー 編者:ナノ表面研究会(石川県工業試験場), 400 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Masahiko Suhara: "Phase Transitions and Modulated Structure of the Incommensurate Phase in Mg {H_2O}_6SiF_6 Crystal" Phase Transitions. Vol.37. 111-119 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Masahiko Suhara: "Temperature and Angular Dependences of EPR Line Width in {N(CH_3)_4}_2CuCl_4 Crystal" J.Phys. Chem. Solids. Vol.53(1). 27-29 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Kobayashi: "Development of Radiation Dosimetry System Adopting ESR Imaging Plates" Adv. ESR Appl., (ISSN 0914-9880). Vol.8. 9-13 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Kobayashi: "Future of Scanning Probe Microscopes (STM, AFM,-----)" Adv. ESR Appl., (ISSN 0918-6824). Vol.9. 5-12 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Kobayashi: "ESR and ESR-Imaging Studies of Biomaterials" INOICS. Vol.20(2). 9-14 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Tadashi Kobayashi: "Observation of the Ferroelastic Domain Structure of MP_5O_<14> (M : La-Tb) by means of Scanning Tunneling Microscope, Electron Sp in Resonance and X-ray Diffraction" Jpn.j.Appl. Phys. Part 2, Letters. Vol.33(5A). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Iwao Takei: "Atomic Force Microscope Observation of Ferroelastic Domain Boundary in GdP_5O_<14>" J.Phys. Soc. Jpn.(submitted).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] A Society for the Scientific Research of Nano-Surface, The Compilation oftechnologies for Application of STM / AFM. T.I.C., -400 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 小林,正: "走査型トンネル顕微鏡(STM)及び原子間力顕微鏡(AFM)等 走査型プローブ顕微鏡(SPM)の今後の発展の動向" ESR応用計測. 9. 5-12 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小林,正: "ESR及びESRイメージングを用いた生体物質の研究" アイオニクス 特集:電子スピン共鳴(ESR)生体、材料、環境研究の手法. 20. 9-14 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Tadashi Kobayashi: "Observation of the Ferroelastic Domain Structure of MP_5O_<14>(M:La-Tb)by means of STM,ESR and X-ray Diffraction" Jpn.J.Appl.Phys.(1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小林,正(第2部と第3部の一部を分担): "「走査型トンネル顕微鏡/原子間力顕微鏡利用技術集成」 ・強弾性体の分域構造のSTM観察(第2部) ・STM,AFMの周辺機器の開発と走査型プローブ顕微鏡の今後の発展動向(第3部)" 出版者:(株)ティー・アイ・シー 編者:ナノ表面研究会(石川県工業試験場), 400頁 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] M.Suhara,T.Bandoh,T,Kitai,T.Kobayashi and H.Katsuda: "Phase Transitions and Modulated Structure of the Incommensurate Phase in Mg〔H_2O〕_6SiF_6 Crystal" Phase Transitions. 37. 111-119 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] M.Suhara and T.Kobayashi: "Temperature and Angular Dependences of EPR Line Width in {N(CH_3)_4}_2Cucl_4 Crystal" J.Phys.Chem.Solids. 53(1). 27-29 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 小林 正、勝田 平俊、原 秀元: "電子スピン共鳴(ESR)の画像化:手法と応用の展開 ー高線形性高磁場勾配コイルの設計と電子スピン共鳴イメージング装置の開発ー" 平成3年度科学研究費補助金(総合(B))研究成果報告書 (研究課題番号NO.03352028 代表者 池谷元伺). 28-31 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 小林 正、勝田 平俊、竹井 巌、原 秀元、柳生 秀樹、森田 洋右、斉藤 晴夫、松永 孝之: "ESRイメージングプレートによる放射線計測システムの開発" Advances in ESR Applications. 8. 9-13 (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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