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Optical Properties of Thin Films of Non-Symmetrical Metallophthalocyanines and Application to Non-Linear Optical Devices

Research Project

Project/Area Number 05555181
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

KONAMI Hideo (1994)  TOHOKU UNIV., ICRS,Research Asociate, 反応化学研究所, 助手 (40186713)

籏野 昌弘 (1993)  東北大学, 反応化学研究所, 教授 (50006293)

Co-Investigator(Kenkyū-buntansha) SHIRATORI Yuichi  Sun-Chemipha CO., Chief Researcher, 研究開発室長
MARUNO Tohru  NTT,Interdisc.Res.Labs., Researcher, 境界領域研究所, 研究員
HAYASHI Takayoshi  NTT,Interdisc.Res.Labs., Chief Researcher, 境界領域研究所, 主任研究員
WATANABE Akira  TOHOKU UNIV., ICRS,Asociate Professor, 反応化学研究所, 助教授 (40182901)
ITO Osamu  TOHOKU UNIV., ICRS,Professor, 反応化学研究所, 教授 (30006332)
小波 秀雄  東北大学, 反応化学研究所, 助手 (40186713)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥18,000,000 (Direct Cost: ¥18,000,000)
Fiscal Year 1994: ¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1993: ¥13,000,000 (Direct Cost: ¥13,000,000)
KeywordsLow-Symmetry / Phthalocyanines / Film Deposition / Film Properties / Nonlinear Optics / Optical Devices / Crystal Growth / 非対称フタロシアニン / 分子設計 / 配向薄膜 / 非線形光学特性 / フタロシアニン金属錯体 / チタニルフタロシン / 多重配向薄膜 / RHEED法
Research Abstract

In the first year of the term of this project, we found that symmetry lowered metallophthalocyanine, 2,3 : 12,13-dibenzophthalocyaninato-Zn (II) (ZnDBPc) shows high optical non-linearity when this novel material is deposited on a sapphire base plate under ultra-low pressure and appropriate temperature. When titanylphthalocyanine (TiOPc) was deposited on a thin film of ZnDBPc, the nonlinearity of this double layred film was improved to ten times more, and the alignment of molecules on the film was uniform over the large area of 10mm x 13mm. On the other hand, we clatified spectroscopic properties of symmetry-lowerd phthalocyanines in terms of the group theory and first-order perturbation treatment.
In the second year of the term, we investigated the reason why ZnDBPc molecules are oriented uniformly over the sapphire plate using X-ray diffraction, scanning electron microscope, ultraviolet photoelectron spectra, and so on. As the results, we have found that the crystal growth of ZnDBPc molecule is dominated by interaction between molecules on contrary to a common expectation such that the growth is dominated by interactions between molecules and the base plate.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] T. Maruno: "Third-Order Optical Nonlinearity of Thin Films of Less-Symmetrical Metallophthalocyanine Formed by OMBD" Nonlinear Optics. 7. 207-211 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T. Maruno: "Crystallographic Structure of the Novel Metallophthalocyanine Derivative 2,3:12,13-dibenzophthalocyaninatoZn(II)" J. Cryst. Growth. 141. 156-164 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T. Hayashi: "Structure and Optical Properties of In-plane Ordered Metallo-phthalocyanine Thin Films Formed of Sapphire by OMBD" Jpn. J. Appl. Phys. (in press). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T. Hayashi: "In-plane Ordering of dibenzo(b,t)phthalocyaninato-Zn(II) Thin Film due to the Atomic Step Arrays of Sapphire(1102) Surface" J. Cryst. Growth. (in press). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] D. Braun: "Spectral Hole Burning on Silicon Phthalocyanines Isolated in an Argon Matrix" Chem. Phys. Lett.225. 398-403 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] N. Kobayashi: "Phthalocyanines of a Novel Structure: Dinaphthoteraaza-porphyrins with D_<2h> Symmetry" Inorg. Chem.33. 1735-1740 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Maruno: ""Third-Order Optical Nonlinearity of Thin Films of Less-symmetrical Metallophthalocyanine Formed by Organic Molecular Besm Deposition"" Nonlinear Optics. 7. 207-211 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Maruno: ""Crystallographic Structure of the Novel Metallophtalocyanine Derivative 2,3 : 12,13-dibenzophthalocyan-nato-Zn (II)"" J.Cryst.Growth. 141. 156-264 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Hayashi: ""In-Plane Ordering of dibenzo [b, t] phthalocyaninato-Zn [II] Thin Film due to the Atomic Step Arrays of Sapphire (1102) Surface"" J.Cryst.Growth. in press. (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] D.Braun: ""Spectral Hole Burning on Silicon Phthalocyanines Isolated in an Argon Matrix"" Chem.Phys.Lett.255. 398-403 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] N.Kobayashi: ""Phthalocyanines of a Novel Structure : Dinaphthotetraazaporphyrins with D_<2h> Symmetry"" Inorg.Chem.33. 1735-1740 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Maruno: "Third-Order Optical Nonlinearity of Thin Films of Less-Symmetrical Metallophthalocyanine Formed by OMBD" Nonlinear Optics. 7. 207-211 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Maruno: "Crystallographic Structure of the Novel Metallophthalocyanine Derivative 2,3:12,13-dibenzophthalocyaninatoZn(II)" J.Cryst.Growth. 141. 156-164 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Hayashi: "Structure and Optical Properties of In-plane Ordered Metallophthalocyanine Thin Films Formed of Sapphire by OMBD" Jpn.J.Appl.Phys.in press. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Hayashi: "In-plane Ordering of dibenzo(b,t)phthalocyaninato-Zn(II) Thin Film due to the Atomic Step Arrays of Sapphire(1102) Surface" J.Cryst.Growth. in press. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] D.Braun: "Spectral Hole Burning on Silicon Phthalocyanines Isolated in an Argon Matrix" Chem.Phys.Lett.225. 398-403 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] N.Kobayashi: "Phthalocyanines of a Novel Structure:Dinaphthotetraazaporphyrins with D_<2h> Symmetry" Inorg.Chem.33. 1735-1740 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Konami: "Electronic Spectra of Benzo-Substituted Phthalocyanine and their Electronic Spectra" Molecular Physics. 80. 153-160 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] A.Watanabe: "Photochemical Properties of Network and Branched Polysilanes" Macromolecules. 26. 2111-2116 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] O.Ito: "Kinetics for Reaction of ArS・ and PhSe・ with Methyl-Substituted Allens in Solution" J.Organic Chemistry. 58. 1466-1471 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Maruno: "Highly Ordered Thin Films of a Novel Less-Symmetrical Metallophthalocyanine Formed by Organic Molecular Beam" Jpn.J.Applied Physics. 32. L628-L630 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Folsch: "Crystallographic Structure of the Novel Metallophthalocyanine Derivatives:2,3:12,13-Dibenzophthalocyaninato-Zn(II)" J.Cryst.Growth. (印刷中). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Maruno: "Third-Harmonic Generation in Highly Ordered Thin Films of Phthalocyaninato-Oxytitanium(IV)" Nonlinear Optics. (印刷中). (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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