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Study of the chemo-mechanical energy conversion in polymer gels

Research Project

Project/Area Number 05640442
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 物性一般(含基礎論)
Research InstitutionNagoya University

Principal Investigator

SEKIMOTO Ken  Technology Dept., Nagoya University Associate Professor, 工学部, 助教授 (00179342)

Co-Investigator(Kenkyū-buntansha) KUWABARA Shinji  Information Dept., Teikyo Gijutsu-Kagaku Univ., Professor, 情報学部, 教授 (30011589)
FUKUMOTO Yasuhide  Technology Dept., Assistant Professor, 工学部, 助手 (30192727)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1994: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1993: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywordsgel / stress transfer / energy conversion / crossover / protein molecular motors / boundary condition / volume phase transition / cycle / イクル / 混合溶媒 / 非平衡 / ソフト・マテリアル / 不安定性 / 拡散 / 中心多様体
Research Abstract

We have got the following concrete findings concerning our theme of research of '94 fiscal year, i.e., to clarify the governing factors of the efficiency of the mutual energy exchange between the chemical energy of gel due to the change of solvent conposition, or generally, that of the solvent-network interaction and the mechanical energy due to the macroscpoic deformation of gel, and to seek the optimization of such factors.
1. We constructed the unified formalism describing the partition of stress into the solvent pressure and the network stress, both of which contribute in taking out the work, and their spatial dependence (publised with the co-author of Y.Rabin).
2. We established the modeling the role of geometric features of gel in the state that can perform mechanical work concerning the gels undergoing volume phase transition, and discovered the notion of the crossover of the similarity law about the characteristinc lengths of the system(publised and submitted with co-author Yoshiki Kuroki.
3. We investigated protein molecular motors as the related system having the "cycles" which are necessary for converting continuously the chemical energy into mechanical energy (or vise versa) , and we found the mechanism of cooperation and/or competition among the spatially distributed elements of energy convertion (submitted with the co-author of K.Tawada).
4. We have found the essential role of the boundary conditions for the system of spatially distributed energy-conversion elements (submitted and in preparation with the co-author of N.Mori, K.Tawada, and Y.Y.Toyoshima).
5. We contributed an English written review article concerning our works up to now, including a part of those described above (in press).

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] K.Sekimoto: "Temperature hysteresis and morphology of volume phase transition of gels" Physical Review Letters(USA). 70. 4154-4157 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kuroki and K.Sekimoto: "Arrested-volume phase transition of a gel around a hole" Europysics Letters(Switzerland). 23. 113-117 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 関本 謙: "相転移は、いつ・どこから始まるか-ゲルの場合" 日本物理学会誌. 49. 35-38 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sekimoto: "First order phase transitions,when and from where do they emerge? The case of gels" International Journal of Modern Physics. (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sekimoto and Y.Rabin: "Role of mechanical pressure in permeation of a solvent through gels" Europysics Letters(Switzerland). 27. 445-450 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Yoshimura and K.Sekimoto: "Copling between diffusion and deformation of gels in binary solvents:a model study" Journal of Chemical Physics(USA). 101. 4407-4417 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] L.Leibler and K.Sekimoto: "On sorption of gases and Iiquids in glassy polymers" Macromolecules. 26. 6937-6939 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sekimoto: "Temperature hysteresis and morphology of volume phase transition of gels" Physical Review Letters (USA). vol.70. 4154-4157 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Kuroki and K.Sekimoto: "Arrested-volume phase transition of a gel around a hole" Europysics Letters (Switzerland). vol.23. 113-117 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sekimoto: "First order phase transitions, when and from where do they emerge? The case of gels" Butsuri Gakkai shi. vol.49. 35-38 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sekimoto: "First order phase transitions, when and from where do they emerge? The case of gels" International Journal of Modern Physics. (in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Sekimoto and Y.Rabin: "Role of mechanical pressure in permeation of a solvent through gels" Europysics Letters (Switzerland). vol.27. 445-450 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] K.Yoshimura and K.Sekimoto: "Copling between diffusion and deformation of gels in binary solvents : a model study" Journal of Chemical Physics (USA). vol.101. 4407-4417 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] L.Leibler and K.Sekimoto: "On sorption of gases and liquids in glassy polymers" Macromolecules. vol.26. 6937-6939 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 関本 謙: "Temperature Hysteresis and Morphology of Volume Phase Transition of Gels" Physical Review Letters. Vol.70. 4154-4157 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] Ludwik Leibler: "On the Sorption of Gases and Liquids in Glassy Polymers" Macromolecules. Vol.26. 6937-6939 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 関本 謙: "一次相転移は,いつ・どこから始まるか:ゲルの場合" 日本物理学会誌. Vol.49. 35-38 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 桑原 真二: "Vortex Model of Turbulence" 日本流体力学会第25回乱流シンポジウム論文集. 132-134 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 福本 康秀: "Steady configurations of a vortex filament in flows" Unstable and Turbulent Motion of Fluid(ed.S.Kida),World Scientific. 50-58 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 福本 康秀: "軸方向流を伴う渦系の3次元運動" ながれ. Vol.13(掲載予定). (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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