| Project/Area Number |
05402041
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| Research Category |
Grant-in-Aid for General Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Electronic materials/Electric materials
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| Research Institution | AICHI INSTITUTE OF TECHNOLOGY |
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Principal Investigator |
IEDA Masayuki A.I.T., Dept.of Electrical Eng., Professor, 工学部, 教授 (50022984)
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| Co-Investigator(Kenkyū-buntansha) |
MAEDA Akinori A.I.T., Dept.of Electrical Eng., Associate Professor, 工学部, 講師 (40078910)
OCHIAI Shizuyasu A.I.T., Dept.of Electrical Eng., Professor, 工学部, 教授 (10078909)
UCHIDA Yoshiyuki A.I.T., Dept.of Information Network Eng., Pro, 工学部, 教授 (20023187)
KOJIMA Kenzou A.I.T., Dept.of Electrical Eng., Professor, 工学部, 教授 (30064942)
OHASHI Asao A.I.T., Dept.of Electrical Eng., Professor, 工学部, 教授 (20023244)
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| Project Period (FY) |
1993 – 1994
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| Project Status |
Completed (Fiscal Year 1994)
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| Budget Amount *help |
¥27,100,000 (Direct Cost: ¥27,100,000)
Fiscal Year 1994: ¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 1993: ¥19,400,000 (Direct Cost: ¥19,400,000)
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| Keywords | Nonlinear Optical Thin Film / Substrate interface / Molecular Beam Epitaxy (MBE) / Vanadyl Phthalocyanine / Mica / Second-order Nonlinear Optical Thin Film / X ray Photoelectron Spectroscopy (ESCA) / X Ray Diffraction (XRD) / 非線形光学材料 / VOPc薄膜のX線光電子分光 / 最適蒸発源温度 / エピタキシキシャル成長 / 溶融石英基板 / マイカ基板 / 基板 / 薄膜界面の強い相互作用 / 化学シフト |
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| Research Abstract |
The orientations of the VOPc plate pressed at 1ton/cm^2 and VOPc thin film produced under Tp : 200ﾟC,Ts : 200ﾟC and te : 190 min by MBE method were investigated by X-ray diffraction. The X-ray diffraction pattern of the VOPc plate pressed at 1ton/cm^2 shows a lot of peaks along diffraction angle. This means that the VOPc plate pressed at 1ton/cm^2 is formed with many random orientation. In the VOPc thin film produced by MBE method, two peaks which are not observed in the X-ray diffraction spectrum for the muscovite subsutrate, markedly exist from these data. This means that the distances between VOPc molecules are estimated as 3 A and 3.8 A.The VOPc molecule is a plane molecule having a triangular structure with 14A as a base line length. These indicate that each molecule in the VOPc thin film is oriented in parallel to the substrate. These results support the existence of strong interaction between VOPc thin film/muscovite interface observed by ESCA.Detailed explanation for the existence of two kinds of parallel orientation on the muscovite is under investigation.
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