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Thermodynamic Study of Secondary Refining Slag for Steelmaking

Research Project

Project/Area Number 05650722
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Metal making engineering
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

HINO Mitsutaka  Tohoku University, Faculty of Engineering, Professor, 工学部, 教授 (10091729)

Co-Investigator(Kenkyū-buntansha) BAN-YA Shiro  Akita National College of Technology, President, 校長 (90005223)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1994: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1993: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsSecondary Refining for Steelmaking / Dephosphorization / Desulphurization / High Purity Steel / Sulphide Capacity / Activity / Sulphur Solubility in Slag / Thermodynamics / 溶鋼二次精錬 / CaO-Al_2O_3系スラグ / サルファイド・キャパシティ
Research Abstract

Various kinds of fluxed for dephosphorization and desulphurization of steel have been developed to produce high purified steel. Practically used flux is CaO-based flux and steel is deoxidized with aluminum in secondary steelmaking proces. As the result, CaO-Al_2O_3 slag is formed in the process. In the present work, at first, the sulphide capacities and sulphur solubility for CaO-Al_2O_3, CaO-Al_2O_3-MgO,CaO-Al_2O_3-SiO_2 and CaO-Al_2O_3-CaF_2 slags were studied at 1823 to 1923K to discuss the desulphurization ability of these slags in the secondary steelmaking process.
Secondary, the activities of the constituents in these slags were determined at 1823 to 1923 K to estimate the equilibrium oxygen distributed between these slags and liquid iron.
From the results obtained, the equilibrium sulphur distribution between these slags and liquid steel was evaluated on the assumption that the steel would be deoxidized with aluminum., and these were compared with the experimentally observed results.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] 江原靖弘・日野光兀・萬谷志郎: "CaO-Al_2O_3-MgO系スラグの成分活量" 材料とプロセス. 7. 883-883 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 伊藤健・日野光兀・萬谷志郎: "CaO-Al_2O_3系スラグの硫黄溶解度に及ぼすCaF_2の影響" 材料とプロセス. 7. 884-884 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 橋本健・日野光兀・萬谷志郎: "CaO、Al_2O_3、MgO耐火物飽和CaO-Al_2O_3-MgO系スラグ-溶鉄間の酸素、硫黄分配平衡" 材料とプロセス. 8. 290-290 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Shiro BAN-YA,Mitsutaka HINO and Tetsuya NAGASAKA: "THERMODYNAMICS OF CaO-BASED SLAGS FOR REFINING OF HIGH PURITY STEELS" Proceedings of the first Intemational Conference on Ultra Higu Purity Base Metals. (掲載予定). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Mitsutaka HINO and Shiro BAN-YA: "EQUILIBRIA OF SULPHUR AND OXYGEN BETWEEN CaO-Al_2O_3 BASED SLAGS AND LIQUID IRON" Proceedings of the first Intemational Conference on Ultra Higu Purity Base Metals. (掲載予定). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Mitsutaka HINO and Shiro BAN-YA: "Thermodynamics of Secondary Refining Slag for Steelmaking" Proceedings of 1995 AIME PTD Theme Conference on Ladle Metallurgy. (掲載予定). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Yasuhiro EHARA,Mitsutaka HINO and Shiro BAN-YA: "Activity measurement of the constituents in CaO-Al_2O_3-MgO slag" CAMP-ISIJ. 7-4. 883-883 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Ken ITOH,Mitsutaka HINO and Shiro BAN-YA: "Effect of CaF2 addition on the sulfur solubility in CaO-Al_2O_3 slag" CAMP-ISIJ. 7-4. 884-884 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Takeshi HASHIMOTO,Mitsutaka HINO and Shiro BAN-YA: "Distribution Equilibria of Oxygen and Sulfur between Liquid Iron and CaO-Al_2O_3-MgO Slag Saturated with CaO,Al_2O_3, or MgO" CAMP-ISIJ. 8-1. 290-290 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Shiro BAN-YA,Mitsutaka HINO and Tetsuya NAGASAKA: "THERMODYNAMICS OF CaO-BASED SLAGS FOR REFINING OF HIHG PURITY STEELS" Proc.1st Intern.Conf.on Ultra High Purity Base Metals. (to be published). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Mitsutaka HINO and Shiro BAN-YA: "EQUILIBRIA OF SULPHUR AND OXYGEN BETWEEN CaO-Al_2O_3 BASED SLAGS AND LIQUID IRON" Proc.1st Intern.Conf.on Ultra High Purity Base Metals. (to be published). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Mitsutaka HINO and Shiro BAN-YA: "Thermodynamics of Secondary Refining Slag for Steelmaking" Proc.of 1995 AIME PTD Theme Conference on Ladle Metallurgy. (to be published). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 江原靖弘,日野光兀,萬谷志郎: "CaO-Al_2O_3-MgO系スラグの成分活量" 材料とプロセス. 7. 883-883 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 伊藤健,日野光兀,萬谷志郎: "CaO-Al_2O_3系スラグの硫黄溶解度に及ぼすCaF_2の影響" 材料とプロセス. 7. 884-884 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 橋本健,日野光兀,萬谷志郎: "CaO、Al2O3、MgO耐火物飽和CaO-Al2O3-MgO系スラグ-溶鉄間の酸素、硫黄分配平衡" 材料とプロセス. 8. 290-290 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Shiro BAN-YA,Mitsutaka HINO and Tetsuya NAGASAKA: "THERMODYNAMICS OF CaO-BASED SLAGS FOR REFINING OF HIGH PURITY STEELS" Proceedings of the first International Conference on Ultra Higu Purity Base Metals. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Mitsutaka HINO and Shiro BAN-YA: "EQUILIBRIA OF SULPHUR AND OXYGEN BETWEEN CaO-Al 2O3 BASED SLAGS AND LIQUID IRON" Proceedings of the first International Conference on Ultra Purity Base Metals. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Mitsutaka HINO and Shiro BAN-YA: "Thermodynamics of Secondary Refining Slag for Steelmaking" Proceedings of 1995 AIME PTD Theme Conference on Ladle Metallurgy. (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Mitsutaka HINO: "Sulphide Capacities of CaO-Al_2O_3-MgO and CaO-Al_2O_3-SiO_2 Slags" ISIJ International. 33. 36-42 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 日野光兀: "CaO-Al_2O_3系スラグの硫黄溶解度" 材料とプロセス. 6. 218 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 日野光兀: "CaO-Al_2O_3-CaF_2系スラグのサルファイド・キヤパシティ" 材料とプロセス. 6. 219 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] 日野光兀: "CaO-Al_2O_3、CaO-Al_2O_3-CaF_2系スラグの成分活量" 材料とプロセス. 7. 41 (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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