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New Development of Organic Electrochemistry

Research Project

Project/Area Number 05235101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionTohoku University

Principal Investigator

OSA Tetsuo  Tohoku University, Emeritus Professor, 名誉教授 (10010753)

Co-Investigator(Kenkyū-buntansha) MASTUOKA Hideaki  Tokyo University of Agriculture and Technology, Faculty of Engineering, Professo, 工学部, 教授 (10143653)
UTIMOTO Kiitiro  Kyoto University, Faculty of Engineering, Professor, 工学部, 教授 (90025958)
TORII Sigeru  Okayama University, Faculty of Engineering, Professor, 工学郡, 教授 (70032927)
NONAKA Tsutomu  Tokyo Institute of Technology, Inter-disciplinary Graduate School of Science and, 大学院・総合理工学研究科, 教授 (00016528)
鈴木 周一  東京工業大学, 名誉教授 (20016710)
Project Period (FY) 1993 – 1995
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥34,700,000 (Direct Cost: ¥34,700,000)
Fiscal Year 1996: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1995: ¥10,900,000 (Direct Cost: ¥10,900,000)
Fiscal Year 1994: ¥9,400,000 (Direct Cost: ¥9,400,000)
Fiscal Year 1993: ¥11,400,000 (Direct Cost: ¥11,400,000)
KeywordsOrganic Electrochemistry / Electron-transfer Field / Electrogenerated Unusual Active Species / Mediator Reaction / Electron Transfer System in Coordination Compounds / Asymmetric Electrolysis / Enantioselective Electrolysis / Biochemistry / 有機反応 / 電極界面 / 錯体電子移動反応 / 不斉合成 / 生物電気化学
Research Abstract

Investigation of this group {X00} playd a function of managemet group for this rescarch project. The group consisted of 6 advisory and 5 executive members exerted an effective propulsion of the research project in close cooperation of four research groups (A01-A04) , getting advice by advisory members.
1.Research Subjects and Ressults The project was set up by four research subjects : 1) Design and Control of Electron-transfer Reaction Fields (A01), 2) Electrogenerated Unusual Active Species (A02), 3) Development of Mediator Reactions (A03), and 4) New Development of Electron Transfer in Coordination Compounds (A04). The project was pursued by 29 project members and 91 public-applicant members for 1995. In October, 1996, we evaluated a fruitful success in all the subjects which developed not only organic electrochemistry remarkably but also contributed to build many organic reaction systems being unable to perform by conventional organic chemistry methods. Furthermore, the results was c … More ontributed to build interdisciplinary areas with coordination chemistry and biochemistry. Its shoul be mentioned that asymmetric or enantioselective electrolysis was achieeved over our intial proposal which would become to a new tool in organic chemistry.
2.Opening of Whole Members' Meeting and Open Symposia Six whole members' meetings and 5 open symposia were connectively opened as well as many times of meetings for management group and each research subject groups. It is noticed that the group leaders arranged actively to maintain informal four cooperative research systems concerning reactive metal surface electrode, electrode reaction by physical method, biofunctionality throughelectron transfer and chiral synthesis.
3.Printing Meterials Research reports composed of each 2 pages in Japanese and English versions by all the members were published in the end of each years and a collective research report by 4 English pages of every member was done in December, 1996. Abstracts at the whole members' meetings and open symposia were not only distributed to the members and other participants every time, but 12 times of news letters relating the research were also distributed to the members. An English book "New Challenges in Organic Electrochemistry" which was applied a support to Monbusho is being prepared to publish in February, 1998. Less

Report

(5 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • Research Products

    (108 results)

All Other

All Publications (108 results)

  • [Publications] Tetsuo Osa: "Preparative,Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly(Acrylic Acid)Layer-Coaated Graphite Felt Electrode Coimmobilizing Ion-Paired Methylviologen-Cation Exchange Polymer and Diaphorase" Chemistry Letter. 1093-1094 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tetsuo Osa: "Enantioselective,Electrocatalytic Oxidation of Racemic Alcohols on a TEMPO-modified Graphite Felt Electrode by Use of Chiral Base(TEMPO=2,2,6,6-tetramethylpiperidin-1-yloxyl)" Chemical Communications. 2745-2746 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tetsiuo Osa: "Enantioselective,Electrocatalytic Lactonization of Methyl-substituted Diols on a TEMPO-modified Graphite Felt Electrode in the Presence of(-)-Sparteine" Chemistry Letter. 1043-1044 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Temperature.Electroreduction of Acetophenone" Chemistry Letter. 862-862 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes.Part4.Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes.Part5.Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3 Systems with Sharpless' Ligand" Journal of Organic Chemistry. 61. 3055-3061 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Sythesis of 3-Chloro-Δ^3-cephem-4-carboxylate by Addition/Cyclization of Allen-carboxylate.Copper(II)-Promoted Aerobic Oxidation of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical,Anion and Cation.Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kiitiro Uchimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letter. 851-852 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kiitiro Uchimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1,1-Dihaloalkanes with Aldehydes.Generation of Chiral a-Iodoethyl Building Block from Aciral 1,1-Diiodoethane" Angewandte Chemie,International Edition in English. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Hideaki Matsuoka: "Application of Multifuncitional Microelectrode to the in vivo Analysis of the K^+ Response to CO_2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Hideaki Matsuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochimica Biophysica Acta. 1289. 1-4 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Novel Trends in Electroorganic Synthesis" Kodansha Ltd., 374 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsetsuo Osa: "Enantioselective, Electrocatalytic Lactonization of Methyl-substitute Diols on a TEMPO modified Graphite Felt Electrode in the Presence of (-) -Sparteine" Chemistry Letters. 1996. 1043-1044

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tetsuo Osa: "Preparative, Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly (Acrylic Acid) Layr-Coated Graphite Felt Electrode Coimmobilizing Ion-paired Methyl Viologen-Cation-Exchange Polymer and Diaphorase" Chemistry Letters. 1996. 1093-1094

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Oxidation of Racemic Alcohols on TEMPO modified Graphite Felt Electrode by Use of Chiral Base (TEMPO=2,2,6,6-trtramethylpiperidin-1-yloxyl)" Chemical Communications. 1996. 2745-2746

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Tempreture. Electroreduction of Acetophenone" Chemistry Letters. 1995. 862-862

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part4. Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tssutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part5. Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3 Systems with Sharpless' Ligand" Journal of Organic Chemistry. 1994. 953-954

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Sythesis of 3-Chloro-DELTA^3-cephem-4-carboxylate by Addition/Cyclization of Allen-carboxylate. Copper (II)-Promoted Aerobic Oxidatio of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. 69. 1391-1396 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical, Anion and Cation. Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kiitiro Utimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letters. 1995. 851-852

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kiitiro Utimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1,1-Dihaloalkanes with Aldehydes. Generation of Chiral a-Iodoethyl Building Block from Aciral 1,1-Diiodoethane" Angewandte Chemie, International Edition in English. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Hideaki Matsuoka: "Application of Multifunctional Microelectrode to the in vivo Analysis of the K^+ Response to CO^2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Hideaki Mastuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochemica Biophysica Acta. 1289. 1-4 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tetsuo Osa: "Preparative, Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly (Acrylic Acid) Layer-Coaated Graphite Felt Electrode Coimmobilizing Ion-paired Methylviologen-Cation Exchange Polymer and Diaphorase" Chemistry Letter. 1093-1094 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Oxidation of Racemic Alcohols on a TEMPO-modified Graphite Felt Electrode by Use of Chiral Base (TEMPO = 2, 2, 6, 6-tetramethylpiperidin-1-yloxyl)" Chemical Communications. 2745-2746 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Lactonization of Methyl-substituted Diols on a TEMPO-modified Graphite Felt Electrode in the Presence of (-)-Sparteine" Chemistry Letter. 1043-1044 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Temperature. Electroreduction of Acetophenone" Chemistry Letter. 862-862 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part4. Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part5. Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3Systems with Sharpless' Ligand" Journal of Organic Chemistry. 61. 3055-3061 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Sigeru Torii: "Sythesis of 3-Chloro-Δ^3-cephem-4-caboxylate by Abbition/Cyclization of Allen-carboxylate. C0pper (II)-Promoted Aerobic Oxidatio of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical, Anion and Cation. Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Kiitiro Uchimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letter. 851-852 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] Kiitiro Uchimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1, 1-Dihaloalkanes with Aldehydes. Generation of Chiral a-Iodoethyl Building Block from Aciral 1, 1-Diiodoethane" Angewandte Chemie, International Edition in English. (印刷中). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] Hideaki Matsuoka: "Application of Multifunctional Microelectrode to the in vivo Analysis of the K^+ Response to CO_2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Hideaki Matsuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochimica Biophysica Acta. 1289. 1-4 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Sigeru Torii: "Novel Trends in Electroorganic Synthesis" Kodansha Ltd., 374 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] Tomonori Hoshi: "Controlled Deposition of Glucose Oxidase on Platinum Electrode Based on an Avidin/Biotin for the Regulation ofOutput Current of Glucose Sensors" Analytical Chemistry. 67. 770-774 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Tomonori Hoshi: "Use of Electrodeposited Avidin Film for the Preparation of Lactate and Choline Sensors" Analytical Sciences. 11. 311-312 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Naotaka Sato: "Electroatalytic Activity of Poly(tetrafluoroaniline)Film-Coated Electrode for Fe^<3+/2+> Redox Response" Denki Kagaku. 63. 437-439 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Po-Chang Chen: "InFluemces of Electroytic Conditions on Emulsion Electrolysis:n-Octanol Oxidation" Denki Kagaku. 63. 395-399 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Mahito Atobe: "Ultrasonic Effects on Electroorganic Processes.Electroreduction of Bezaldehydes on Ultrasoundvibrating Electrodes" Chemistry Letters. 669-670 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Naotake Sato: "Electopolymerization of o-Mercaptoniline Monolayer Self-assembled on an Au Electrode" Chemistry Letters. 805-806 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Katsuhiko Tsunashima: "Product-Selectivity Control in an Electroorganic Process by Temperature.Electroreduction of Acetophenone" Chemistry Letters. 862-862 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hideko Tanaka: "Synthesis of 2-exo-Methylenepenam by Reductive 1,2-Elimination and S-S Bond Fission in a PbBr_2/Al Bimetal System" Chemistry Letters. 709-710 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Tsutomu Inokuchi: "One-pot Conversion of Primary Alcohols to α-Oxygenated Alkanals with TEMPO in Combination with Moleculaar Oxygen and Ruthenium Complex" Tetrahedron Letters. 36. 3223-3226 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sigeru Torii: "A Novel Ru(VII)/Ru(IV)Mediarory System for Electrooxidation of Primary and Seondary Alcohols,Leading to Aldehydes and Ketones" Chemistry Letters. 369-370 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sigeru Torii: "Electrochemical Deamination of Aromatic Amines" Synlett. 439-440 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Sigeru Torii: "Electrochemical Os-Catalyzed Asymmetric Dihydrixylation of Olefins with Sharpless Ligand" Chemistry Letters. 319-320 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Kazuhiko Takai: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letters. 851-852 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Kiitiro Utimoto: "Diastereoselective 1,4-Addition of Organocopper-Lanthanoid Reagents to α,β-Unsaturated Ketones Containing 1,3-Oxathiane as a Chiral Auxiliary" Synlett. 501-502 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Seijiro Matsubara: "Alkylidenation of Ketones By gem-Dibromoalkane,SmI_2,and Sm in the Presence of Catalytic Amount of CrCl_3" Chemistry Letters. 259-260 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Kiitiro Utimoto: "A Preparation of β-Oxoester Enolate Equivalents from SmI_2 and a-Bromoalkanoates" Chemistry Letters. 197-198 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hideaki Matsuoka: "Combined Effect of Amphoterricin B and Flucytosine on Hyphal Growth of Canadida Albicans Estimated at a Single Hypha Level" Journal of Medical and Veterinary Mycology. 33. 191-195 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hyeong-Cheol Yang: "Application of a Microscopic Fluoresdence Indicator to the Determination of Antimycotic Activity" Journal of Antibacterial Antifungal Agent. 23. 3-7 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 戸田不二雄: "シクロデキストリン(5・4シクロデキストリンと電気化学)" 産業図書, 348 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Yoshitomo Kashiwagi: "The Effects of Chain Length of Ferrocene Moicty on Mediator-and Enzymes-Modified Electrode" Denki Kagaku. 62. 1240-1246 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Tetsuo Osa: "Enantioselective,Electrocatalytic Oxidative Couplings of Naphthols,Naphthyl Ether and Phenanthrol on a TEMPO-Modified Graphite Fell Electrode in the Presence of (-)-Sparteine" Journal of Chemical Society,Chemical Communications. 2535-2537 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Mahito Atobe: "Utrasonic Effects on Electroorganic Processes II.Electroreduction of Methyl Halides on a Reactive Tin Cathode" Denki Kagaku. 62. 1298-1299 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Akiko Yoshiyama: "Preparation of PTEE Composite-Plated Hydrophobic β-PbO_2 Electrodes" Chemistry Letters. 1565-1568 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Kazuya Matsuda: "Ultrasonic Effects on Electroorganic Processes.Product-Selectivity in Electroreduction of Benzaldehydes" Chemistry Letters. 1619-1622 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Yasushi Ono: "Electrolysis Using Composite-Plated Electrodes.Preparation of a Binary Type Composite-Plated Nickel Electrode with Poly(terafluoroethylene)and Silica Gel and 1ts Application in Electroreduction of Aldehydes" Chemistry Letters. 1623-1626 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Toshio Fuchigami: "Electrocatalysis of self a Self-Assembled Thiol-modified Electrode Having Immobilized Dopamine for Oxidation of Reduced Nicotinamide-Adenine Dinucleotide(NADH)" Denki Kagaku. 62. 1251-1253 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Yasushi Ono: "Electrolysis Using Composite-plated ElectrodesX Preparation of Hydrophobic Nickel and Zinc Electrodes Composite-plated with Fluorinaated Pitch and Their Application in Electroreduction of Organic Compounds" Denki Kagaku. 62. 1048-1053 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Yasushi Ono: "Electrolysis Using Composite-plated Electrodes XII.Theoretical and Experimental Analysis of Hydrophobic Effect of Ni/PTFE Composite-plated Electrodes on an Electroorganic Process" Denki Kagaku. 62. 1264-1268 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Tsutomu Inokuchi: "Indirect Electrochemical Radical Cyclization of Bromo Acetals by the Combined Use of Cobaloxime and Sacrificial Electrode" Bulletin of the Chemical Society of Japan. 67. 595-598 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hideo Tanaka: "Use of Aluminium as an Electron Pool.Reductive Coupling of Iodebenzenes Promoted by Electron Transsfer in an Ni/Pb/Al Multi Redox System" Inorganica Chim ica Acta. 222. 323-325 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hideo Tanaka: "A Facile Access to 3-A1lyl-and 3-Benzyl-3-cephems via Reductive Addition/Cyclization of Allenecarboxylate with Allyl and Benzyl Halides in an Al/Pb/Ni Redox System" Journal of Chemical Society,Chemical Communications. 1461-1462 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Tsutomu Inokuchi: "Oxidations of Dihydroxyalkanoates to Vicinal Tricarbonyl Compounds with a 4-Bzo TEMPO- Sodium Bromite System or by Indirect Electrolysis with 4-Bzo TEMPO and Bromide Ion" Chemistry Letters. 1411-1414 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Kazuhiko Takai: "Stereoselective Preparation of Primary(E)-Allylic Amines by the Reaction of Tantalum-Alkyne Complexes with Metallo-Imines" Tetrahedron Letters. 35. 1893-1896 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Kazuhiko Takai: "A Novel Catalytic Effect of Lead on the Red uction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compounds Acceleration of the Witting-Type Ole fination with the RCHX_2-TiO_2-Zn Systems by Addition of Lead" Journal of Organic Chemistry. 59. 2668-2670 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Toshiaki Yokoo: "A Room Temperature Preparation of Alkenyl Lithium-Halogen Exchange between Alkenyl Iodides and n-BuLi in Hydrocarbon Solvents" Synlett. 645-647 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidative Coupling Reaction of Naphthols and Naphthol Ethers" Chemistry Letters. 81-84 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidative Coupling of Methylquinolines on TEMPO-Modified Graphite Felt Electrode" Chemistry Letters. 257-260 (1993)

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  • [Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidation of NADH on Thin Poly(acrylic acid)Film Coated Graphite Felt Electrode Coimmobilizing Ferrocene and Diaphorase" Chemistry Letters. 677-680 (1993)

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  • [Publications] Iwao Suzuki: "Electrochemical Conversion of Alcohols into Aldehydes Mediated by Lipophilic γ-Cyclodextrin Bearing a Ferrocene Moiety" Chemistry Letters. 1719-1722 (1993)

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  • [Publications] 長 哲郎: "高分子修飾電極を用いる電解合成" 化学工業. 45. 121-126 (1994)

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  • [Publications] Tetsuo Osa: "Electroenzymatic Oxidation of Alcohols on a Poly(acrylic acid)-coated Graphite Felt Electrode Terimmobilizing Ferrocene,Diaphorase and Alcohol Dehydrogenase" Chemistry Letters. 367-370 (1994)

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  • [Publications] M.Umezawa: "Electroreductive Polymerization of Dichlorocarbosilanes" Electrochimica Acta. 38. 529-533 (1993)

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  • [Publications] Po-Chung Cheng: "Electroreduction of Methyl Cinnamate Using a Rotating Cylinder Electrode" Denki Kagaku. 61. 218-223 (1993)

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  • [Publications] Shu-Yong Guo: "Maximum in Oxidizing Power of Anodically-Generated Br-Cl Composite Reagents" Denki Kagaku. 61. 245-246 (1993)

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  • [Publications] Po-Chung Cheng: "Electron-Transfer Process in Emulsion Electrolysis" Denki Kagaku. 61. 886-887 (1993)

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  • [Publications] Yoshihito Kunugi: "Electroorganic Reactions on Organic Electrodes.Part18" Journal of Electroanalytical Chemistry. 353. 209-215 (1993)

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  • [Publications] Yoshihito Kunugi: "Preparation of Hydrophobic Zinc and Lead Electrodes and Their Application to Electroreduction of Organic Compounds" Journal of Electroanalytical Chemistry. 356. 163-169 (1993)

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  • [Publications] Yoshihito Kunugi: "Electrolysis of Emulsion of Organic Compounds" Denki Kagaku. 140. 2833-2836 (1993)

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  • [Publications] 野中 勉: "電極電子化学" 電気学会誌. 113. 727-731 (1993)

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  • [Publications] 野中 勉: "有機電解用電極材料の新展開" 表面. 31. 737-745 (1993)

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  • [Publications] 野中 勉: "疎水性電極による有機電解" 化学工業. 45. 127-130 (1994)

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  • [Publications] Hideo Tanaka: "2-Substituted Penems,New Candidates for Cephalosporinase Inhibitors" Bioorganic & Medicinal Chemistry Letter. 3. 2253-2254 (1993)

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  • [Publications] Hideo Tanaka: "Mg/PbBr_2 Bimetal Redox-Promoted Stannation of Propargyl,Allyl,Vinyl,and Aryl Halides" Synlett. 835-836 (1993)

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  • [Publications] Tsutomu Inokuchi: "Electrochemical Wacker Type Reaction with a Double Mediatory System Consisting of Palladium Complex and Tri(4-bromophenyl)amine" Chemistry Letters. 121-124 (1994)

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  • [Publications] Sigeru Torii: "Electroreduction of 5-Chloro-7-nitrobenzofuran Derivative,a Facile Access to a Key Intermediate for ACTA Inhibitors" Synlett. 68 (1994)

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  • [Publications] Sigeru Torii: "Electrochemical Generation of C-N-C 1,3-Dipole Leading to Pyrrolidine Skeleton" Synlett. 印刷中. (1994)

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  • [Publications] Ryohei Yamaguchi: "A Highly Effective One-Pot Bicycloannulation Methodology for the Synthesis of Berban and Yohimban Systems Based on Organotin-Mediated Three-Componennt Coupling(N-Acylative Pentadienylation of C=N Bonds)" Journal of Organic Chemistry. 58. 1136-1143 (1993)

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  • [Publications] Hiroshi Shinokubo: "tert-Butyldimethylsilyldichloromethyllithium as a Dichloromethylene Dianion Synthon 1,3-Rearrangement of Silyl Group from Carbon to Oxide" Tetrahedron Letters. 34. 1951-1954 (1993)

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  • [Publications] Hiroshi Shinokubo: "Rearrangement of β-t-Butyldimethylsiloxy Carbenoids.Regio-and Stereoselective Synthesis of (Z)-1-Halo-2-tert-butyldimethylsiloxy-1-alkenes" Tetrahedron Letters. 34. 4985-4988 (1993)

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  • [Publications] Masahiko Taniguchi: "Triethylborane Induced Intermolecular Hydrogermylation of Homoallylic Alcohols and Homopropargylic Alcohols" Chemistry Letters. 1751-1754 (1993)

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  • [Publications] Kozo Matsumoto: "Lithium Carbenoids Induced Ring Enlargement of Silacyclobutane into 2-Halo-1-silacyclopentane and its Use in Organic Synthesis" Tetrahedron. 49. 8487-8502 (1993)

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  • [Publications] 内本喜一朗: "有機金属化合物を用いる高選択的有機反応" 有機化学合成協会誌. 51. 1064-1073 (1993)

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  • [Publications] Masahiko Taniguchi: "Stereoselective Reduction of 2-Methyl-3-oxo Ethers(or Amides)with Sodium Borohydride Catalyzed By Manganese(II)Chloride or Tetrabutylammonium Borohydride.A Practical Preparation of erythro and threo-3-Hydroxy-2-methyl Esters(or Amides)" Tetrahedron. 49. 11169-11182 (1993)

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  • [Publications] Kazuhiko Takai: "A Dramatic Effect of a Catalytic Amount of Lead on the Simmons-Smith Reaction and Formation of Alkylzinc Compounds from Iodo Alkanes.Reactivity of Zinc Metal:Activation and Deactivation" Journal of Organic Chemistry. (印刷中). (1994)

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  • [Publications] Seijiro Matsubara: "Lanthanoid Triflate Catalyzed Conjugate Addition of Amines to α,β-Unsaturated Esters.A Facile Route to Optically Active β-Lactam" Chemistry Letters. (印刷中). (1994)

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  • [Publications] Seijiro Matsubara: "Diastereoselective Addition of Organometallic Reagents to Imines or Hydrazones Containing 1,3-Oxathiane as a Chiral Template" Chemistry Letters. (印刷中). (1994)

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  • [Publications] Tsutomu Nonaka: "New Functionality Materials,Vol.C(ed by M.Doyama)" Elsevier Sci.Pub.B.V., 6 (1993)

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Published: 1993-04-01   Modified: 2016-04-21  

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