Direct Preparation of Metal Sulfide Fine Particles by Electro-Spray Pyrolysis Method
| Project/Area Number |
05650750
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| Research Category |
Grant-in-Aid for General Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Research Field |
化学工学一般
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| Research Institution | HIROSHIMA UNIVERSITY |
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Principal Investigator |
OKUYAMA Kikuo Hiroshima University, Faculty of Engineering, Professor, 工学部, 教授 (00101197)
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| Project Period (FY) |
1993 – 1994
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| Project Status |
Completed (Fiscal Year 1994)
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| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 1994: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1993: ¥1,300,000 (Direct Cost: ¥1,300,000)
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| Keywords | Electro-spray / Metal surfide / Semiconductive particles / Pyrolysis / Functional particles / Droplet |
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| Research Abstract |
Metal sulfide semiconductive fine particles such as ZnS and CdS are very much attractive functional materials as photoconductor, catalysis, liquid crystal material and so on.In this study, fine ZnS and CdS particles were tried to prepare by electro-spray pyrolysis method, and the following results were obtained.
1)The electro-spray pyrolysis system was made by putting the high vitage to the needle to which the aqueous solution containing metal nitrate of Zn and Cd and thiourea was introduced by sringe pump.
2)The number and size distribution of generated droplets were measured by the differential mobility analyzer and condensation nucleous counter.With the increase in the viscosity of the solution, higher voltage was found to necessary to form the Taylor cone ofsolution at the tip of the needle.
3)Fine particles of ZnS AND CdS were able to be prepared by electro-spray pyrolysis method, and the particles obtained were spherical smaller than 0.1mum in diameter.The crystalline phase was found to have hexagonal under limited preparation conditions.
4)The size dependence of fluorescence spectrum of ultrafine ZnS and CdS was measured.
5)The sizes of particles obtained by the electro-spray pyrolysis method were compared with those obtained by the ultrasonic spray-pyrolysis method, and it was found that the electro-spray pyrolysis method can produce smaller particles by 1/5 in diameter compared with those by ultrasonic spray-pyrolysis method.
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Report
(3 results)
Research Products
(12 results)
