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Study on Formation Mechanisms and Control of NO_x in High Prssure Combustion

Research Project

Project/Area Number 05650209
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionTOKAI UNIVERSITY

Principal Investigator

SANO Taeko  Tokai University, Faculty of Engineering, Professor, 工学部, 教授 (60013728)

Co-Investigator(Kenkyū-buntansha) TAKAMOTO Kenji  Tokai University, Faculty of Engineering, Professor, 工学部, 教授 (90056276)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1994: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1993: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsMethane Flame / NO Formation / Prompt NO Formation / Laminar Flame / Numerical Analysis / Reaction Kinetics / NOx生成 / 層流予混合火炎 / 化学反応動力学 / 数値計算
Research Abstract

The equations of one-dimensional laminar flame propagation were numerically resolved to study the formation of NO and prompt NO in the premixed methane-air flame by considering 37 species with 144 elementary reactions and by using theoretically calculated transport properties.
(1) By comparing the concentration profiles of NO calculated with and without prompt NO formation reactions, the formation of prompt NO is found to be predominantly governed by the reaction CH+N_2*HCN+N.
(2) At any equivalence ratio from 0.6 to 1.4, the prompt NO is rapidly formed in the visible flame region and does not increase in the downstream rgion except for the equivalence ratio of 1.4. In the flame of equivalence ratio of 1.4, the prompt NO is formed still in the downstream region.
(3) The concentration ratio of the prompt NO to the total NO is large in the visible flame region and it deacreases rapidly in the downstream region except for the equivalence ratio of 1.4.
(4) The formation of prompt NO increases slightly with the unburned gas temperature from 298K to 398K in the lean flame, but does not change in the rich flame.
(5) The formation of prompt NO increases with the pressure from 0.1MPa to 0.2MPa in the rich flame.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 佐野妙子: "メタン火炎内でのprompt NOの生成" Thermal Science & Engineering. 1. 7-21 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐野妙子: "メタン平面火炎内でのNOの生成;温度・圧力・当量比の影響" ガスタービン講演会講演論文集. 53-59 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Sano: "Formation of prompt NO in Flat Flame of Methane" Proceedings of Fifteench Task Leaders Meeting. 15. 112-119 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐野妙子: "NOxの生成" 日本機械学会第71期通常総会講演論文集. 652- (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] SANO.T.: "Formation of prompt NO in flat flames of methane." Thermal Science & Engineering.vol.1-2. 1-7 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] SANO,T., YAMAMOTO,T., and TAMARU,T.: "Formation of NO in flat flames of methane : effect of temperature, pressure and equivalence ratio." Proceedings of Gas Turbine Conf.53-59 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] SANO,T.: "Formation of prompt NO in flat flame of methane." Proceedings of Fifteenth Task Leaders Meeting. (1993-Sept).pp.112-119. IEA Exeutive Committee on Energy Conservation and Emission Reduction in Combustion.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] SANO.T.: "NO_x Formation" Proceedings of 71st Cof. of JSME. 652-653 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 佐野妙子: "メタン平面火炎内でのprompt NOの生成" Thermal Science & Engineering. 1. 7-21 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐野妙子: "メタン平面火炎内でのNOの生成:温度・圧力・当量比の影響" ガスタービン講演会講演論文集. 53-59 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Sano: "Formation of prompt NO in Flat Flame of Methane" Proceedings of Fifteenth Task Leaders Meeting. 15. 112-119 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐野妙子: "NOxの生成" 日本機械学会第71期通常総会講演論文集(III). 652- (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐野妙子: "メタン平面火炎内でのprompt NOの生成" Thermal Sience & Engineering. 1. 7-21 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 佐野妙子: "NOxとその生成" ガスタービン学会誌. 21. 23-28 (1993)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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