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Production and surface improvement of functional materials by using DC arc, RF,magnetron plasma.

Research Project

Project/Area Number 05555189
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Material processing/treatments
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

TOMII Yoichi  KYOTO UNIVERSITY,FACULTY OF TECHNOLOGY,LITERATURE, 工学部, 講師 (90026245)

Co-Investigator(Kenkyū-buntansha) 加藤 周一郎  (株)日本アルミ工業, 滋賀製造所, 所長
KUWAHARA Hideyuki  INSTITUTE OF APPLIED SCIENCE,HEAD OF PLASMA RESEARCH, プラズマ研究室, 室長 (90132795)
YOSHIDA Katsukuni  INSTITUTE OF ATOMIC ENERGY,ASSISTANT PROFESSOR, 原子エネルギー研究所, 助教授 (70027142)
TAKADA Jun  OKAYAMA UNIVERSITY,FACULTY OF TECHNOLOGY,PROFESSOR, 工学部, 教授 (60093259)
KATO Shuichro  PLANT MANAGER OF SHIGA WORKS,JAPAN ALUMINIUM IND.CO.LTD.
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥16,500,000 (Direct Cost: ¥16,500,000)
Fiscal Year 1994: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1993: ¥14,000,000 (Direct Cost: ¥14,000,000)
Keywordsplasma jet / CVD / diamond / hetero metal joining / plasma nitriding / percolation / supercunducting material / brazing by ultra sonic wave / プラズマジェット / DCアークプラズマ / 表面改質 / スパッターリング / X線回折 / EPMA分析 / 活性ラディカルイオン / 色温度
Research Abstract

An establishment in the synthesizing conditions of high functional materials for industrial production and an improvement in joinability of surface treatment were aimed by conducting some small experiments using a large scale experimental plasma CVD reactor with a special spectrometer financially supported by this project.
The main program in this project were not changed, but will be finished in a few month later than initial plan due to the small delay in a adjustment of measurements system. Main obtained experimental results are as follows ;
(1)An expression of the spatial distributions for the active radical ion species in DC arc plasma such as C,C_2, CH,CH_2, CH_3 and CH^<3+> was performed by special spectrometer. Using this techniques, an establishment in the synthesizing conditions of high functional materials was experienced through spectrometrical results.
(2)Polycrystaline bur small diamond film and block was synthesized on several refractory substratum metala. Numbers in nucleating sites than growth rate were much influenced by the reaction between substratum surface and radical ions exited in DC arc plasma.
(3)Using above mentioned CVD reactor, powder spray or coatings of high functional solids in high temperature plasma on functional ceramics such as YSZ electrode for fuel cell.
(4)A high functional mechanism in solids such as oxide super conductor and high quality composite materials were cleares by percolation theory.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] 冨井洋一: "プラズマジェットCVDダイヤモンド膜形成におよぼす非ダイヤモンド質の影響" 粉体および粉末冶金. 40. 80-84 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Katsukuni Yoshida: "『Percolative behavior of Ag-phase clusters in superconducting" Physica C. 208. 127-132 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.YOSHIDA: "Thermal Transport and Percolative Trannsition in the Ag-BPSCCO Composite System" J.Phys. Soc. of Japan. 64. 164-169 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 桑原秀行: "鉄合金のプラズマ窒化" 粉体および粉末冶金. 41. 1341-1351 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] S.Kato: "CHARACTERISTICS OF MICRO CRYSTALLINE DIAMONDO FLMS SYNTHESIZED BY PLASMA JET CVD" Proc. of the 14th Int. Thermal Spray Conf.(to be poblished). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 加藤周一郎: "超音波はんだ付技術を用いたアルミニウムと異種金属の接合" アルトピア. 6. 9-13 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Tomii: "Effect of Non-diamond Material on the Diamond Film Formation by Plasma Jet CVD" J.J.Soc.Pow.& Pow.Met.vol.40. 80-84 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] S.Nishikawa: "PRECIPITATION OF NITRIDE IN IRON ALLOYS PREPARED BY PLASMA NITRIDING" Proc.of 1993 Powder Metallurgy Congress. 670-673 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Kuwahara: "Plasma Nitriding of Iron Alloys" J.J.Soc.Pow.& Pow.Met.vol.41. 1341-1351 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] M.Matsukawa: "Thermal Transport and Percolative Transition in the Ag-BPSCCO Composite System" J.Phys. Soc.Japan. vol.64. 164-169 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kusano: "Chemical Stability of the Bi-2223 Phase" J.J.Soc.Pow.& Pow.Met.vol.40. 1057-1060 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Niinae: "Mechanical Grinding and Reforming Process of the Bi-2201 Phase" J.J.Soc.Pow.& Pow.Met.vol.40. 1065-1068 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kusano: "Phase and their Relations in the BiO_<1.5>-SrO (SrCO_3)-CuO System at 72OC" J.J.Soc.Pow.& Pow.Met.vol.40. 1049-1052 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kusano: "Segregation and Resolution Reactions of the 2223 Phase in the Bi.Pb-Sr-Ca-Cu-O System on Annealing in Air" Physica C. vol.219. 366-370 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] J.Takada.: "Effect of Li Addition to the Low-TC Phase in the Bi-Sr-Ca-Cu-O System" Proc.of 1993 Powder Metallurgy Congress. 1302-1305 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kusano: "Chemical and Mechanical Stability of the High-Tc in the Bi-Pb-Sr-Ca-Cu-O System" Proc.of 1993 Powder Metallurgy Congress. 1298-1301 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Takesita: "Quantitative Analysis of small amounts of Oxygen in Titanium by Secondary Ion Mass Spectrometry" J.Japan Inst.Metals. vol.57. 1421-1425 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] S.K.Ratkje: "Transported Entropy in Zirconia with 3 to 12 Mole Percent Yttria" J.Electrochem.Soc.vol.140. 59-66 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Amezawa: "The Effect of Phase Change of Li-Al Alloy Electrode on Thermoelectric Power in LiCl-KCl Eutectec System" Denki Kagaku. vol.61. 736-737 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.YOSHIDA: "Effect of Ag-Doping on the Intergranular Properties of the Superconducting Bi-(Pb)-Sr-Ca-Cu-O System" Physica B. vol.194-196. 1949-1950 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] H.Takeshita: "Determination of Small Amounts of Oxygen in Titanium by Secondary Ion Mass Spectrometry (SIMS)" Proc.Nith Int.Conf.on Secondary Ion Mass Spectroscopy, SIMS IX,Editted by A.Benninghoven, Y.Nihei, R.Shimizu and H.W.Werner, Wiley. 166-169 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Amezawa: "The Single Electrode Peltier Heats of Li-Al Alloy Electrodes in LiCl-KCl Eutectec System" J.Electrochem.Soc.vol.141. 3096-3103 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 冨井 洋一: "プラズマジェットCVDダイヤモンド膜形成におよぼす非ダイヤモンド質の影響" 粉体および粉末冶金. 40. 80-84 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] Katsukuni Yoshida: "『Percolative behavior of Ag-phase clusters in superconducting" Physica C. 208. 127-132 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.YOSHIDA: "Thermal Transport and Percolative Trannsition in the Ag-BPSCCO Composite System" J.Phys.Soc.of Japan. 64. 164-169 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 桑原 秀行: "鉄合金のプラズマ窒化" 粉体および粉末冶金. 41. 1341-1351 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Kato: "CHARACTERISTICS OF MICRO CRYSTALLINE DIAMONDO FLMS SYNTHESIZED BY PLASMA JET CVD" Proc.of the 14th Int.Thermal Spray Conf.(to be poblished). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 加藤 周一郎: "超音波はんだ付技術を用いたアルミニウムと異種金属の接合" アルトピア. 6. 9-13 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 松本史朗、加藤周一郎、冨井洋一: "プラズマジェットCVDダイヤモンド膜形成におよぼす非ダイヤモンド質の影響" 粉体および粉末冶金. 40. 80-84 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 竹下博之、冨井洋一、大石敏雄、小野勝敏: "二次イオン質量分析法によるチタン中の微量酸素の定量" 日本金属学会誌. 57. 1421-1425 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Kusano,T.Nanba,J.Takada,T.Egi,Y.Ikeda and M.Takano: "Segregation and dissolution reactions of the 2223 phase in the Bi,Pb-Sr-Ca-Cu-O system on annealing in air" PHYSICA C. 219. 366-370 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Koji AMEZAEWA,Mitsuko OSUGI,Yoichi TOMII and Yasuhiko ITO: "The Effects of Phase Change of Li-Al Alloy Electrode on Thermoelectric Power in LiCl-KCl Eutectic System" DENKI KAGAKU. 61. 736-737 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 新苗稔展、高田潤、池田靖訓、坂東尚周: "Bi系2201相の機械的粉砕と再生成過程(II)" 粉体および粉末冶金. 40. 1065-1068 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 井神浩、加藤周一郎: "超音波はんだ付技術を用いたアルミニウムと異種金属の接合" アルトピア. 6. 9-14 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] S.Nishikawa,T.Hama,H.Kuwahara and J.Takada: "PRECIPITATION OF NITRIDE IN IRON ALLOYS PREPARED BY PLASMA NITRIDING" Edited by Y.Bando and K.Kosuge Proceedings of 1993 Powder Metallurgy World Congress,Kyoto,Japan,1993, 670-673(1416) (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Kusano,T.Nanba,J.Takada,Y.Ikeda,Z.Hiroi,M.Takano & H.Mazaki: "CHEMICAL AND MECHANICAL STABILITY OF THE HIGH-Tc PHASE IN THE Bi-Pb-Sr-Ca-Cu-O SYSTEM" Edited by Y.Bando and K.Kosuge Proceedings of 1993 Powder Metallurgy World Congress,Kyoto,Japan,1993, 1298-1301(1416) (1993)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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