| Project/Area Number |
05640623
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
MORITA Yasushi Osaka Univ.Dep.of Chem.Research Associate, 理学部, 助手 (70230133)
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| Project Period (FY) |
1993 – 1994
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| Project Status |
Completed (Fiscal Year 1994)
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| Budget Amount *help |
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1994: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1993: ¥1,400,000 (Direct Cost: ¥1,400,000)
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| Keywords | alkylthio / biphenoquinone / biphenochydroquinone / capto-dative / DDQ / アルキルチオ置換ビフェノキノン / キャプト-デイティブ / キンヒドロン錯体 |
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| Research Abstract |
Quinone and hydroquinone are familier elecronic systems as components for the charge-transfer (CT) complexes. Recent finding of new phase transition for 1,4-benzoquinhydrone has provided a renewed aspect for such systems to obtain interesting solid state properties. Generally, it is important to modify the electronic systems so as to enhance the degree of CT.The extension of a conjugated system is a typical chemical modification for such a purpose. The introduction of substituents with chalcogen atoms or with capto-dative effect is also important. Utilizing biphenoquinone as an exteneded conjugated system of benzoquinone, I synthesized firstly the alkylthio derivatives of biphenoquinones (1) and biphenohydroquinones (2) by the following method.
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