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MOLECULAR THERMAL ENGINEERING RESEARCH ON CONDENSATION

Research Project

Project/Area Number 05239101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionTOYO UNIVERSITY (1995)
The University of Tokyo (1993-1994)

Principal Investigator

KOTAKE Susumu  Toyo University.Dept.of Mechanical Engineering.Professor, 工学部, 教授 (30013642)

Co-Investigator(Kenkyū-buntansha) FUJIKAWA Shigeo  Toyama Prefectural University, Dept.of Mechanical Engineering, Professor, 工学部, 教授 (70111937)
OKUYAMA Kikuo  Hiroshima University, Dept.of Chemical Engineering, Professor, 工学部, 教授 (00101197)
OKADA Tatsuo  Kyushu University, Dept.of Electronic Devices, Professor, 工学部, 教授 (90127994)
AIHARA Toshio  Tohoku University, Institute of Fluid Science, Professor, 流体科学研究所, 教授 (90006172)
IMAISHI Nobuyuki  Kyushu University, Institute of Advanced Material Study, Professor, 機能物質化学研究所, 教授 (60034394)
長崎 孝夫  東京工業大学, 工学部, 助教授 (30155923)
井上 剛良  九州大学, 機能物質科学研究所, 助教授 (20193592)
土方 邦夫  東京工業大学, 工学部, 教授 (60016582)
岡崎 健  東京工業大学, 炭素循環素材研究センター, 教授 (20124729)
Project Period (FY) 1993 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥104,600,000 (Direct Cost: ¥104,600,000)
Fiscal Year 1995: ¥33,100,000 (Direct Cost: ¥33,100,000)
Fiscal Year 1994: ¥38,500,000 (Direct Cost: ¥38,500,000)
Fiscal Year 1993: ¥33,000,000 (Direct Cost: ¥33,000,000)
KeywordsMolecular condensation / Film condensation / Thermal and chemical CVD / Cluster / Fineparticle / Thin film / Condensation control / Molecular thermal Engineering / 熱CVD・プラズマCVD
Research Abstract

With the aim of understanding the molecular mechanism of clustering and film condensation of gaseous atoms and molecules and of finding the controlling techniques for fine-particle and thin-film processing, the following subjects have been studied theoretically and experimentally ; (1) Molecular mechanism of cluster formation and film condensation, (2) Control of film thickness, composition and crystal structure of thermal CVD process, (3) Fundamental processes of thin film condensation of metal atoms, (4) Micro-scale heat transfer in formation processes of clusters and thin films, (5) Molecular kinetic theory of phase change, (6) Molecular dynamics of cluster formation, (7) Atomic and molecular behavior in laser ablation, (8) Formation and growth processes of fine particles in gaseous reaction, (9) Molecular dynamics mechanism of condensation and evaporation of liquid molecules, (10) Effects of small temperature gradient on CVD process. The major results yield the relationships betwee … More n the cluster size the film condensation rate, film condensation mechanism of thermal CVD with surface reactions, evidence of uniform and rapid film formation by high-speed rotating thermal CVD,effects of translational energy of condensing metallic atoms on film condensation, detection of cluster formation in expansion beams of metallic atoms by a retarding electric field method, condensation coefficients of methanol vapor with the shock-tube method by measuring the film thickness and temperature change, molecular dynamics processes of cluster and hydrogen-bond formation of water molecules, atomic and molecular behavior in the process of laser ablation of high-temperature super-conducting thin film through in-situ observation using laser-induced fluorescence, sintering and growth characteristics of fine particles formed in gaseous reactions, molecular dynamics mechanism of condemsation and evaporation of liquids, and effects of small temperature gradient on CVD process through formed radicals. Less

Report

(4 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • Research Products

    (56 results)

All Other

All Publications (56 results)

  • [Publications] 青木 功: "分子クラスターと膜凝縮速度に関する研究" 日本機械学会論文集. B61-591. 283-287 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Akiyama,Y.: "Shape of film grown on micro-size trenches and holes by chemical vapor deposition:3-dimensional Monte Calro simulation" Japan Journal Applied Physics. 34. 6171-6177 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Fujikawa,S.: "Molecular study on phase transition phenomena of fluid" Thermal Science and Engineering. 3-3. 45-50 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ohara,T.: "Molecular dynamics study on phase change and cluster formation in fluid" Thermal Science and Engineering. 3-3. 7-13 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Nakata,Y.: "Two-dimensional laser-induced fluorescence imaging on non-emissive species in pulsed-laser deposition process of YBa2Cu307-x" Applied Physics Letters. 66-23. 3206-3208 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Seto,T.: "Evaluation of sintering on nanometer-sized titania using aerosol method" Aerosol Science Technology. 23-2. 183-200 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Aoki, I and Kotake, S.: "Study of cluster size effects on film condensation" Trans.of JSME. B61-591. 283-287 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Akiyama, Y.and Imaishi, N.: "Shape of film grown on micro-size trenches and holes by chemical vapor deposition : 3-dimensional Monte Calro simulation" Japan Journal Applied Physics. 34. 6171-6177 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Inoue, T.: "Effect of the translational energy of silver atoms and the deposition rate on the film condensation process and crystalline of thin film" Thermal Science and Engineering. 3-3. 51-56 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Fujikawa, S.: "Molecular study on phase transition phenomena of fluid" Thermal Science and Engineering. 3-3. 45-50 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Fujikawa, S.: "Theory of film condensation on shock-tube endwall behind reflected shock wave" Trans.of JSME. 61B-581. 635-642 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ohhara, T.and Aihara, T.: "Molecular dynamics study on phase change and cluster formation in fluid" Thermal Science and Engineering. 3-3. 7-13 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ohara, T.and Aihara, T.: "Molecular dynamics study on hydrogen bond in water" Trans.of JSME. 61B-595. 1107-1114 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Nakata, Y.and Okada, T.: "Two-dimensional laser-induced fluorescence imaging on non-emissive species in pulsed-laser deposition process of YBa2Cu307-x" Applied Physics Letters.66-23. 3206-3208 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Seto, T.and Okuyama, K.: "Evaluation of sintering on nanometer sized titania using aerosol method" Aerosol Science Technology. 23-2. 183-200 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Matsumoto, M.: "Molecular mechanism of evaporation and condensation" Thermal Science and Engineering. 3-3. 27-33 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 青木 功: "分子クラスターと膜凝縮速度に関する研究" 日本機械学会論文集. B61-591. 283-287 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 北原 元: "分子クラスターの薄膜凝縮に関する研究" 32回日本伝熱シンポジウム講演論文集. 2. 577-578 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Akiyama: "Applicability of one-dimensional diffusion model for step coverage analysis-comparison with a single Monte-Carlo method" Applied Physics Letters. 67. 620-622 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Akiyama: "Shape of film grown on micro-size trenches and holes by chemical vapor deposition:3-dimensional Monte Calro simulation" Jpn Journal Applied Physics. 34. 6171-6177 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Inoue: "Effect of the translational energy of silver atoms and the deposition rate on the film condensation process and crystalline of thin film" Thermal Science and Engineering. 3-3. 51-56 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 長崎 孝夫: "金属蒸気の膨張におけるクラスター生成に関する研究" 32回日本伝熱シンポジウム講演論文集. 3. 859-860 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Fujikawa: "Molecular study on phase transition phenomena of fluid" Thermal Science and Engineering. 3-3. 45-50 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Fujikawa: "Shock-tube-deduced condensationcoefficient" Proc.of 20th Int.Symp on Shock Waves. in press (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Ohara: "Molecular dynamics study on phase change and cluster formation in fluids" Thermal Science and Engineering. 3-3. 7-13 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 小原 拓: "水の水素結合に関する分子動力学的研究(第2報,水素結合ネットワークの解析" 日本機械学会論文集. B61-583. 1107-1113 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] W.K.A.Kumuduni: "Effect of cumulative ablation on the ejection of particulates and molecular species from YBa2Cu307-x targets" J.Applied Physics. 77-11. 5961-5967 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Nakata: "Two-dimensional laser-induced fluorescence imaging of non-emmisive species in pulsed-laser depostion process of YBa2Cu307-x" Applied Physics Letters. 66-23. 3206-3208 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Seto: "Evaluation of sintering of nanometer-sized titania using aerosol method" Aerosol Science Technology. 23-2. 183-200 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Adachi: "Film preparation by a new chemical vapor deposition process using ionization of tetraethylorthosilicate" Jpn.J.Applied Phys.34-2(9A). 1148-1150 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Matsumoto: "Molecular mechanism of evaporation and condensation" Thermal Science and Engineering. 3-3. 27-31 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Yasuoka: "Dynamics near a liquid surface:mechanism of evaporation and condensation" J.Molecular Liquids. 65-66. 329-332 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 橋本博文: "相変化過程における分子振動エネルギー変化の分光学的研究" 日本機械学会論文集(B). 60-571. 977-982 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Hashimoto: "Fourier transform infrared spectroscopy of molecular clusters" Progress in Astronautics and Aeronautics. 158. 302-310 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 今石宣之: "酢酸亜鉛によるZnOのCVDに及ぼす操作圧の効果" 化学工学論文集. 21-2. 印刷中 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] N.Imaishi: "Reaction analysis for ZrO_2 and Y_2O_3 thin film growth by LPCVD using β-diketonate complexes" J.Crystal Growth. 147. 130-146 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 藤川重雄: "会合性液体の蒸発・凝縮現象に関する分子論的研究" 日本機械学会論文集(B). 61-581. 215-222 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 藤川重雄: "衝撃波の反射領域・衝撃波管管端面での蒸気の膜状凝縮理論" 日本機械学会論文集(B). 61-582(印刷中). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小原 拓: "水の水素結合に関する分子動力学的研究(第1報:結合数及び寿命の温度・密度依存成)" 日本機械学会論文集(B). 61-582(印刷中). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小原 拓: "水の水素結合に関する分子動力学的研究(第2報:水素結合ネットワークの解析)" 日本機械学会論文集(B). 61-583(印刷中). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Nakata: "Plume-subtrate interaction in pulsed-laser deposition of high temperature superconducting thin film" Appl.Phys.Lett.64. 2599-2801 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] W.K.A.Kumudani: "Spatial distribution of YO molecules ejected from laser-ablated YBa_2Cu_3O_7-x" Applied Physics. B58. 289-294 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Shimada: "Wall deposition of ultrafine particles by thermophoresis in nonisothermal laminar pipe flow of different carrier gas" Jpn J.Appl.Phys.33. 1174-1181 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Shimada: "Size change of very fine silver agglomerates by sintering in a heated flow" J.Chem.Eng.Jpn.27. 795-802 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 橋本博文: "相変化過程の分子振動エネルギーの研究" 30回日本伝熱シンポジウム講演論文集. 1. 331-333 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小林伸和: "分子線TOF法による金属薄膜凝縮の研究" 30回日本伝熱シンポジウム講演論文集. 1. 325-327 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小林伸和: "分子線TOF法によるクラスターの凝縮の研究" 日本機械学会論文集. B59. 3877-3882 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Imaishi: "LPMOCVD of YSZ thin film:experiment and model analyses" Proc.12 Int.Symp.Chem.vapor Deposition. PV.93-2. 300-305 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Imaishi: "Maragoni convection in small liquid bridge of molton NaCl" Proc.Int.Symp.Microgravity Sci.Appl.C-7. 1-6 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Imaishi: "Reaction analysis for Zr02 and Y203 thin film growth by LPCVD using β-diketonate complexes" J.Crystal Growth. 135(未定). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] K.Okazaki: "Highly nonequilibrium plazma chemistry at atmospheric pressure and temperature in the conrol of material conversion processes" Thermal Science and Engineering. 2. 21-27 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 岡崎健: "高電圧極短パルスプラズマの構造形成過程制御と応用" 30回日本伝熱シンポジウム講演論文集. 3. 736-738 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 土方邦夫: "金属蒸気の凝縮核生成に関する研究" 30回日本伝熱シンポジウム講演論文集. 1. 319-321 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 藤川重雄: "衝撃波の反射領域における蒸気の相変化の理論" 日本機械学会北陸信越支31期講演論文集. 1(未定). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 藤川重雄: "異波長レーザービームによる多原子分子蒸気の相変化測定" 日本機械学会北陸信越支31期講演論文集. 1(未定). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 藤川重雄: "レーザー差動干渉法による衝撃波管内気体密度の測定" 日本機械学会北陸信越支31期講演論文集. 1(未定). (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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