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Sulfur-isotope study on the mass extinction boundaries

Research Project

Project/Area Number 04804066
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 鉱物学(含岩石・鉱床学)
Research InstitutionUniversity of Tsukuba

Principal Investigator

KAJIWARA Yoshimichi  Inst.Geosci., Professor, 地球科学系, 教授 (80015578)

Project Period (FY) 1992 – 1993
Project Status Completed (Fiscal Year 1993)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1993: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1992: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsMass extinction / Sulfur isotopes / K / T boundary / P / Tr boundary / Oceanic anoxia / Stratified ocean / Isotope effect / Bacteria / 生物大量絶滅 / 酸化還元条件 / バクテリア同位体効果 / 古環境
Research Abstract

Systematic sulfur isotope data for whole-rock sulfides have been obtained from the chert-dominated, continuous, pelaqic sedimentary sequences spanning the Permian/Triassic (P/Tr) boundary at Tenjinmaru in the chichibu Terrane and at Sasayama in the Tanba Terrane in Japan. The P/Tr boundary is characterized by the occurrence of siliceous shales in association with a carbonaceous black mudstone which is similar in appearance to the worldwide distributed Cretaceous/Tertiary (K/T) boundary claystone. The obsarved data ciearly demonstrate a significant bimodalism. The 34S/32S ratios with respect to CDT are generally low throughout the Hiddle Permian (ca.-39 to -25 %.) and show a remarkable increase beginning in the lower Upper Permian and persisting into the Lower Triassic (ca.-20 to -2 %.), with a temporary and drastic negative shift, down to roughly the same isotopic level as in the Hiddle Permian, just at the suspected P/Tr boundary (ca.-41 to -23 %.). Interestingly, the mode of isotopic excursion across the P/Tr boundary is in striking contrast to that across the K/T boundary which was recently disclosed at Kawaruppu in Hokkado, Japan. The apparent extent of fractionation, with rospect to contemporaneous seawater sulfate, in the high-34S/32S grouplies within the range of -25(〕SY.+-.〔)10 %, which is quantitatively equivalent to the currently confirmed range of kinetic isotope effect during bacterial dissimilatory sulfate reduction, and that in the low-34S/32S group mostly exceeds this range, giving the values typically in the range of -45(〕SY.+-.〔)10 %, which is similar to what is generally observced in the present-day oceanic sediments. The present data would provide strong evidence for the development of a largely stagnant, anoxic stratified ocean, which presumably began to form in the early Late Permian and persisted into the Early Triassic, and for the outbreak of its temporary massive mixing just at the suspected P/Tr boundary. Such an oceanic oxic-anoxic histor

Report

(3 results)
  • 1993 Annual Research Report   Final Research Report Summary
  • 1992 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] Kajiwara,Y.and Kaino,K.: "Oceanic anoxia at the Cretaceous/Tertiary boundary supported by the sulfur isotope record" Palaeoceanogr.Palaeoclimatol.Palaeoecol.99. 151-162 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] 梶原良道: "硫黄の同位体比は語る-K/T境界の海洋環境異変-" 地質ニュース. 458. 6-15 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Shimada,T.and Kajiwara,Y.: "Sulfur isotopic variation within the Cretaceous/Tertiary boundary claystone at Kawaruppu in Hokkaido,Japan" Ann.Rep.,Inst.Geosci.,Univ.Tsukuba. 18. 98-101 (1992)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara,Y.他3名: "Sulfur isotope data from the Permian/Triassic boundary at Tenjinmaru in the Chichibu Terrane in eastern Shikoku,Japan" Ann.Rep.,Inst.Geosci.,Univ.Tsukuba. 19. 59-65 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara,Y.他3名: "Sulfur isotope data from the Permian/Triassic boundary at Sasayama in the Tanba Terrane in Central Honshu,Japan" Ann.Rep.,Inst.Geosci.,Univ.Tsukuba. 19. 67-71 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara,Y.他4名: "Development of a largely anoxic stratified ocean and its temporary massive mixing at the Permian/Triassic boundary" Palaeoceanogr.Palaeoclimatol.Palaeoecol.105(印刷中). (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara, Y.and Kaiho, K.: "Oceanic anoxia at the Cretaceous/Tertiary boundary supported by the sulfur isotopic record." Palaeoceanogr.Palaeoclimatol.Palaeoecol.99. 151-162 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Shimada, T.and Kajiwara, Y.: "Sulfur istopic variation within the Cretaceous/Tertiary boundary at Kawaruppu in Hokkaido, Japan." Ann.Rep., Inst.Ceosci., Unive.Tsukuba. 18. 98-101 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara, Y.: "Sulfur isotope ratios tell-Oceanic environment change at the Cretaceous/Tertiary boundary." Chishitsu News. 458. 6-15 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara, Y., Yamakita, S., Kobayashi, D.and Imai, A.: "Sulfur isotope data form the Permian/Triassic boundary at Tenjinmaru in the Chichibu Terrane in eastern Shikoku, Japan." Ann.Rep., Inst.Geosci., Univ.Tsukuba. 19. 59-65 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara, Y., Ishida, K., Tanikura, Y.and Ishiga, H.: "Sulfur isotope data from the Permian/Triassic boundary at Sasayama in the Tanba Terrane in central Honshu, Japna." Ann.Rep., Inst.Geosci., Univ.Tsukuba. 19. 67-71 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara, Y., Yamakita, S., Ishida, K., Ishiga, H.and Imai, A.: "Development of a largely anoxic stratified ocean and its temporary massive mixing at the Permian/Triassic boundary supported by the sulfur isotopic record." Palaeoceanogr.Palaeoclimatol.Palaeoecol.105 in press. (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara, Y.: "Ocean biogeochemical controls on the Kuroko ore genesis." Chikyukagaku. Spec.Issue in press. (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1993 Final Research Report Summary
  • [Publications] Kajiwara,Y. 他3名: "Sulfur isotope data from The Permian/Triassic boundary at Tenjinmaru in The Chichibu Terrane in eastern Shikoku,Japan" Ann.Rep.,Inst.Geosci.,Univ.Tsukuba. 19. 59-65 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Kajiwara,Y. 他3名: "Sulfur isotope data from the Permian/Triassic boundary at Sasayama in the Tanba Terrane in central Honshu,Japan" Ann.Rep.,Inst.Geosci.,Univ.Tsukuba. 19. 67-71 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Kajiwara,Y. 他4名: "Development of a largely anoxic stratified ocean and its temporary massive mixing at the Permian/Triassic boundary" Palaeogeogr.Palaeoclimatol.Palaeoecol.105(印刷中). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Kajiwara,Y.: "Ocean biogeochemical controls on the Kuroko ore genesis:a review" 地球科学. 特集号(印刷中). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Kajiwara,Y.and Kaino,K.: "Oceanic anoxia at the Cretaccous/Tertiary boundary supported by the sulfur isotopic record" Palaeogeogr.Palaeoclimatol.Palaeoecol.99. 151-162 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 梶原 良道: "硫黄の同位体比は語る:K/T境界の海洋環境異変" 地質ニュース. 458. 6-15 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] 梶原 良道: "硫黄と地球央" 資源地質特別号. 13. 30-36 (1992)

    • Related Report
      1992 Annual Research Report
  • [Publications] Shimada,T.and Kajiwara,Y.: "Sulfur isotopic variation within the Cretaceousl Tertiary boundary claystone at Kawaruppu in Hokkaido,Japan" Ann.Rep.,lnst.Geosci.,Univ.Tsukuba. 18. (1992)

    • Related Report
      1992 Annual Research Report

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Published: 1992-04-01   Modified: 2016-04-21  

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