| Project/Area Number |
04640584
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
無機・錯塩・放射化学
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| Research Institution | OSAKA CITY UNIVERSITY |
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Principal Investigator |
ISAMU Kinoshita Osaka City Univ. Material Sci. Asoc. Prof., 理学部, 助教授 (80128735)
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| Co-Investigator(Kenkyū-buntansha) |
KITANO Kenichi Osaka Pref. College of Tech. Lecturer, 講師 (20234263)
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| Project Period (FY) |
1992 – 1993
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| Project Status |
Completed (Fiscal Year 1993)
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| Budget Amount *help |
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1993: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1992: ¥1,600,000 (Direct Cost: ¥1,600,000)
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| Keywords | Platinum / Cluster / Tin / Mixed-Metal Complex / スズクラスター / スタニレン / ヘテロ接合 |
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| Research Abstract |
The organic tin clusters as well as Zintle phase anions are quite unstable and difficult to treat. The only acievement to make heterojunction between tin cluster and transition metal is that for Ti(C_5H_5)_2{Sn_5R_6CH_3}Cl. Other exzample with[Co_2(CO)_8] proceeds polymerization, and the product could not be isolated yet. Because of these results, we have changed the view point and proposed the system that could incorporate a series of transition and post transiton metals. Reaction of[P4-mpytH)_4]Cl_2(4-mpytH=4-methy1-2-pyridinethiiol) with transition and post transition metal such as V, Cr, and Sn metal salts produce the new heterometal binuclear complexes as follows. This process can apply to other metal ion system, and further development is expected.
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