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Critical electronic phenomena in liquid alloys with miscibility gap

Research Project

Project/Area Number 04640427
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 物理化学一般
Research InstitutionHokkaido University

Principal Investigator

ITAMI Toshio  Faculty of Science, Depatment of chemistry Associate Professor, 理学部, 助教授 (40113518)

Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1993: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1992: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsLiquid metals. / Critical Phenomena / Two Liquid Separations / Spinodal / Microgravity / Electrical Resistivity / スピノーダル
Research Abstract

Behaviors of conduction electrons were investigated near the critical point of two liquid phase separation in liquid Bi-Ga alloys. The resistivity, rho, of liquid Bi-Ga alloys decreases moderately with the decrease of temperature, T,far above the ctitical temperature, T_c. However, with the approach to T_c the rho decreases abruptly particularly in the supercooling temperature range of homogeneous liquid, that is in the T range below the binodal line. This is considered to reflect the growth of concentration fluctuations up to the onset of the two phase separations. In addition it is to be noted that the T range of this supercooling is minimum at the critical composition X_c and larger around X_c. This indicates that the onset of two phase separations may be initiated by the spinodal decomposition. Based on these experimental facts the rho of liquid Bi-Ga alloys were investigsated under the microgravity, which was realized by the launch of rocket. It was found that under the micrograviuty, the decrease of rho on cooling process begins at 15K higher temperature than the the binodal temperature. This indicates that the microgravity condition is very effective to surpress the convection effects on the growth process of concentration fluctuations and provides the appropriate experimental circumstances for the study of true feature of two liquid phase separations. In addition it was found that the degree of supercooling is far larger under microgravity than under 1 g condition. This also indicates that microgravity conditions are very effective to study the supercooling or non equilibrium properties.

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] T.Itami,T.Masaki,K.Kuribayasi,M.Hinada,M.Yamasita,K.Kawasaki: "Phase separation behaviours into two liquid phases under a micrograviy of liquid Bi-Ga alloys due to the launch of rocket" The Proc.of the 10th space Utilization symposium. 10. 181-183 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami,T.Masaki,K.Kuribayasi,M.Hinada,M.Yamasita,K.Kawasaki: "Two Liquid phase separation of the Bi-Ga alloys under low gravity" The Proc.of the IUMRS-ICAN-93. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami,R.Xu,W.van der Lugt: "The resistivity of liquid potassium-gallium alloys" J.Alloys and Compounds. 201. 37-41 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami,K.Izumi,N.Iwaoka: "Electronic properties of liquid alkali-thallium alloys" J.non Cryst.Solids. 156. 285-288 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami,T.Kusakabe,Y.Yasuhara: "Electronic properties of liquid mercuy alloys" J.non Cryst.Solids. 156. 281-284 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] P.Desre,T.Itami,I.Ansara: "Statistical thermodynamic approach of the stability of liquid mixtures and its application to ternary metallic system" Z.Metallkde.84. 185-284 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Toshio Itami: "[Theory of Diffusion for Liquid Metals in the High Temperature]" Netsu Bussei. Vol.6. 105-111 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, T.Masaki, K.Kuribayashi, M.Hinada, M.Yamasita and K.Kawasaki: "[Measurements of Electrical Resistivity for liquid Bi-Ga alloys with Criticsal Mixing under Low Gravity by rocket Launch]" JASMA. Vol.9. 201-208 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, T.Masaki, K.Kuribayasi, M.Hinada, M.Yamasita and K.Kawasaki: "[Critical Fluctuation Behaviors and Separation Processes into Two Liquid Phases for Liquid Alloys with Critical Mixing under Low Gravity]" Proc. of the 9th Space Utilization Symposium. 53-56 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, K.Kusakabe, Y.Yasuhara: "[Electronic Properties of Liquid Mercury Alkali Alloys]" J.Non-Cryst. Solids. Vol.156-158. 281-283 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] P.Desre, T.Itami, I.Ansara: "A Statistical thermodynamic Approach of the Stability of Liquid Mixtures and its Application to Ternary Metallic Systems" Zeit.fur Metalkde.Vol.84. 185-191 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Toshio Itami: "[Space Circumstances and Fundamental Scientific Experiments Under Microgravity]" Civil Lectures in Hokkaido University [Circumstances and Futures]. 45-50 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, T.Masaki, K.Kuribayasi, M.Hinada, M.Yamasita and K.Kawasaki: "[Two liquid phase separation of the Bi-Ga alloys under low gravity]" Proc. of the IUMRS-ICAN-93. (in press). 4 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, T.Masaki, K.Kuribayasi, M.Hinada, M.Yamasita and K.Kawasaki: "[Phase separation behaviors into two liquid phases under a micro gravity of liquid Bi-Ga alloys due to thelaunch of rocket]" Proc.of the 10th Space Utilization Symposium. 181-183 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Toshio Itami: "[Diffusions and Two Liquid Phases Separations in Liquid Metals and Alloys]" Proc. of the Symposioum of Japan Institute of Metals[Microgravity Material Processing]. 5-8 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Toshio Itami: "[Fundamental Scientific Expeiments Under Microgravity and Their Examples]" Technical Report in Faculty of Science, Hokkaido University. No.3. 10-19 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, R.Xu and W.van der Lugt: "[The Resistivity of Liquid Potassium-Gallium Alloys]" J.Aloys and Compounds. 201. 37-41 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami, K.Izumi and N.Iwaoka: "[Electronic Properties of Alkali-Thallium alloys]" J.Non-Cryst.Solids. Vol.156-158. 285-288 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] T.Itami,T.Masaki,K.Kuribayasi,M.Hinada,M.Yamasita,K.Kawasaki: "Phase separation behaviours into two liquid phases under a micrograviy of liquid Bi-Ga alloys due to the launch of rocket" The Proc.of the 10th space utilization symposium. 10. 181-183 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Itami,T.Masaki,K.Kuribayasi,M.Hinada,M.Yamasita,K.Kawasaki: "Two liquid phase separation of the Bi-Ga alloys under low gravity" The proc.of the IUMRS-ICAN-93. (in press).

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Itami,R.Xu,W.van der Lugt: "The resistivity of liquid potassium-gallium alloys" J.Alloys and Compounds. 201. 37-41 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Itami,K.Izumi,N.Iwaoka: "Electronic properties of liquid alkali-thallium alloys" J.non Cryst.Solids. 156. 285-288 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Itami,T.Kusakabe,Y.Yasuhara: "Electronic properties of liquid alkali-thallium alloys" J.non Cryst.Solids. 156. 281-284 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] P.Desre,T.Itami,I.Ansara: "Statistical thermodynamic approach of the stability of liquid mixtures and its application to ternary metallic system" Z.Metallkde.84. 185-284 (1993)

    • Related Report
      1993 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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