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Reactive and Unusual Molecules

Research Project

Project/Area Number 05303003
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionUniversity of Tsukuba

Principal Investigator

ANDO Wataru  Univ.of Tsukuba, Dept.of Chemistry, Professor, 化学系, 教授 (30008429)

Co-Investigator(Kenkyū-buntansha) MIYASHI Tsutomu  Univ.of Tohoku, Dept.of Chemistry, Professor, 理学部, 教授 (20004442)
TOMIOKA Hideo  Univ.of Mie, Dept.of Chemistry, Professor, 工学部, 教授 (20024599)
SUZUKI Hitomi  Univ.of Kyoto, Dept.of Chemistry, Professor, 理学部, 教授 (50025342)
ODA Masaji  Univ.of Osaka, Dept.of Chemistry, Professor, 理学部, 教授 (60004438)
FURUKAWA Naomichi  Univ.of Tsukuba, Dept.of Chemistry, Professor, 化学系, 教授 (80015966)
石川 満夫  広島大学, 工学部, 教授 (20025985)
Project Period (FY) 1993 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥11,200,000 (Direct Cost: ¥11,200,000)
Fiscal Year 1995: ¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 1994: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1993: ¥6,000,000 (Direct Cost: ¥6,000,000)
Keywordssilylene / fullerene / reactive intermediate / unusual reactions / strained compounds / perooxysulfinate / long triplet carbene / フラーレン / 歪化合物 / 反応性ケイ素種 / 活性分子 / 異常原子価 / 高歪み化合物 / 活性種 / 反芳香族性 / π-共役 / 歪み化合物 / 活性中間体 / ヘテロ原子 / 機能性有機材料 / 反応制御
Research Abstract

Ando has synthesized 9,10-dimethyl-9,10-disilanthracene dimer by treatment of the corresponding dihydrodisilaanthracene with lithium. The dianion is regarded as synthetic equivalent for disilaaromatics with respect to its reactivity toward diphenylacetylene. Tomioka obtained extremely long lived triplet carbene. Oku has reported the ring-expansion reaction via ethereal bicyclooxonium ylides of carbenes.a stable triple carbene. Kira found unique reactions of tetrakis (trialkylsily) disilene and digermenes. Sugimori shows the cyclopentadienyliodo (dimethyldithiocarbamato) cobalt reacts with diazomethane to give a novel complex having a five membered dithiolene ring and four membered cobaltathiethane ring. Sekiguchi reported unique properties of the polyorganosilyllithium. Iyoda reported the unusual reactivities of fullereols and fullerene dimers containing perfluoroalkyl groups. Oda reported the regioselective lithiations carbanion formation of arylmethanes directing towards new synthetic building blocks. Tokitoh have synthesized extremely hindered disilenes bearing a new steric protection group and found the both cis and trans were kinetically very stable but thermally labile to give the corresponding silylene under very mild conditions. Sawaki found the new structure and reactivity of XOO active oxygen species.

Report

(4 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • Research Products

    (97 results)

All Other

All Publications (97 results)

  • [Publications] W Ando: "Polyorganosilicon Compounds in Strained Carbocyclic Systems" Bull Chem. Soc. Jpn. 69. 1-16 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Kimura, H. Nakayama, N. Furukawa: "Highly Diastereoselective Oxidation of 1-Alkylsufinyl-9- (Alkylthio) dibenzothiophene with MCPBA in the presence of Trifluoroboran Etherate" Heterocycles. 42. 71-74 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A. Naka, S. Okazaki, M. Havashi, M. Ishikawa: "Silicon-carbon unsaturated compounds LIV:Nickel-catalyzed reactions of 3, 4-binzo-1, 1, 2, 2-tetraethyl-1, 2-disilacyco-but-3-ene with alkynes" J. Organo Chem. 35-41 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H. Nakano, T. Ibata: "The Rhodium (II) Acetate-Catalyzed Reaction of Alkenyl and Alkynylα-Dazoacetates with Thioketene" Bull.Chem.Soc.Jpn. 1393-1400 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Iyoda, L. Zhao, H. Matsuyama: "Synthesis of Pentacarbonyl (1-oxazulen2-ylidene) chromium (0) and -tungsten (0) Complexes" Tetraheron Lett.36. 3699-3702 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Ptsudo, S. Inoue, H. Jigami, F. Ogura: "Synthsis structure and polymerization of 2, 2-bitellurophene" Synthetic Metals. 69. 537-538 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. O., K. M., K. A., Y. I., M. Oda: "Pareparations and Spin-Spin Interaction of 4,4'- (m-Phenylene) bis (1-Methyl-2, 6-Diphenylpyridenvl) and its Analogue" Tetrahedron lett.36. 6689-6692 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. K., G. H., M. T., T. F., M. S., T. A., A. Sugimori: "Electrophilic and Radical Substitution of 1, 2, 5-Cobaltadithiolenes" J. AM. Chem. Soc.(1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Matano, M. Yoshimune H. Suzuki: "Electrophilic Allylation of Arenes with in situ Generated Allyltiarylbismunium Compounds: The Bismuth-Mediated Polarity Inversion of Allylsilanes" Tetrahedron lett.36. 7475-7478 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Naota, N. Hirai, S. Murahashi: "Aerobic Ozidation of Alcohols with Ruthenium-Cobalt Bimetallic Catalyst in the Presence of Aldehydes" J. Org. Chem.58. 7318-7319 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Unno, H. Shioyama, M. Ida, H. Matsumoto: "Reductive dehalogenation of 4, 8-Dihalooctakis (1, 12-trimethylpropyl) tetracvclo [3, 3, 0, 0^<2.7> 0^<3.6>] octasilanes with sodium: Formation of Octasilacubane" Organometallics. 14. 4004-4009 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] L. Zhang, C. Kabuto, H. Sakurai, M. Kira: "Synthesis and Structure of Hezacoordinate Organosilicon Compounds Having Tropolonato Ligands" Chemistry Lett.659-660 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] W. Ando, T. Akasaka: "Photochemical [2+3] Cycloaddition of C_<60> with Disiliranes'" J. Am. Chem. Soc.115. 10366-10367 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Akasaka, S. Nagase: "A theiretical study of C_<80> and La_2@C_<80>" Chem.Phys.Lett.245. 230-236 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Matsumoto, R. Okazaki N. Tokitoh: "Formation and reactions of the First Diarylgermanone Stable in Solutin" Chemstry Lett.1087-1088 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Nanji, C. Kabuto, H. Sakurai, A. Sekiguchi: "Preparation of (Pentamethyldisilany) lithium and Two Isomers of (Heptamijethyltrisilanyl) lithium. Structural Characterrization of (Ch_3)_5Si_2I_1i'" Organometallics. 14. 2630-2632 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] W.Ando: "Polyoraganosilicon Compounds in Wtrained Carbocyclic Systems" Bull.Chem.Soc.Jpn. 69. 1-16 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Kimura, H.Nakayama, N.Furukawa: "Highly Diastereoselective Ozidation of 1-Alkylsufinyl-9- (Alkythio) dibenzothiophene with MCPBA in the presence of Trifluoroboran Etherate" Heterocycles. 42. 71-74 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Naka, S.Okazaki, M.Havashi, M.Ishikawa: "Silicon-carbon unsaturated compounds LIV : Nickel-catalyzed reactions of 3,4-binzo-1,1,2,2-tetraethyl-1,2-disilacycobut-3-ene with alkynes" J.Organ.Chem.35-41 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Nakano, T.Ibata: "The Rhodium (II) Acetate-Catalyzed Reaction of Alkenyl and Alkynylalpha-Dazoacetates with Thioketene" Bull.Chem.Soc.Jnp. 1393-1400 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Iyoda, L.Zhao, H.Matsuyama: "Synthesis of Pentacarbonyl (1-oxazulen2-ylidene) chromium (O) and -tungsten (o) Complexes" Tetrahedron Lett'.36. 3699-3702 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Otsubo, S.Inoue, H.Jigami, F.Ogura: "Synthsis, structure and Polymerization of 2,2-bitellurophene" Synthetic Metals. 69. 537-538 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.O., K.M., K.A., Y.I., M.Oda: "Pareparations and Spin Ineraction of 4,4'- (m-phenylene) bis (1-Methyl-2,6-Diphenylphridenvl) and its Analogue" Tetrahedron Lett.36. 6689-6692 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.K., G.H., M.T., T.F., M.S., T.A., A.Sugimori: "Electrophilic Allylation of Arenes with in situ Generated Allyltiarylbismunium Compounds : The Bismuth-Mediated Polarity Inversion of Allylsilanes" J.AM.Chem.Soc.(1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Unno, H.Shioyama, M.Ida, H.Matsumoto: "Reductive dehalogenation of 4,8-Dihalooctakis (1,12-trimethylpropyl) tetracvclo 3,3,0.0 octasilanes with sodium : Formation of Octasilacubane" Organometallics. 14. 4004-4009 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Naota, N.Hirai, S.Murahashi: "Aerobic Ozidation of Alcohols with Ruthenium-Cobalt Bimetallic Catalyst in the Presence of Aldehydes" J.Org.Chem.58. 7318-7319 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] W.Ando, T.Akasaka: "Photochemical [2+3] Cycloaddition of C_<60> with Disiliranes" J.Am.Chem.Soc.115. 10366-10367 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Akasaka, S.Nagase: "A theiretical study of C_<80> and La_2 C_<80>" Chem Phys.Lett.245. 230-236 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Natsumot, R.Okazaki, N.Tokitoh: "Formation and reactions of the First Diarylgermanone Stable in Solution" Chemistry Lett.1087-1088 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Manji, C.Kabuto, H.Sakurai, A.Sekiguchi: "Preparation of (Pentamethyldisilany) lithium and Two Isomers of (Heptami jethyltrisilanyl) lithium. Stractural Characterrization of (CH) Si Li" Organometallics. 14. 2630-2632 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] W Ando: "Polyorganosilicon Compounds in Strained Carbocyclic Systems" Bull. Chem. Soc. Jpn.69. 1-16 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Kimura, H. Nakayama, N. Furukawa: "Highly Diastereoselective Oxidation of 1-Alkylsulfinyl-9-(Alkylthio) dibenzothiophene with MCPBA in the presence of Trifluoroboran Etherate" Heterocycles. 42. 71-74 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] A Naka, S. Okazaki, M. Hayashi, M. Ishikawa: "Silicon-carbon unsaturated compounds LIV:Nickel-catalyzed reactions of 3, 4-binzo-1, 1, 2, 2-tetraethy1-1, 2-disilacyclobut-3-ene with alkynes" J. Orgno. Chem.35-41 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Nakano, T. Ibata: "The Rhodium (II) Acetate-Catalyzed Readction of Alkenyl and Alkynyl α-Dazoacetates with Thioketene" Bull. Chem. Soc. Jpn.1393-1400 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Iyoda, L. Zhao, H. Matsuyama: "Synthesis of Pentacarbonyl (1-oxazulen2-ylidene) chromium (0) and-tungsten (0) Complexes" Tetrahedron Lett.36. 3699-3702 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Otsubo, S. Inoue, H. Jigami, F. Ogura: "Synthesis, structure,and polymerization of 2, 2′-bitelluroohene" Shnthetic Metals. 69. 537-538 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. O., K. M., H. M., K. A., Y. I., M. Oda: "Pareparations and Spin-Spin interactions of 4,4′-(m-Phenylene) bis (1-Methyl-2, 6-Diphenylpyridinyl) and its Analogue" Tetrahedron lett. 36. 6689-6692 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. K., G. H, M. T., T. F., M. S., T. A., A. Sugimori: "Electrophilic and Radical Substitution of 1, 2, 5-Cobaltadithiolenes" J. Am. Chem. Soc.(1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y. Matano, M. Yoshimune, H. Suzuki: "Electrophilic Allylation of Arenes with in situ Generated Allyltriarylbismunium Compounds : The Bismuth-Mediated Polarity Inversion of Allylsilane" Tetrahedron lett.36. 7475-7478 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Naota, N. Hirai, S. Murahashi: "Aerobic Oxidation of Alcohols with Ruthenium-Cobalt Bimetallic Catalyst in the Presence of aldehydes" J. Org. Chem.58. 7318-7319 (1993)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Unno, H. Shioyama, M. Ida, H. Matsumoto: "Reductive dehalogenation of 4,8-Dihalooctakis (1,12-trimethylpropyl) tetracvclo [3.3.0.0^<2.7>.0^<3.6>] octasilanes with sodium:Formation of Octasilacubane" Organometallics. 14. 4004-4009 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] L. Zhang, C. Kabuto, H. Sakurai, M. Kira: "Synthesis and Structure of Hexacoordinate Organosilicon Compounds Having Tropolonato Ligands" Chemistry Lett.659-660 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] W. Ando, T. Akasaka: "Photochemical[2+3]Cycloaddition of C_<60> with Disiliranes^1" J. Am. Chem. Soc.115. 10366-10367 (1993)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Akasaka, S. Nagase: "A theiretical study of C_<80> and La_2OC_<80>" Chem. Phys. Lett.245. 230-236 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Matsumoto, R. Okazaki, N. Tokitoh: "Formation and reactions of the First Diarylgermanone Stable in Solution" Chemistry Lerr.1087-1088 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Nanji, C. Kabuto, H. Sakurai, A. Sekiguchi: "Prepartion of (Pentamethyldisilany) lithium and Two Isomers of (Heptamjjethyltrisilanyl) lithium.Structural Characterization of (CH_3)_5Si_2Li^1" Organometallics. 14. 2630-2632 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Akaska,B.Mitsuda,W.Ando,K.Kobayashi,S.Nagase: "Adduct of C_<60> at the Equatorial Belt:Photochemical Cycloaddition with Disilirane" J.Amer.Chem.Soc.116. 2627-2628 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] N.Furukawa: "The Pummerer and the Thio-Claisen-type Rearrangements of Naphtho[1.8-bc]-1.5-dithiocin Monooxide and N-p-Tosylsulfilimine" Heteroatom Chem.(in press).

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Kurata,T.Kawase,M.Oda: "Alkali Metal Reduction of Oligo-6-(2-thienyl)pentafulvenes.Synthesis of Oligothienylenemethines Attached with Cyclopentadienede Croups" Chemistry Lett.2219-2222 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Matano,N.Azuma,H.Suzuki: "Synthesis,X-Ray Structure and Reactions of (2-Oxoalkyl)triarylbismuthonium Salts" J.Chem.Soc.Perkin Trans.1. 1739-1747 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Tomioka,H.Okada,T.Watanabe,K.Hirai: "An Extremely Long-Lived Triplet Carbene;Reactivity,Optical Absorption Spectrum,and Kinetics of Highly Congested Diarylcarbenes" Angew.Chem.Int.Ed.Engl.33. 873-875 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Takahashi,S.M.,K.W.T.Suzuki,T.Miyashi: "Cycloreversion of Arene Endoperoxides Induced by Electron Transfer" J.Chem.Soc.Chem.Commun.13-14 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Nagao: "New Intramolecular Spiro-Endo-Mpde Ring Closure of Allenyl (Methoxy-Substituted Phenyl)alkyl Ketones" Tetrahedron Lett.(in press).

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Iyoda: "Synthesis of Pentacarbonyl(1-oxazulen-2-ylidene)chromium(0) and -tungsten(0)complexes" Tetrahedron Lett.36(in press). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Nagase,K.Kobayashi: "Theoretical Study of the Dimetallefullerene SC_2 C_<84>" Chem.Phys.Lett.231. 319-324 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Inoue,T.Jigami,H.N.,T.O.,F.Ogura: "2,2^1-Bitelluropgene and 2,2^1:5^1,2^<11>-Tertellurophene as Novel High Homologues of Telluropgene" Tetrahedron Lett.35. 8009-8012 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Unno,A.Kyushin,H.Matsumoto: "Ring-Opening Reaction of Octakis(1,1,2-trimethylpropyl)octasilacubane:Chlorination with PCl_5 Leading to Stereoisomeric 4,8-Dichloroota-" Organometallics. 13. 4633-4640 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Miyashita,M.Hotta,Y.Saida: "Selective sp C-H bond activation of alkylaromatics promoted by platinum complexes" J.Organo.Chem.473. 353-358 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Kajitani,A.Sugimori: "Photochemical Reactions of Several Adducts of Metalladithiolens and Metalladithiazoles-Dissocioation and Rearrangement" Coord.Chem.Revs.132. 175-180 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Kimura,Y.Sawaki: "Electrocatalyzed Reaction of Aldehydes with Trialkoxysilanes" Denki Kagaku. 62. 1119-1124 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Sekiguchi: "官能性シクロテトラゲルマンおよびはしご形ポリゲルマンの合成と構造" 日本化学会誌. 248-252 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Suzuki,N.Tokitoh,R.Okazaki: "A Novel Reactivity of a Silylene:The First Examples of [1+2]Cycloaddition with Aromatic Compounds" J.Am.Chem.Soc.116. 11572-11573 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Murahashi,Y.Imada,H.Ohtake: "Tungstate-Catalyzed Cecarboxylative Oxidation of N-Alkyl-a-amino Acids:An efficient Method for Regioselective Synthesis" J.Org.Chem.59. 6170-6172 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Murahashi,T.Naota: "Pergamon Press,Oxford,E.W.Abel,F.G.A.Stone,G.Wilkinson,eds" Comprehensive Orgfanometallic Chemistry II. (in press).

    • Related Report
      1994 Annual Research Report
  • [Publications] Toshiyuki Ohtaki,Yoshio Kabe,Wataru Ando: "Synthesis,Structure and Photoreaction of Bis(germanimines)" Organometallics. 13. 434-435 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Kusukawa,Y.Kabe,W.Ando: "Transition Metal Catalyzed Reaction of Peralkylated 3,4-(alkylidene)-1,2-disilacyclobutane" Chemistry Letters. 985-988 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] H.Fujihara: "Three-center Selenium Interaction in Electrochemical Oxidation of a Linear Trisselenide" Chemistry Letters. 619-622 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] J.Ohshita,H.Hasebe,Y.Masaoka,M.Ishikawa: "Silicon-Carbon Unsaturated Compounds 49.Nickel-Catalyzed Reactions of Adamantyl-2-(trimethylsiloxy)-1,1-bis(trimethyl)Silene" Organometallics. (in press). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Hirofumi Nakano: "The Rhodium(II)Acetate-Catalyzed Reaction of Diacyldiazomethanes with Isothiocvanates:Formation of 2-Thioxo-2H-1,3-oxazin-4(3H)-one" Bull.Chem.Soc.Jpn.66. 238-244 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Toshikazu Ibata: "Formation and Reaction of Azomethine Ylide by the Reaction of Cu(acac)_2-Ketocarbenoids with 1,1-Diphenylmethanimine" Chemistry Letters. 81-84 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masato Yoshida: "Reaction of C_<60> with Diacyl Peroxides Containing Perfluoroalkyl Groups.The First Example of Electron Transfer Reaction via C_<60>" Tetrahedron Letters. 34. 7629-7632 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Masahiko Iyoda: "Synthesis of the Tris(9-fluorenylidene)cyclopropane Dianion and Related Dianions:[3]Radialenes with Novel Electronic Properties" Angew.Chem,Int.Ed.Engl.32. 89-90 (1993)

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      1993 Annual Research Report
  • [Publications] Masahiko Iyoda: "Synthesis of (1,5-Diazabicyclo[4.3.0]nonan-2-ylidene)pentacarbonylchromium and -tungsten Using Reaction of Carbene Complex" Chemstry Letters. (in press). (1994)

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      1993 Annual Research Report
  • [Publications] A.Oku et al: "Reaction of Carbenes with Cyclic ethers in the Presence of Nucleophiles.A Three-Component Coupling Reaction" Acta Chemica Scandinavica. 47. 391-397 (1993)

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      1993 Annual Research Report
  • [Publications] T.Katsuhira: "Reaction of Propargylic Substrates with triorganozincates.A Novel Method for the Preparation of Allenic Zinc Reagents" Journal of Organic Chemistry. 58. 6166-6168 (1993)

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      1993 Annual Research Report
  • [Publications] Takahiro Fukumoto: "Syntheses of β-Amidovinyltellurides and Oxazoles by Addition Reactions of Alkynes with Benzenetellurinyl Trifluoromethanesulfonate in Acetonitrile" Heteroatom Chemistry. 4. 511-516 (1993)

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      1993 Annual Research Report
  • [Publications] Masaki Irie: "Sythesis of Optically Active Tellurium-Containing Binaphthyls and Their Use in the Asymmetric 1,4-Addition of α,β-Unsaturated Kitones" Tetrahedron Asymmetry. 4. 2127-2130 (1993)

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      1993 Annual Research Report
  • [Publications] Masaji Oda: "Regioselective Lethiations of Di(2-thienyl)methane:A Celean Kinetic and Thermodynamic Controlin Lithiation" Tetrahedron Letters. 4. 8143-8146 (1993)

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      1993 Annual Research Report
  • [Publications] S.Tsuji: "Phosphadioxirane Intermediates in the Reaction of Singlet Oxygen with Phosphites and Phosphines" J.Org.Chem.58. 5055-5059 (1993)

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      1993 Annual Research Report
  • [Publications] K.Takagi: "Controlled Photocycloaddition of Unsaturated Carboxylates Intercalated In Hydrotalcite Clay Interlayers" J.Am.Chem.Soc.115. 4339-4344 (1993)

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      1993 Annual Research Report
  • [Publications] Akira Sugimori: "Formation and Photochemical and Thermal Reactions of Adduct between 1,2,5,3-Cobaltadithiazole and Dimethyl Acethlendicarboxlate" Chem.Lett.1994. 473-476 (1994)

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      1993 Annual Research Report
  • [Publications] Akira Sugimori: "Photochemical Reactions of Several Adducts of Metalladithiolenes and Metalladithiazones-Dissociation and Rearrangement" Coord.Chem.Rev.(in press).

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      1993 Annual Research Report
  • [Publications] Akira Sugimori: "A Novel Metallacycle,1,2,5,3-Cobaltadithiazole.Formation,Structure and Properties of (Cp)(phenylmethanimine-N.1-dithiolato)cobalt(III)" J.Organomet.Chem.(in press).

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      1993 Annual Research Report
  • [Publications] Hitomi Suzuki: "Synthesis and First X-ray Analysis of a atabilized Chiral Chlorobismuthine Fixation of Molecular Geometry Induced by the Intramolecular Coordination of a Sulfonyl Group" J.Chem.Soc.,Perkin Trans.1. 1169-1175 (1993)

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      1993 Annual Research Report
  • [Publications] Hitomi Suzuki: "Chiral Chlorobismuthines Stabilized by the Intramolecular Coordination of an N,N-Dimethylamino Group.X-ray Structure Analysis,Asymmetric Induction at Bismuth Center,Dynamic Behaviour in Solution" J.Chem.Soc.,Perkin Trans.1. 2969-2973 (1993)

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      1993 Annual Research Report
  • [Publications] Y.Nagao: "New Intramolecular Five-Endo-Mode Cyclization of Allenyl Aryl Ketones" Chemistry Letters. 389-392 (1994)

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      1993 Annual Research Report
  • [Publications] Y.Nagao: "New six-to Eight-Membered-Ring Formation Based on the Intramolecular Endo Mode Ring Closure of Allenyl(Substituted Phenyl)alkyl Ketones" Chemistry Letters. 597-600 (1994)

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      1993 Annual Research Report
  • [Publications] S.Nagase: "Metallotullerenes MC_<82>(M=Sc,Y,and La).A Theoretical Study of the Electronic and Structural Aspects" Chem.Phys.Lett.214. 57-63 (1993)

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      1993 Annual Research Report
  • [Publications] S.Kyushin: "Selective Si-Si Bond Cleavage in Decaisopropylbicyclo[2,2,0]hexasilane.A Route to Sterically Hindered 1,4-dichlorocyclohexasilanes" Chemistry Letters. 221-224 (1994)

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      1993 Annual Research Report
  • [Publications] H.Ikeda: "Substitution Effects on Regioselective Cyclizations of 1,5-and 2,4-Diphenyl-1,5-hexadiene Cation Radicals" Tetrahedron Lett.34. 2323-2326 (1993)

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      1993 Annual Research Report
  • [Publications] H.Ikeda: "The Cation Radical Cope Rearrangement of 2,5-Diphenyl-1,5-hexadienes under Electron Ionization" J.Chem.Soc.,Chem.Commun.367-369 (1993)

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      1993 Annual Research Report
  • [Publications] Y.Takahashi: "Electron Transfer Photochemisty of Endoperoxides" J.Chem.Soc.,Perkins.2. 243-253 (1993)

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      1993 Annual Research Report
  • [Publications] M.Kira: "Extraordinary Large Red Shift of the n(Si)→3p(Si) Transition of Silylenes Caused by Trimethylsilyl and Trimethylgermyl Substituents" Chem.Lett.1345-1348 (1993)

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      1993 Annual Research Report
  • [Publications] A.Miyashita,M.Hotta,Y.Saida: "Selective Sp^3 C-H Bond Activation of fAlkylaromatics by Platinum Complexes" J.Organomet.Chem.(in press). (1994)

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      1993 Annual Research Report
  • [Publications] N.Tokitoh: "The First Stable Stannaethione in Solution Dirived from a Kinetically Stabilized Diarylstannylene" J.Am.Chem.Soc.115. 2065-2066 (1993)

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      1993 Annual Research Report
  • [Publications] M.Kira: "Trialkyltin Cation in solution" J.Organomet.Chem.(in press), (1993)

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      1993 Annual Research Report
  • [Publications] 宮下 晃: "季刊 化学総説「前周期遷移金属の有機化学」 (分担)" 学会出版センター, 207 (1993)

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      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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