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Development of"in situ"measuring system for an oxidization process of metals by using Raman spectroscopy

Research Project

Project/Area Number 05555180
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

ARASHI Haruo  Faculty of Engineering, Tohoku University, Professor, 工学部, 教授 (80006155)

Co-Investigator(Kenkyū-buntansha) SHIMIZU Ryousuke  ATAGO BUSSAN CO., LTD., Director, ラマンシステム部, 部長
NARUSHIMA Takayuki  Faculty of Engineering, Tohoku University, Associate Professor, 工学部, 助教授 (20198394)
IGUCHI Yasutaka  Faculty of Engineering, Tohoku University, Professor, 工学部, 教授 (90005413)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥14,200,000 (Direct Cost: ¥14,200,000)
Fiscal Year 1994: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1993: ¥13,000,000 (Direct Cost: ¥13,000,000)
KeywordsHigh Temperature Oxidization / High Temperature Raman / Micro Raman / Fe-Si Alloy / Liquid Al-Mg Alloy / 高感度迅速ラマン散乱測定 / SiO-B_4C複合セラミックス / Al,Ag-Hg合金 / 酸化皮膜 / 鉄-シリコン合金
Research Abstract

Laser Raman spectroscopy is one of the most suitable methods for"in situ"observation of the oxidization process of metals from the following points of view ; specimens are not destroyed and a small area can be analyzed by micro-Raman spectroscopy. We developed the "in situ"measuring system, which has a triple monochromator, a CCD detector, and a heating stage which can change the environmental conditions, for an oxidization process of metals by using Raman spectroscopy. This system clarified that the growth process of oxide films during thermal oxidization of Fe-6.5mass%Si alloy at 1073K in O_2 and CO_2 atmospheres depends on the concentration of the oxygen defects in the SiO_2 surface layr. This system also performed to observe the oxidization of the liquid Al and Al-Mg alloys at 1273K.
This system developed in this study is the suitable method for"in situ"observation of oxidization especially at high temperatures.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] 成島尚之: "ラマン分光法を用いた高温酸化皮膜の"その場"観察装置の開発" 鉄と鋼. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Koji Matsui: "Raman Spectroscopic Scudies on the Formation Mechanism of Hydrous-Zirconia Fine Particles" J. American Ceramic Society. 78. 146-152 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M. Kakihara: "Anomalous behaviour of the 147cm^<-1>Cu(2)Raman made in YBa_2Cu_4O_8 under high pressure Signature of ehange in the electronic stete of the CuO_2 plane" Physica C. 230. 199-206 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Katsuya OHTAKE: "MELT-QUENCHING SYNTHESIS AND RAMAN SCATTERING STUDY OF ZrO_2-RO_<1.5>(R=RARE EARTH)SOLID SOLUTIONS" Trans. Mat. Res. Soc. Jpn.14A. 717-720 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M. YASHIMA: "Oxygen-Induced Structual Change of the Tetragonal Phase Around the Tetragonel-Cubic Phase Boundarg in ZrO_2-YO_<1.5> Solid Solutions" Acta Crystallographica. B50. 663-673 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hideaki MORISHIMA: "Raman spectroscopic study for MgSiO_3-perouskite and majorite solid solutions HgSiO_3-Mg_3Al_2Si_3O_<12>" Mineralogical Journal. 16. 399-406 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Masamoto Yashima: "Determination of cubic-tetragonal phase boundary in Zr_<1-X>Y_XO_<2-X/2> solid sdutions by Raman spectroscopy" Journal of Applied Physics. 74. 7603-7605 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 嵐 治夫: "高圧未知相構造解明への高圧ラマン散乱の応用" 高圧力の科学と技術. 2. 308-314 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Narushima, N.Kikuchi, M.Maruyama, H.Arashi, Y.Nishina and Y.Iguchi: "Development of "in-situ"observation sysytem for oxide films formed during thermal oxidation using Raman spectroscopy." Iron and Steel. (in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Matsui, H.Suzuki, M.Ohgai and H.Arashi: "Raman Spectroscopic Studies on the Formation Mechanism of Hydrous-Zirconia Fine Particles." J.Am.Ceram.Soc.78. 146-152 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Kakihana, H.Arashi, M.Yashima, M.Yoshimura, L.Borjesson and M.Kall: "Anomalous Behavior of the 147 cm^<-1> Cu (2) Raman Mode in YBa_2Cu_4O_8 under High Pressure. Signature of Change in the Electronis State of the CuO_2 Plane." Physica C. 230. 199-206 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Ohtake, M.Yashima, H.Arashi, M.Kakihana and M.Yoshimura: "Melt-Quenching Synthesis and Raman Scattering Study of ZrO_2-RO_<1.5> (R=Rare Earth) Solid Solutions." Trans.Mat.Res.Soc.Jpn.14A. 717-720 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Yashima, S.Sasaki, M.Kakihana, Y.Yamaguchi, H.Arashi and M.Yoshimura: "Oxygen-Induced Structual Change of the Tetragonal Phase Around the Tetragonal-Cubic Phase Boundary in ZrO_2-YO_<1.5> Solid Solutions." Acta Crystallographica. B50. 663-673 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Morishima, E.Ohtani and H.Arashi: "Raman Spectroscopic Study for MgSiO_3-Perovskite and Majorite Solid Solutions MgSiO_3-Mg_3Al_2Si_3O_<12>." Mineralogical Journal. 16. 399-406 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Yashima, K.Ohtake, H.Arashi, M.Kakihana and M.Yoshimura: "Determination of Cubic-Tetragonal Phase Boundary in Zr_<1-X>Y_XO_<2-X/2> Solid Solutions by Raman Spectroscopy." J.Appl.Phys.74. 7603-7605 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Arashi: "Application of Raman Spectroscopic Measurement to High Pressure Researches." The Rev.of High Pressure Sci.and Tech.2. 308-314 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Kakihena: "Ancmalous bshaviour of the 147cm^<-1> Cu(2) Raman Made in YBa_2Cu_4Og under high pressure Signature of change in de dectrcnic of the CuO_2 plane" Phgsica C. 230. 199-206 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.OHTAKE: "MELT-QUENCHING SYNTHESIS AND RAHAN SCATTERING STUDY OF ZrO_2-RO_<1S>(R=RARE EARTH) SOLID SOLUTIONS" Trans.Mat.Res.Soc.Jpn.14A. 717-720 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.YASHIMA: "Oxyyen-Induced Siructual Chany of the Tervayrel Phase Around the Tecragousl-Cubic Phase Boundany in ZrO_2-YO_<15> Solid Soluticus" Acta Cryscallographica. B50. 663-673 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 成島 尚之: "ラマン分光法を用いた高温酸化皮膜の“その場"観察装置の開発" 鉄と鋼. (印刷中).

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Yashima: "Determination of cubic-tetragonal phase boundary in Zr_<1-X>Y_XO_<2-X/2> solid solutions by Raman spectroscopy" J.Appl.Phys.74. 7603-7605 (1993)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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