| Project/Area Number |
04640507
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
有機化学一般
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| Research Institution | Ehime University |
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Principal Investigator |
TANAKA Koich Ehime Univ.Applied Chemistry, Associate Prof., 工学部, 助教授 (10116949)
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| Project Period (FY) |
1992 – 1993
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| Project Status |
Completed (Fiscal Year 1993)
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| Budget Amount *help |
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1993: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1992: ¥1,400,000 (Direct Cost: ¥1,400,000)
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| Keywords | Molecular Design / Inclusion Complex / Separation / Resolution / Host Compound / Host-Guest Complex / Molecular Recognition / 包接現象 / 異性体分離 / 不斉反応制御 / キラルシフト試剤 / 不斉織別 |
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| Research Abstract |
Some new host compounds (1-6) were designed and synthesized. For example, spider host compound (1) was found to include six guest molecule selectively. 1,4-Diphenyl-1,4-cyclohexanediol (2) tends to include several types of alcohols and phenols in a 1 : 1 ratio. Some ammonium halides (3,4) were found to form crystallin inclusion complex with various phenol derivatives. Optical resolution of bis-beta-naphthol derivatives by complexation with optically active amonium halide (5) was found to be very efficiently. We also desiged some phosponium salt host compounds such as 6.
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