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The Development of Chemical Bimetal

Research Project

Project/Area Number 05804040
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 分離・精製・検出法
Research InstitutionKyoto Institute of Technology

Principal Investigator

YAMADA Takeshi  Kyoto Institute of Technology, Department of Textile Science, assistant professor, 繊維学部, 助教授 (60093358)

Co-Investigator(Kenkyū-buntansha) KIMURA Yoshiharu  Kyoto Institute of Technology, Department of Textile Science, professor, 繊維学部, 教授 (10132276)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1994: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1993: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsChemical Bimetal / Spiral Spring Chemical Bimetal / functionality material / sensor / iminodiacetic resin / イミノジ酢酸樹脂 / センサー / 機能性樹脂 / ポリスチレン / シュミレーション
Research Abstract

Bimetal is composed of two metal plates which have different rates of expansion. When the temperature rises, the length of two metal plates become different. Then, bimetal is curved. We extended this principle to the chemical reaction and developed the Chemical Bimetal. The Chemical Bimetal consisted of two plates. One plate does not change the length. On the contrary, another plate changes the length by chemical reaction, such as dissolution of reaction material or phase change.
The iminodiacetic resin Chemical Bimetal was developed. Chlorostylene, stylene, and divinylbenzene were polymerized on PET membrance. Next, this membrane were introduced iminodiacetate.
The Spiral Spring Chemical Bimetal has sharper sensitivity than the conventional Chemical Bimetal, because it has longer length. Also, it's output can take out from the rotation of spindle. Then, Iminodiacetic-stylene, stylene, and divinylbenzene were polymerized on PET membrane.
Computer simulations of the Chemical Bimetal in the case that sample solution were weak bases were done. Also, simulations which contain ion-pair formation reaction were done. These simulations well agreed with experimental results.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (7 results)

All Other

All Publications (7 results)

  • [Publications] 山田武: "7-(ドデセニル)-8-キノリノールを反応試薬とした銅イオン応答性ケミカルバイメタル" 分析化学. 45. 415-418 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Yamada: "Ion responsive chemical bimetal in “New functionality materials vol.C".Tsuruta,M.Doyama,and M.Seno ed." Elsevier, 261-266 (1993)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Yamada, T.Sakai, A.KIN,and M.Sato: "Copper ion-responsive chemical bimetal using 7- (dodecenyl) -8-quinolinol." Bunseki. 43,5. 415-418 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Yamada and Y.Kimura: "Ion responsive chemical bimetal" in "New functionality materials Vol. C" , T.Tsuruta, M.Doyama, and M.Sano ed.Elsevier, 261-266 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 山田 武: "7-(ドデセニル)-S-キノリノールを反応試薬とした銅イオン応答性ケミカルバイメタル" 分析化学. 43. 415-418 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Yamada: "Ion responsive chemical bimetal in "New functionalit:materials vol.C".Turuta,M.Doyama,and M.Seno ed." Elsevier, 261-266 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 山田武: "LIX26を用いた銅イオン感応性ケミカルバイメタル" 分析化学. 43 (印刷中). (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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