Structure of aggregates of alcohols studied by near-infrared and NMR spectrscopic measurements
| Project/Area Number |
04640457
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
物理化学一般
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| Research Institution | Kitasato University |
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Principal Investigator |
IWAHASHI Makio Kitasato University, School of Hygienic Sci., Professor, 衛生学部, 教授 (70087120)
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| Project Period (FY) |
1992 – 1993
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| Project Status |
Completed (Fiscal Year 1993)
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| Budget Amount *help |
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1993: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1992: ¥1,600,000 (Direct Cost: ¥1,600,000)
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| Keywords | Hydrogen bonding / Aggregates of alcohol / NMR relaxation time / Alcohos / 1-Butanol / Near-infrared spectroscopy / Alkanes / Oleyl alcohol (cis-9-octadecen-1-ol) / 近赤外分光法 / オクタノール / 会合体形成 / 会合数 / 炭素鎖長依存性 |
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| Research Abstract |
The self-association of normal alcohols (1-butanol, 1-hexanol, and 1-octanol) and unsaturated alcohol (cis-9-octadecen-1-ol) in the pure liquid state in decane and in tetrachloride solutions has been studied by near-infrared (NIR) and NMR spectroscopic observations.
The mean degree of association obtained for the normal alcohols is approximately four regardless of the hydrocarobon-chain length and inds of the solvent.
The higher association number for the normal alcohols compared with that for fatty acids having the same nuber of carbon atoms as the alcohol most likely accounts for their higher viscosity and lower self-diffusion coefficient than those for the fatty acids. The association number for cis-9-octadecen-1-ol (oleyl alcohol) is less than that for normal alcohol. This is because of the steric hindrance of cis-type double bond included in its molecular structure.
Almost perfect NIR band assignment in the spectrum were carried out for the series of alkanes ; the absorption band at 1450 nm for alkanes was concluded to be assigned not to CH_2 but CH groups. Relaxation-time study for NMR obviusly showed that the alcohol aggregates dissociate into monomeric molecules with an increase in temperature.
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Report
(3 results)
Research Products
(13 results)
