Oxidation Catalyzed by Polyoxometalate-Anion-Intercalated Layred Compounds
| Project/Area Number |
05453106
|
|---|
| Research Category |
Grant-in-Aid for General Scientific Research (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
触媒・化学プロセス
|
|---|
| Research Institution | The University of Tokyo |
|---|
Principal Investigator |
TATSUMI Takashi Univ.Tokyo, Fac.of Eng.Associate Professor, 工学部(試), 助教授 (30101108)
|
|---|
| Project Period (FY) |
1993 – 1994
|
| Project Status |
Completed (Fiscal Year 1994)
|
| Budget Amount *help |
¥6,300,000 (Direct Cost: ¥6,300,000)
Fiscal Year 1994: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1993: ¥3,500,000 (Direct Cost: ¥3,500,000)
|
|---|
| Keywords | Layred compound / Poly acid / Alkene / Oxidation / Aldehyde / Oxygen / Hydrogen peroxide / ハイドロタルサイト / アニオン交換 / インターカレーション / ミクロポア / モリブデン / タングステン |
|---|
| Research Abstract |
Layred double hydroxides (LDH) consisting of Mg-Al, Zn-Al, and Ni-Al with the atomic ratios varied were prepared, and intercalated with heteropolyoxometalate anions including Mo or W as the addenda atom. It has been found rather difficult to insert SiW_<12>O_<40>^<4-> into the layr space of Zn-Al LDH with the Zn/Al ratio of 2. However, the insertion was promoted with decreasing Al/Zn ratio, To avoid decomposition of polyoxometalate, the pH during the insertion was kept at lower than 4, where the Zn-Al LDH was more stable than the Mg-Al LDH.Zn-Al LDHs intercalated with silicotungstates SiW_<12>O_<40>^<4->, SiW_<11>O_<39>^<8->, and SiW_9O_<34>^<10-> were prepared and the structure of the anions in the gallery space was examined by infrared spectroscopy. The SiW_<11>O_<39>^<8-> intercalate proved to be a good catalyst for olefin epoxidation with H_2O_2 as oxidant. In contrast, the SiW_<12>O_<40>^<4-> intercalate was effective in epoxidizing olefins with O_2-aldehyde, although it showed poor activity in the epoxidation with H_2O_2 Substitution of V for W of the addenda atom resulted in enhancement of activity for epoxidation with O_2-aldehyde. The Ni-Al LDH with no polyoxometalate included exhibited considerable activity in olefin epoxidation with O_2-aldehyde. Thus it has been suggested that the introduction of active metals into both the LDH itself and the gallery space may lead to emergence of bifunctional catalysis, which would be applied to novel catalytic reactions.
|
Report
(3 results)
Research Products
(8 results)
-
-
-
-
[Publications] T.Tatsumi and K.Yamamoto: "Polyoxometalate-pillared Layred Double Hydroxides as Oxidation Catalysts" Advanced Materials '93, II,A : Biomaterials, Organic and Intelligent Materials, ed.H.Aoki, et al., Trans.Mat.Res.Soc., Jpn., Volume 15A,Elsevier, Amsterdam. 141-144 (1994)
Description
「研究成果報告書概要(欧文)」より
Related Report
-
-
-
-
