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Development of a Novel Multi-Functionalized System for Surface Reaction Analysis in Photo excited Epitaxy

Research Project

Project/Area Number 05554019
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 機能・物性・材料
Research InstitutionThe University of Tokyo

Principal Investigator

IWASAWA Yasuhiro  The University of Tokyo, Graduate School of Science, Professor, 大学院・理学系研究科, 教授 (40018015)

Co-Investigator(Kenkyū-buntansha) SASAKI Takehiko  The University of Tokyo, Graduate School of Science, Assistant, 大学院・理学系研究科, 助手 (90242099)
ONISHI Hiroshi  The University of Tokyo, Graduate School of Science, Assistant, 大学院・理学系研究科, 助手 (20213803)
有賀 哲也  東京大学, 大学院・理学系研究科, 講師 (70184299)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥9,500,000 (Direct Cost: ¥9,500,000)
Fiscal Year 1994: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1993: ¥7,500,000 (Direct Cost: ¥7,500,000)
Keywordsphoto induced epitaxy / electron stimulated desorption / reflection absorption infrared spectroscopy / scanning tunneling microscopy / solid surface / surface reaction / silicon / organometallic compound / 光励起選択エピタキシー / 角度分解刺激脱離イオン分光法 / 反射型赤外吸収分光法 / 飛行時間フーリエ変換型イオン分光器 / 表面吸着線
Research Abstract

The investigators developed a Time-of-Flight Fourier Transformed Ion Energy Analyzer for space-resolved and energy-resolved observation of products in electron-or photo-stimulated desorption. In the present project, a multi-functionalized ultrahigh vacuum system was built to observe the coordination, energy state, and structure of absorbed reaction intermediates, by combining the analyzer with an Reflection Absorption Infared Spectroscope (RAIRS) .
The RAIRS with a reaction chamber allowed us to observe in-situ surface reaction in atmospheric reactant ambient. The ion analyzer operated with pulsed electron beam enabled the detection of reaction intermediate in a time resolution as small as 20 ms.
As the developing the system, thermal and photo induced reaction of alkygallium compounds on a Si (111) - (7*7) surface was studied by scanning tunneling spectroscopy (STM) . The decomposition of individual trimethylgallium and triethylgallium molecule was imaged. The manipulation of adsorbed formate, a simple organic molecule, was also successfully examined on TiO_2 (110) .

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (31 results)

All Other

All Publications (31 results)

  • [Publications] Hiroshi Onishi: "Reconstruction of TiO_2 ( 110 ) Surface:STM Study with Atomic-Scale Resolution" Surface Science. 313. L783-L789 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "STM-Imaging of Formate Intermediates Adsorbed on a TiO_2 ( 110 ) Surface" Chemical Physics Letters. 226. 111-114 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope;Formate Anions on TiO_2 ( 110 ) Surface" Japanese Journal of Applied Physics. 33. L1338-L1341 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Observation of Anisotropic Migration of Adsorbed Organic Species Using Nanoscale Patchworks Fabricated with a Scanning Tunneling Microscope" Langmuir. 10. 4414-4416 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Takehiko Sasaki: "A Reactive Oxygen Adlayer on Cu ( 110 ) at 100K" Surface Science. 316. L1081-L1087 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐々木岳彦: "表面吸着種解析法としての電子刺激脱離法の最近の発展" 化学. 49. 450-451 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Junji Inukai: "Photochemical Decomposition of Triethylgallium on Si ( 111 ) Studied by Means of STM, LEED, AES and Mass Spectroscopy" Japanese Journal of Applied Physics. 32. 1768-1771 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Takehiko Sasaki: "HREELS Study on CO Adsorbed on Clean,Nitrided and Oxidized Fe/Ru ( 001 ) Surfaces" Surface Science. 291. 429-438 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ken-ichi Fukui: "Chemisorption of CO and H_2 on clean and oxygen-modified Mo ( 112 )" Surface Science. 281. 241-252 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Tetsuya Aruga: "Control of Methanol Reaction Pathway by Oxygen Adsorbed on Mo ( 112 )" American Chemical Society Symposium Series. 523. 110-121 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ken-ichi Fukui: "Novel Reaction Path Induced by Selective Blocking of Surface Atoms Methanol Dehydrogenation on Mo ( 112 )" Surface Science. 295. 160-168 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hirosh Onishi: "Catalytic Reactions on a Metal Oxide Single Crystal: Switchover of the Reaction Paths in Formic Acid Decomposition on TiO_2 ( 110 )" Journal of Americal Chemical Society. 115. 10460-10461 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Reconstruction of TiO_2 (110) Surface : STM Study with Atomic-Scale Resolution" Surface Science. 313. L783-L789 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "STM-Imaging of Formate Intermediates Adsorbed on a TiO_2 (110) Surface" Chemical Physics Letters. 226. 111-114 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope : Formate Anions on TiO_2 (110)" Japanese Journal of Applied Physics. 33. L1338-L1341 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Observation of Anisotropic Migration of Adsorbed Organic Species Using Nanoscale Patchworks Fabricated with a Scanning Tunneling Microscope" Langmuir. 10. 4414-4416 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Takehiko Sasaki: "A Reactive Oxygen Adlayr on Cu (100) at 100 K" Surface Science. 361. L1081-L1087 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Takehiko Sasaki: "Recent Developments in Analysis of Adsorbed Species Using Electron Stimulated Desorption (in Japanese)" Kagaku. 49. 450-451 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Junji Inukai: "Photochemical Decomposition of Triethylgallium on Si (111) Studied by Means of STM,LEED,AES and Mass Spectroscopy" Japanese Journal of Applied Physics. 32. 1768-1771 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ken-ichi Fukui: "Novel Reaction Path Induced by Selective Blocking of Surface Atoms : Methanol Dehydrogenation on Mo (112)" Surface Science. 295. 160-168 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Takehiko Sasaki: "HREELS Study on CO Adsorbed on Clean, Nitrided and Oxidized Fe/Ru (001) Surfaces" Surface Science. 291. 429-438 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ken-ichi Fukui: "Chemisorption of CO and H_2 on Clean and Oxygen-Modified Mo (112)" Surface Science. 281. 241-252 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Tetsuya Aruga: "Control of Methanol Reaction Pathway by Oxygen Adsorbed on Mo (112)" American Chemical Society Symposium Series. 523. 110-121 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Catalytic Reactions on a Metal Oxide single Crystal : Switchover of the Reaction Paths in Formic Acid Decomposition on TiO_2 (110)" Journal of American Chemical Society. 115. 10460-10461 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hiroshi Onishi: "Reconstruction of TicO_2(110)Surface:STM Study with Atomic-Scale Resolution" Surface Science. 313. L783-L789 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hiroshi Onishi: "STM-Imaging of Formate intermediates Adsorbed on a TiO_2(110)Surface" Chemical Physics Letters. 226. 111-114 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hiroshi Onishi: "Removal of Adsorbed Organic Molecules with Scanning Tunneling Microscope:Formate Anions on TiO_2(110)Surface" Japanese Journal of Applied Physics. 33. L1338-L1341 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hiroshi Onishi: "Observation of Anisotropic Migration of Adsorbed Organic Species Using Nanoscale Patchworks Fabricated with a Scanning Tunneling Microscope" Langmuir. 10. 4414-4416 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Takehiko Sasaki: "A Reactive Oxygen Adiayer on Cu(110)at 100 K" Surface Science. 316. L1081-L1087 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐々木岳彦: "表面吸着種解析法としての電子刺激脱離法の最近の発展" 化学. 49. 450-451 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] J.Inukai,W.Mizutani,K.Fukui,H.Shimizu and Y.Iwasawa: "Photochemical Decomposition of Triethylgallium on Si(III) Studied by Means of STM,LEED,AES and Mass Spectroscopy" Jpn.J.Appl.Phys.32. 1768-1771 (1993)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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