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NMR Studies of the magnetic order at low temperatures in the Antiferromagnetic Phase of Oxide High-T_c Superconductor

Research Project

Project/Area Number 05640425
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionUniversity of the Ryukyus

Principal Investigator

NIKI Haruo  University of the Ryukyus, Division of General Education, Associate Professor, 教養部, 助教授 (80145549)

Co-Investigator(Kenkyū-buntansha) TOMIYOSHI Shoichi  Ehime University, Faculty of Engineering, Professor, 工学部, 教授 (50005922)
YAGASAKI Kastuma  University of the Ryukyus, College of Science, Professor, 理学部, 教授 (70045037)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1994: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1993: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsOxide High-T_C Superconductor / Antiferromagnetic Materials / NMR / NQR / Spin-Lattice Relaxation Time / Spin-Spin Relaxation Time / 核スピン-格子緩和時間
Research Abstract

Proton NMR and Cu NQR of Cu (1) and C (2) sites have been measured on the antiferromagnetic phase (T_N = ca.410 K) of a powdered sample of hydrogen-doped tetragonal YBa_2Cu_3O_<6+X>H_y. It was found by proton NMR studies that hydrogen atoms are occupied in the vicinity of Cu(1) site in the oxygen deficient layr. The line width, DELTAomega, of ^1H NMR increases abruptly below 20 K.The enhancements of T_2^<-1> and T_1^<-1> of ^<63>Cu (1) NQR occur around 20 K and 40 K,respectively. The nuclear magnetization does not recover in a simple exponential manner below 80 K.The predominant mechanism governing T_1 below 80 K was found to be the fluctuating magnetic fields induced by the hole doping effect. These enhancements and the abrupt increase in DELTAomega are attributed to this fluctuating magnetic field.
Above 80 K,however, the nuclear magnetization recover in a simple exponential manner. The contribution of the fluctuating magnetic field to T_1 decreases rapidly above 80 K.Taking the place of the fluctuating field, other T_1 relaxation mechanismsm dominate above 80 K.In order to investigate the relaxation mechanism above 80 K,the temperature dependence of T_1, T_2, the resonance frequencies, and the line width of ^<63>NQR in the Cu (1) site has been measured in the high temperature region above 80 K.The measurement of Cu NQR in the Cu (2) site has also carried out to investigate the antiferromagnetic phase of YBCO.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] Haruo Niki: "Hydrogen-doped Antiferromagnetic YBa_2Cu_3O_<7-δ> Hx as Studied by Proton NMR and Cu NQR"" Zeitschrift fur Naturforschung. 49a. 401-406 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 二木治雄: "強相関系物質のNMR" 東北大学金属材料研究所新素材開発施設共同利用研究報告書. 5. 78-81 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 二木治雄: "強相関係物質のNMRとNQRによる研究" 東北大学金属材料研究所新素材開発施設共同利用研究報告書. 6. (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Haruo Niki: "Inequivalent Reoriention of Trichloromethyl Groups in 1,4-Bis(Trichloromethyl)Brnzene as Studies by Pulsed ^<35>C1 NQR" Zeitschrift fur Naturforschung. 49a. 273-278 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Masao Hashimoto: "^<35>C1 NQR Relaxation and Hydrogen Bond in Some Chloral Hemiacetals" Zeitschrift fur Naturforschung. 49a. 279-285 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Haruo Niki: "Hydrogen-doped Antiferromagnetic YBa_2Cu_3O_<7-8>H_X as studied by Proton NMR and Cu NQR" Zeitschrift fur Naturforschung. 49a. 401-406 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Haruo Niki: "NMR Studies of Materials Influenced on Strong Correlations between Electrons" Research Report of Laboratory for Development Research of Advanced Materials, the Institute for Materials Research, Tohoku University.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Haruo Niki: "NMR and NQR Studies of Materials Influenced on Strong Correlations between Electrons" Research Report of Laboratory for Development Research of Advanced Materials, the Institute for Materials Research, Tohoku University.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Haruo Niki: "Inequivalent Reorientation of Trichloromethyl Groups in 1,4-Bis (Trichoromethyl) Benzene as Studies by Pulsed ^<35>C1 NQR" Zeitschrift fur Naturforschung. 49a. 273-278 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Masao Hashimoto: "^<35>C1 NQR Relaxation and Hydrogen Bond in Some Chloral Hemiacetals" Zeitschrift fur Naturforschung. 49a. 279-285 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Hauro Niki: "Hydrogen-doped Antiferromagnetic YBa_2Cu_3O_<7-δ> H_X as Studied by Proton NMR and Cu NQR"" Zeitschrift fur Naturforschung. 49a. 401-406 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 二木治雄: "強相関系物質のNMR" 東北大学金属材料研究所新素材開発施設共同利用研究報告書. 5. 78-81 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 二木治雄: "強相関系物質のNMRとNQRによる研究" 東北大学金属材料研究所新素材開発施設共同利用研究報告書. 6. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Haruo Niki: "Inequivalent Reorientation of Trichloromethyl Groups in 1,4-Bis(Trichloromethyl)Brnzene as Studies by Pulsed ^<35>Cl NQR" Zeitschrift fur Naturforschung. 49a. 273-278 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Masao Hashimoto: "^<35>Cl NQR Relaxation and Hydrogen Bond in Some Chloral Hemiacetals" Zeitschrift fur Naturforschung. 49a. 279-285 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Haruo NIKI: "Hydrogen-doped Antiferromagnetic YBa_2Cu_3O_<7-delta> Hxas Sudied by Proton NMR and NQR" Zeitschrift f〓r Naturforschung. 49a. (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 二木治雄: "強相関係物質のNMR" 東北大学金属材料研究所新素材開発施設共同利用研究報告書. 5. (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2020-05-15  

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