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Stereochemistry of Octahedral Silicon (IV) Complexes

Research Project

Project/Area Number 05403009
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionOkazaki National Research Institutes (1994-1995)
Okayama University (1993)

Principal Investigator

YOSHIKAWA Yuzo  Okazaki National Research Institute, Coordination Chemistry Laboratories, 分子科学研究所, 教授 (30022643)

Co-Investigator(Kenkyū-buntansha) KURODA Yasushige  Okazaki National Research Institute, Coordination Chemistry Laboratories, 分子科学研究所, 助手 (40116455)
KOJIMA Masaaki  Fuculty of Science, Okayama University, Department of Chemistry, 理学部, 助教授 (20022725)
Project Period (FY) 1993 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥34,200,000 (Direct Cost: ¥34,200,000)
Fiscal Year 1995: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1994: ¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 1993: ¥26,600,000 (Direct Cost: ¥26,600,000)
KeywordsOctahedral Silicon Complex / Six-coordinate Silicon Complex / High-coordinate Silicon Complex / Stereochemistry
Research Abstract

Higher (than four)-coordinated complexes of silicon (IV) are not very familiar as compared to four-coordinated tetrahedral compounds.
We already reported the complete optical resolution and the properties of [Si (phen)_3]^<4+>. The resoluion of [Si (phen)_3]^<4+> was performed by a liquid column chromatographic method using SP-Sephadex C-25 as an adsorbent and a 0.08 M potassium bis ((+)-tartrato) diantimonate (III) as an eluent. Each enantiomer is so stable in an aqueous that solution the absorption spectrum and optical rotation were unchanged after a month at room temperature. This is the first example of stable (in water) enanntiomers of six-coordinated octahedral silicon (IV) complexes.
Successively the ion-association contants between the optically-active complex cations (LAMBDA- or DELTA-[Si (phen)_3]^<4+>) and the aforementioned resolving agent anions ([Sb_2{(+)-tart}_2]^<2->, tart=tartrate(4-) ion) were determined spectrophotometrically. The ion association between the complex ca … More tion and the resolving agent anions occurred in two steps and the stereoselective interaction was observed in the second step. The second-step association constant for the LAMBDA-enantiomer (KAPPA_2=1.41*10^3) is larger than that for the DELTA-one (KAPPA_2=1.07*10^3). The second-step association plays a dominant role in determining the elution order in column-chromatographic resolution.
The molecular mechanics calculations for the ion-associated species were performed to obtain the information about the microscopic interaction between the ions. The total strain energy for the species containing the LAMBDA-enantiomer is smaller than that containing the DELTA-one and this result can explain the experimental finding that the LAMBDA-enantiomer is eluted faster than the DELTA-one.
In the present study, the optical resolution of [Si (bpy)_3]^<4+> was also attempted by a chromatographic method using an SP-Sephadex C-25 column and various resolving-agent solutions, sodium (+)-bitartrate (NaHtart), sodium (+)-tartrate (Na_2tart), potassium bis ((+)-tartrato) diantimonate (III)(K_2[Sb_2{(+)-tart}_2), and sodium (2R,3R)-O,O'-dibenzoyltartrate (Na_2(benz)_2tart) as eluents. This faster-moving enantiomer was LAMBDA except the DELTA moved faster for K_2[Sb_2{(+)-tart}_2]. However, the complete resolution (i.e.the complete separation of the elution band) was attained only by the use of an aqueous solution (0.16 M) of sodium (2R,3R)-O,O'-dibenzoyltartrate as the elunt.
We carried out the force-field calculations of the above ion-pair systems and elucidated the chromatographic elution mechanism.
This study was developed to syntheses and stereochemistry of the other higher-coordinated silicon (IV) compounds containing Schiff Bases and Hinokitiolate.
At present the stereoselective formation is being investigated about the silatrane derivatives having L-alaninol and L-valinol skeletons. Less

Report

(4 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • Research Products

    (84 results)

All Other

All Publications (84 results)

  • [Publications] Y. Kuroda: "Structural Characterization of Adsorbed Dinitrogen on Copper-Ion-Exchange Mordenitethrough XAFS Measurements" Jpn. J. Apple Phys.32. 493-495 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S. Emura: "Coordination of Cr^<3+> Ions in α-Al_2O_3" Jpn. J. Appl. Phys.32. 734-736 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 黒田泰重: "単結晶酸化物表面の吸着種の結合状態" 化学と工業. 46. 1748-1749 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Heat of Adsorption of Water on SrF_2 : Relation to Two-deimensional Condensation of Water adsorbed on SrF_2" J. Chem. Soc., Faraday Trans.89. 2041-2048 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] P. S. K. Chia: "Synthesis and Characterization of Cobalt Cyclidene Complexes with Long Polymethylene Bridges and Their Binding to Small Molecules" Inorg. Chem.32. 2736-2744 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S. Kittaka: "Dynamic Properties of Monolayer Water Molecules on the lonic Crystalline Surfaces." KENS Report-X. 71- (1993 1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F. M. Akhter: "Photolysis of trans(t-N, S)-[Co{S(O)_2CH_2COO-S,O}(tren)]^+(t-N=tertiary aminnitrogeri tern=tris(2-aminoethyl)amine), Linkage and Geo metrical Isomerization" Chem. Lett.1994. 171-174 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Kojima: "Synthesis of trans(N)-Carbonatobis(N, N-dimethylglycinato)Cobaltate(III) by Decarboxylation of N, N-Dimethylglycine" Bull. Chem. Soc. Jpn.67. 108-112 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Kojima: "A Photochemically Prepared O-Bonded Sulfinato Complex of Cobalt(III). Optical Resolution and X-Ray Structure of (2-Aminoethanesulfinato-O, N)[tris(2-amonoethyl)amine] cobalt(III)" Bull. Chem. Soc. Jpn.67. 108-112 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] D. H. Busch: "Dioxygen Adducts of Lacunar Cobalt(II) Cyslidene Complexes" Inorg. Chem.33. 910-923 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Kojima: "Green and Orange Crystalline Forms of [VO{N-salycylidene-N' -3-ethoxysalicy lidene-(R, R)-1, 2-cyclohexanediamine}], Separation of the Diastereomeric Pair, and Isomerization between Them in the Solid State" Chem. Lett.1994. 949-952 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Nakajima: "Isomerization of a Diastereomeric Oxovanadium(IV) Complex Containing an Un-symmetrical Tetradentate Schiff Base Ligand Catalyzed by Oxovanadium(V) Species" Chem. Lett.1994. 1593-1596 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Kojima: "Photochemistry of Tris(L-cysteinesulfinato-N, S)cobaltate(III). Linkage Isomerization from Sulfinato-Sto Sulfinato-O" Proc. Japan Acad.70B. 101-105 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Hirotsu: "Steric Cotrol of Redox Potentials of Cobalt(II) Schiff Base Complexes with Phenyl Substituents" Chem. Lett.1994. 2183-2186 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F. M. Akhter: "Photochemical Reaction of(L-cysteinesulfinato-N, S) {tris(2-aminoethyl) amine}-cobalt(III). Formation of a Cabalt(III) Complex with an Uncoordinated Sultinate group" Chem. Lett.1994. 2393-2396 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 黒田泰重: "誘電率測定による水の吸着状態の研究" Adsorption News. 9. 4-8 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Dielectric Behavior in the SrF_2-H_2O System. 1. Measurement at Room Temperature" Langmuir. 11. 259-264 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Dielectric Behavior in the SrF_2-H_2O System. 2. Measurement at Low Temperature" Langmuir. 11. 2173-2178 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Kojima: "Characterization of Monomeric Green and Polymeric Orange Forms of a Schiff Base-Oxovanadium(IV) Complex and Interconvesion between" Proc. Japan. Acad.71B. 175-178 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Nagao: "Calorimetric Study of Water Two-dimensionally Condensed on the Homegeneous Surface of a Solid" Thermochimica Acta. 253. 221-233 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Specific Feature of Copper-Ion-Exchanged Mordenic for Dinitrogen Adsorption at Room Temperature" J. Phys. Chem.99. 10621-10628 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Desorption Phenomenon of Adsorbed Water on Homogeneous SrF_2 Surface at Lower Temperatures" Langmuir. 11. 4031-4035 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Hirotsu: "Manganese(III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands. Effect of Phenyl Substituents" Inog. Chem.34. 6173-6178 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Nakashima: "Chiral Recognition in the Electron-Transfer Reaction between Optically Active Schiff Base-Oxovanadium(IV) and-Oxovanadium(V) Complexes" Chem. Lett.1995. 1017-1018 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F. MD. Akhter: "Photochemical Desulfurization of a Sulfinate-S-Cobalt(III) Complex. Formation of an Organic Peroxide Complex" Chem. Lett.1995. 81-82 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Stabilization of Copper Metal Clustersin Mordenite Nanopores : Water Treatment of Evacuated Copper-Ion-Exchanged Mordenite at 300K" Photon Factory Activity Report. 1995. (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Yoshii: "Force Field Caluclations of Antitumor Platinum(II) Complex Systems" J. Coord. Chem.(1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Kuroda: "Dielectric Behavior in the Y_2O_3-H_2O System at Lower Temperatures : In Comparison with Desorption Phenomenon of Adsorbed H_2O in the SrF_2-H_2O System Temperatures" Langmuir. (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F. MD. Akhter: "Photochemistry of Cobalt(III) Complexes Containing a Sulfinate-S Ligand. Linkage and Geometrical Isomerization" J. Coord. Chem.(1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y. Ohmori: "Chromatographic Resolution Mechanism of Tris (1,10-phenanthroline) silicon(IV) Complex" J. Coord. Chem.(1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S. Utsuno: "Solid-State Circular Dichroism Spectra of trans-Diamminetetranitrocobaltate(III) Salts and mer Triamminetrinitrocobalt(III)" Inorg. Chim. Acta. (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, S.Konno, H.Maeda, and Y.Yoshikawa: "Structural Characterization of Adsorbed Dinitrogen on Copper-Ion-Exchange Mordenite through XAFS Measurements" Jpn.J.Appl.Phys.32. 493 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Emura, H.Maeda, Y.Kuroda, and T.Murata: "Coordination of Cr^<3+> Ions in alpha-Al_2O_3" Jpn.J.Appl.Phys.32. 734 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, T.Matsuda, and M.Nagao: "Heat of Adsorption of Water on SrF_2 : Relation to Two-deimensional Condensation of Water Adsorbed on SrF_2" J.Chem.Soc., Faraday Trans.89. 2041 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] P.S.K.Chia, M.Masarwa, P.R.Warburton, W.Wu, M.Kojima, D.Nosco, N.W.Alcock, and D.H.Busch: "Synthesis and Characterization of Cobalt Cyclidene Complexes with Long Polymethylene Bridges and Their Binding to Small Molecules" Inorg.Chem.32. 2736 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Kittaka, Y.Kuroda, M.Nagao, T.Yamaguchi, M.Yamagami, and K.Shibata: "Dynamic Properties of Monolayr Water Molecules on the Ionic Crystalline Surfaces" KENS Report-X. 1993. 71 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F.MD.Akhter, M.Kojima, T.Yoshii, S.Kashino, and Y.Yoshikawa: "Photolysis of trans (t-N,S)-[Co{S (O)_2CH_2COO-S,O}(tren)]^+(t-N=tertiary amine nitrogen ; tren=tris (2-aminoethyl) amine), Linkage and Geometrical Isomerization" Chem.Lett.171 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.KOjima, R.Saito, K.Nakajima, Y.Ouyang, and J.Fujita: "Synthesis of tarns (N)-Carbonatobis (N,N-dimethylglycinato) cobaltate (III) by Decarboxylation of N,N-Dimethylglycine" Bull.Chem.Soc.Jpn.67. 108 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kojima, Y.Shimizu, K.Nakajima, and Y.Yoshikawa: "A Photpchemically Prepared O-Bonded Sulfinato Complex of Cobalt (III). Optical Resolution and X-Ray Structure of (2-Aminoethanesulfinato-O,N)[tris -amonothyl) amine]cobalt (III)" Bull.Chem.Soc.Jpn.67. 869 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] D.H.Busch, P.J.Jackson, M.Kojima, P.Chmielewski, N.Matsumoto, et al.: "Dioxygen Adducts of Lacunar Cobalt (III) Cyclidene Complexes" Inorg.Chem.33. 33 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kojima, K.Nakajima, M.Tsuchimoto, M.Tanaka, T.Suzuta, Y.Yoshikawa, and J.Fujita: "Green and Orenge Crystalline Forms of [VO{N-salycylidene-N'-3-ethoxysalicylidene-(R,R)-1,2-cyclohexanediamine}], Separation of the Diastereomeric Pair, and Isomerization between Them in the Solid State" Chem.Lett.949 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Nakajima, M.Kojima, M.Tsuchimoto, Y.Yoshikawa, and J.Fujita: "Isomerization of a Diastereomeric Oxovanadium (IV) Complex Containing an Un-symmetrical Tetradentate Schiff Base Ligand Catalyzed by Oxovanadium(V) Species" Chem.Lett.1593 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kojima, I.Sugimoto, Y.Shimizu, and Y.Yoshikawa: "Photochemistry of Tris (L-cystenesulfinato-N,S) cobaltate (III). Linkage Isomerization from Sulfinato-S to Sulfinato-O" Proc.Japan.Acad.70B. 101 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Hirotsu, M.Kojima, K.Nakajima, S.Kashino, and Y.Yoshikawa: "Steric Cotrol of Redox Potentials of Cobalt (II) Schiff Base Conplexes with Phenyl Substituents" Chem.Lett.2183 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F.M.Akhter, M.Kojima, M.Hirotsu, S.Kashino, and Y.Yoshikawa: "Photochemical Reaction of (L-cysteinesulfinato-N,S){tris (2-aminoethyl) amine}-cobalt (III). Formation of a Cpbalt (III) Complex with an Uncoordinated Sulfinate Group" Chem.Lett.2393 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, Y.Yoshikawa, T.Morimoto, and M.Nagao: "Dielectric Behavior in the SrF_2-H_2O System. 1. Measurement at Room Temperature" Langmuir. 11. 259 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, Y.Yoshikawa, T.Morimoto, and M.Nagao: "Dielectric Behavior in the SrF_2-H_2O System. 2. Measurement at Low Temperatures" Langmuir. 11. 2173 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kojima, K.Nakajima, M.Tsuchimoto, P.M.Treichel, S.Kashino, and Y.Yoshikawa: "Characterization of Monomeric Grenn and Polymeric Orenge Forms of a Schiff Base-Oxovanadium (IV) Complex and Interconversion between These Species" Proc.Japan Acad.71B. 175 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Nagao, R.Kumashiro, T.Matsuda, and Y.Kuroda: "Calorimetric Study of Water Two-dimensionally Condensed on the Homegeneous Surface of a Solid" Thermochimica Acta.253. 221 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, Y.Yoshikawa, S.Konno, H.Hamano, H.Maeda, R.Kumashiro, and M.Nagao: "Specific Feature of Copper-Ion-Exchanged Mordenite for Dinitrogen Adsorption at Room Temperature" J.Phys.Chem.99. 10621 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, Y.Yoshikawa, and M.Nagao: "Desorption Phenomenon of Adsorbed Water on Homogeneous SrF_2 Surface at Lower Temperatures" Langmuir. 11. 4031 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Hirotsu, K.Nakajima, M.Kojima, and Y.Yoshikawa: "Managenese (III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands. Effect of Phenyl Substituents" Inorg.Chem.34. 6173 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Nakajima, Y.Ando, M.Inamo, and M.Kojima: "Chiral Recognition in the Electron-Transfer Reaction between Optically Active Schiff Base-Oxovanadium (IV)and Oxovanadium (V) Complexes" Chem.Lett.1017 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, H.Hamano, H.Maeda, R.Kumashiro, Y.Kubozono, Y.Yoshikawa, and M.Nagao: "Stabilization of Copper Metal Clusters in Mordenite Nanopores : Water Treatment of Evacuated Copper-Ion-Exchanged Mordenite at 300 K" Photon Factory Activity Report. (in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F.MD.Akhter, M.Kojima, K.Nakajima, and Y.Yoshikawa: "Photochemical Desulfulization of a Sulfinate-S-Cobalt (III) Complex. Formation of an Organic Peroxide Complex" Chem.Lett.81 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Yoshii, M.Kojima, and Y.Yoshikawa: "Force Field Calculations of Antitumor Platinum (II) Complex Systems" J.Coord.Chem.(in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda, Y.Yoshikawa, H.Hamano, and M.Nagao: "Dielectric Behavior in the Y_2O_3-H_2O System at Lower emperatures : In Comparison with Desorption Phenomenon of Adsorbed H_2O in the SrF_2-H_2O System" Langmuir. (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] F.MD.Akhter, M.Hirotsu, I.Sugimoto, M.Kojima, S.Kashino, and Y.Yoshikawa: "Photochemistry of Cobalt (III) Complexes Containings a Sulfinate-S Ligand. Linkage and Geometrical Isomerization" Bull.Chem.Soc.Jpn.(in press). (1996)

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      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Ohmori, M.Kojima, S.Kashino, and Y.Yoshikawa: "Chromatographic Resolution Mechanism of Tris (1,10-phenanthroline) silicon (IV) Complex" J.Coord.Chem.(in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Utsuno, A.Suganuma, and Y.Yoshikawa: "Solid-State Circular Dichroism Spectra of trans-Diamminetetranitrocobaltate (III) Salts and mer-Triamminetrinitrocobalt (III)" Inorg.Chem.Acta.(in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Kuroda: "Dielectric Behavior in the SrF_2-H_2O System. 2.Measurement at Low Temperatures" Langmuir. 11. 2173-2178 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Kojima: "Characterization of Monomeric Green and Polymeric Orange Forms of a Schiff Base-Oxovanadium (IV) Complex and Interconversion between These Species." Proc.Japan Acad.71B. 175-178 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Nagao: "Calorimetric Study of Water Two-dimensionally Condenesd on the Homegeneous Surface of a Solid" Themochimica Acta. 253. 221-233 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kuroda: "Specific Feature of Copper-Ion-Exchanged Mordenite for Dinitrogen Adsorption at Room Temperature" J.Phys.Chem.99. 10621-10628 (1995)

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      1995 Annual Research Report
  • [Publications] Y.Kuroda: "Desorption Phenomenon of Adsorbed Water on Homogeneous SrF_2 Surface at Lower Temperatures" Langmuir. 11. 4031-4035 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Hirotsu: "Manganese (III) Complexes Containing Optically Active Tetradentate Schiff Base Ligands." Inorg.Chem.34. 6173-6178 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Nakashima: "Chiral Recognition in the Electron-Transfer Reaction between Optically Active Schiff Base-Oxovanadium (IV) and Oxovanadium (V) Complexes" Chem.Lett.1995. 1017-1018 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kuroda: "Stabilization of Copper Metal Clusters in Mordenite Nanopores : Water Treatment of Evacuated Copper-Ion-Exchanged Mordenite at 300 K" Photon Factory Activity Report,. in press (1995).

    • Related Report
      1995 Annual Research Report
  • [Publications] F.MD.Akhter: "Photochemical Desulfurization of a Sulfinate-S-Cobalt (III) Complex. Formation of an Organic Peroxide Complex" Chem.Lett.1996. 81-82 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Yoshii: "Force Field Calculations of Antitumor Platinum (II) Complex Systems" J.Coord.Chem.,. in press (1996).

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kuroda: "Dielectric Behavior in the Y_2O_3-H_2O System at Lower Temperatures : In Comparison with Desorption Phenomenon of Adsorbed H_2O in the SrF_2-H_2O System Temperatures21GC11:Langmuir," in press (1996).

    • Related Report
      1995 Annual Research Report
  • [Publications] F.MD.Akhter: "Photochemistry of Cobalt (III) Complexes Containing a Sulfinate-S Ligand. Linkage and Geometrical Isomerization" Bull.Chem.Soc.Jpn.in press (1996).

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Ohmri: "Chromatographic Resolution Mechanism of This (1,10-phenanthroline) silicon (IV) Complex" J.Coord.Chem.in press (1996).

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Utsuno: "Solid-State Circular Dichroism Spectra of trans-Diamminetetranitrocobaltate (III) Salts and mer-Triamminetrinitrocobalt (III)" Inorg.Chim.Acta. in press (1996).

    • Related Report
      1995 Annual Research Report
  • [Publications] 小島正明: "Green and Orange Crystalline Forms of [VO{N-Salicyliclene-N´-3-eisxysaticy tidene-(R,R)-1,2-cycls hexanediamine}],Separation of the Diastereomeric Pair,and Isomerization between Them in the Sdid State" Chemistr,Letters. 1994. 949-952 (1994)

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      1994 Annual Research Report
  • [Publications] 中島清彦: "Isomerization of a Diastereomeric Oxovanadium(IV)Compex Containing an Unsymmetrical Tetradentate Schiff Base Ligord Catclyzet in Oxovanadium(V)Species" Chemistry Letters. 1994. 1593-1596 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 小島正明: "Photochemistry of Tris(L-cysteinesulfinato-N,S)∞e=Ltate(III),Linkage Isomerisation from Sultinato-S to Sultinato-O" Proceedings of the Japan Academy. 70B. 101-105 (1994)

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      1994 Annual Research Report
  • [Publications] 広津昌和: "Steric Control of Redox Potentials of Cobalt(II)Schiff Base Conplexes with Pheny L Sebstitnents" Chemistry Letters. 1994. 2183-2186 (1994)

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      1994 Annual Research Report
  • [Publications] ファル-ク MD.アクタール: "Phstschemical Reaction of(L-cysteinesulfinato-N,S){tris(2-aminoethy L)amine}∞balt(III).Formation of a Cobalt(II)Csmplex with an Uncoordinated Sulfinate Gronp" Chemistry Letters. 1994. 2393-2396 (1994)

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      1994 Annual Research Report
  • [Publications] 黒田泰重: "Dielectric Bahavior in the SrF_2-H_2O System.1.Measurement at Room Temperature" Langmuir. 11. 259-264 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 黒田泰重: "Heat of Adsorption of Water on SrF_2:Relation to Two-dimensional Condensation of Water Adsorbed on SrF_2" Journal of the Chemical Society,Faraday Transaction. 89. 2041-2048 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] ファルーク MD.アクタール: "Photolysis of trans(t-N,S)-[Co{S(O)_2CH_2COO^-S,O}]^+(t-N=tertiary amine nitrogen;tren=tris(2-aminoethyl)amine),Linkage and Geometrical Isomerisation" Chemistry Letters. 1994. 171-174 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 小島正明: "A Photochemically Prepared O-bonded Sulfinato Complex of Cobalt(III).Optical Resolution and X-ray Struclure of(2-Aminoethanesulfinato-O,N)[tris(2-aminoethyl)amine]cobalt(III)" Bulletin of the Chemical Society of Japan. 67 (in press). (1994)

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      1993 Annual Research Report
  • [Publications] 山崎一雄: "錯体化学" 裳華房, 315 (1993)

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      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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