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Development of magnesium oxide/water chemical heat pump

Research Project

Project/Area Number 05558062
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field エネルギー学一般・原子力学
Research InstitutionTOKYO INSTITUTE OF TECHNOLOGY

Principal Investigator

YOSHIZAWA Yoshio  Tokyo Institute of Technology, Professor, 原子炉工学研究所, 教授 (00016627)

Co-Investigator(Kenkyū-buntansha) KATO Yukitaka  Tokyo Institute of Technology, Research Assistant, 原子炉工学研究所, 助手 (20233827)
Project Period (FY) 1993 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥15,800,000 (Direct Cost: ¥15,800,000)
Fiscal Year 1995: ¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 1994: ¥4,300,000 (Direct Cost: ¥4,300,000)
Fiscal Year 1993: ¥8,200,000 (Direct Cost: ¥8,200,000)
KeywordsHeat pump / Energy saving / Magnesium hydroxide / Magnesium oxide / Dehydration / Hydration / 省エネルギ / 気固反応
Research Abstract

A laboratory scale system of Magnesium oxide/water chemical heat pump was designed for the heat output o 100W class. The performance of the repetitive operation was demonstrated because the durability of the reactant material and the system to the repetitive operation was important matter for the heat pump development.
A new reactant material which had a durability to repetitive reaction had been developed in this work. The material was used for the laboratory heat pump.
On the heat pump experiment, the fraction reacted and heat output were measured directly and simultaneously in the experiment. The former was followed by measurements of weight change with a load cell. The latter was measured with a heating tube installed in the reactor. From the first to the third repetitive operation, the decrease of reactivity about 20% was measured, but after the time to the tenth, the reactivity was stable. The result showed the feasibility of the heat pump for practical repetitive utilization.
On the first repetition, it was shown that the system was able to store a thermal energy at about 430゚C and to supply a thermal energy at 75-120゚C from a low temperature steam at 70-90゚C,and that the thermal power exceeded 50-100w per 1kg of initial magnesium hydroxide during the first 60minutes. The profile of reaction rate and heat transfer in the reactor were simulated by two-dimensional numerical analysis. The results of the experiments and the simulations showed that the heat pump had enough thermal storage capacity and thermal power as a commercial system.

Report

(4 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • 1993 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] Yukitaka Kato,S.Inoue,W.Nanmoku and Yoshio Yoshizawa: "Kinetic study of magnesium oxide/water chemical heat pump" Proc.30th Intersoc.Energy Conversion Engineering Conf.3. 17-22 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato,Takuya Honda and Atsushi Kanzawa: "Kinetic measurement on the isobutene/water/tert-butanol chemical heat pump ; dehydration of tert-butanol" Internat.J.Energy Research. 19 (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato.N.Yamashita.K.Kobayashi and Yoshio Yoshizawa: "Kinetic study of the hydration of magnesium oxide for a chemical heat pump" Applied Thermal Engineering. 1 (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato,S.Inoue.W.Nanmoku and Yoshio Yoshizawa: "A kinetic study of magnesium oxide/water chemical heat pump" Proc.44th Canadian Soc.Chem.Eng.295-296 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato, S.Inoue, W.Nanmoku and Yoshio Yoshizawa: ""Kinetic study of magenesium oxide/water chemical heat pump"" Proc.30th Intersoc.Energy Conv.Eng.Conf.vol.3. 17-22 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato, Takuya Honda and Atsushi Kanzawa: ""Kinetic measurement of the isobutene/water/tert-butanol chemical heat pump ; dehydration of tert-butanol"" Internat.J.Energy Res.19 (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato, N.yamashita, K.Kobayashi and Y.Yoshiozawa: ""Kinetic study of the hydration of magnesium oxide for a chemical heat pump"" Applied Thermal Eng.vol.1 (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato, S.Inoue, W.Nanmoku and Y.Yoshizawa: ""A kinetic study of magnesium oxide/water chemical heat pump"" Proc.44th Canadiac Soc.Chem.Eng.295-296 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Yukitaka Kato, S. Inoue. W.Nanmoku and Yoshio Yoshizawa: "Kinetic study of magnesium oxide/water chemical heat pump" Proc. 30th Intersoc. Energy Conversion Engineering Conf.3. 17-22 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Yukitaka Kato, Takuya Honda and Atsushi Kanazawa: "Kinetic measurement on the isobutene/water/tert‐butanol chemical heat pump:dehydration of tert‐butanol" Internat. J. Energy Research. 19 in press. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Yukitaka Kato, N. Yamashita. K. Kobayashi and Yoshio Yoshizawa: "Kinetic study of the hydration of magnesium oxide for a chemical heat pump" Applied Thermal Engineering. 1 in press. (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Yukitaka Kato, S. Inoue, W. Nanmoku and Yoshio Yoshizawa: "A kinetic study of magnesium oxide/water chemical heat pump" Proc. 44th Canadian Soc. Chem. Eng.295-296 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kato,S.Inoue,K.Kobayashi and Y.Toshizawa: "The Kinetic study for Magnesium oxide/water chemical heat pump" 44th Canadian Chem.Eng.Conf.(Calgry). 295-296 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 加藤之貫,山下理道,吉澤善男: "酸化マグネシウムケミカルヒートポンプに関する研究-酸化マグネシウム水和反応の活性化-" 化学工学論文集. 19. 1213-1216 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 加藤之貫,渡辺佳則,吉澤善男: "無機系炭酸化反応を利用したケミカルヒートポンプの検討" 化学工学会第59年会予稿集. R303 (1993)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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