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Investigation on Self-Organization Process of Buckminsterfullerence in Space around an Arc Discharge

Research Project

Project/Area Number 05808039
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field プラズマ理工学
Research InstitutionShizuoka University

Principal Investigator

MIENO Tetsu  Shiizuoka Univ., Dept.of Physics, Associate Professor, 理学部, 助教授 (50173993)

Co-Investigator(Kenkyū-buntansha) SAKURAI Atsushi  Shiizuoka Univ., Dept.of Physics, Associate Professor, 理学部, 助教授 (70021938)
ASANO Tsutomu  Shiizuoka Univ., Dept.of Physics, Associate Professor, 理学部, 助教授 (10021940)
Project Period (FY) 1993 – 1994
Project Status Completed (Fiscal Year 1994)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1994: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1993: ¥1,500,000 (Direct Cost: ¥1,500,000)
Keywordsfullerene / cagelike cabon molecule / continuous production / automatic production / chip type carbon material / material recycling / arc discharge / self-organizing process / 自己形成 / アーク放電 / C_<60> / 自己形成過程 / ハイヤーフラーレン / 原料リサイクル / チップ状炭素
Research Abstract

An automatic producer of fullerence by arc discharge in a closed chamber is developed and production process and parameter dependence of production rate of C60 are investigated. As a result, effective production of C60 is obtained when effective sublimation of carbon atoms from carbon meterials is carried out, when helium gas pressure is adequate to carbon stoms colliding each other frequently in high temperature atmosphere and when impurity gas such as oxygen and water gases are scacely included. In order to realize continuous production for long time, dropping material type new fullerence producer is developed and we succeeded in the synthesis of fullerenes from chip type carbon materials. Production rate is improved remarkably by a JxB type new arc discharge method. It is also improved by a pulse modulated discharge. These results will be useful for industrial scale production of many kinds offullerenes.

Report

(3 results)
  • 1994 Annual Research Report   Final Research Report Summary
  • 1993 Annual Research Report
  • Research Products

    (32 results)

All Other

All Publications (32 results)

  • [Publications] T. Mieno, T. Asano, A. Sakurai: "Continuous Production of Fullerene by Evaporation of Carbon Powder and Carbon Chips in an Arc Discharge" Advanced Materials,'93 I/B. 14B. 1201-1204 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T. Mieno: "Continuous Synthesis of Fullerenes" New Technology Japan, JETRO. 21. 19-19 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 三重野 哲: "電極への炭素再付着を抑えたアーク放電によるフラーレン自動合成実験" 第7回C_<60>総合シンポジウム講演要旨集. 242-245 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T. Mieno: "Automatic Production of Fullerone by a JxB Arc Jet Discharge Preronting Carron Vapor from Depositing on the Cathode" Fullerene Sci. and Tech.3(in press). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 三重野哲,出羽健志,桜井厚: "繰り返し低動工場中アーク放電によるフラーレン合成" Proc. 11th ISAS Space Utilization Symp.238-241 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T. Mieno, A. Sakurai: "Fluorination of Fullerene Film by CF_4 Plasma" Jpn. J. Appl. Phys. 34(in press). (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] 三重野 哲: "フラーレンの合成とプラズマ反応(第1回プラズマエレクトロニクスサマースクール、分筆)" 応用物理学会, P.5 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Miyauchi, T.Mieno: "Measurement of Production Rate of C_<60> in Case of an Arc Discharge in a Closed Chamber." Proc.6th Sympo., Plasma Sci.for Materials. SPSM-6. 107-112 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno: "Automatic Production of Buckminster - Fullerenes by Use of an Arc Discharge in a Closed Chamber." J.Phys.Soc.Jpn.Vol.62. 4146-4147 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno: "Production of Fullerene and Its Reaction in a Plasma (in Japanese)." Text of Plasma Electronics Summer (Society of Applied Physics). 69-74 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno: "Automatic Production of Fullerene Preventing Deposition of Carbon Atoms on a Cathode (in Japanese)" Proc.7th Symp.C_<60>. 242-245 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno, A.Asano: "Fluorination of Fullerene Film by CF_4 Plasma" Abstract 7th Symp.Plasma Science for Materials. 60 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno, Y.Kuroki, T.Hibino: "Preparatory Experiment of Fullerene Production by Use of Solar Voltaic Power (in Japanese)." Proc.1994 JSES/JWEA Joint Conf.121-124 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno, T.Dewa, A.Sakurai: "Production of Fullerene in Repetitive low-Gravitational Field (in Japanese)." Proc.11th ISAS Space Utilization Sympo.238-241 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno, T.Dewa, A.Sakurai: "Production of Fullerene in Repetitive low-Gravitational Field (in Japanese)." Proc.8th Symp.C_<60>. 70-73 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno, A.Sakurai: "Fluorination of Fullerene Film by Use of CF4 Plasma (in Japanese)." Proc.8th Symp.C_<60>. 184-189 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno, T.Asano, A.Sakurai: "Continuous Production of Fullerense by Evaporation of Carbon Powder and Carbon Chips in an Arc Discharge." Advanced Materials, '93, I/B. Vol 14B. 1201-1204 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] T.Mieno: "Automatic Production of Fullerene by a JxB Arc Jet Discharge Preventing Carbon Vapor from Depositing on the Cathode"" Fullerence Science & Technology. Vol.3(in press). (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1994 Final Research Report Summary
  • [Publications] Y.Miyauchi,T.Meino: "Measurement of Production Rate of C_<60> incase of an Arc Discharge in a Closed Chamber" Proc.6th Symp.Plasma Science for Materials.SPSM-6. 107-112 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 三重野哲,高塚博幸,条川恵理子,浅野勉: "閉鎖容器中アーク放電によるバックミンスターフラーレン(C_<60>,C_<70>)の合成と研究成長" J.Plasma and Fusion Res.69. 793-800 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Mieno: "Automatic Production of Buckminsterfullerene by Use of an Arc Discharge ina Closed Chamber" J.Phys.Soc.Jpn.62. 4146-4147 (1993)

    • Related Report
      1994 Annual Research Report
  • [Publications] 三重野哲,黒木康臣,日比野武: "太陽光発電電力を用いたフラーレン合成の予備実験" 太陽/風力エネルギー講演論文集(1994). 121-124 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Mieno: "Automatic Production of Fullerene by J×B Arc Jet Discharge Preventing Carron Vapor from Depositing on the Cathade" Fullerene Science & Technology. 3(in press). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Mieno: "Continuoas Synthesis of Fullerene" New Technology Japan,JETRO. 21. 19-19 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 三重野哲: "フラーレンの合成とプラズマ反応 第1回プラズマエレクトロニクス(サマースクールテキスト,分筆)" 応用物理学会, 5 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 三重野 哲: "閉鎖容器中アーク放電によるバックシンスターフラーレン(C_<60>,C_<70>)の合成と結晶成長" プラズマ・核融合学会誌(論文). 69. 793-800 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Mieno: "Automatic Production of Buckminsterfulkrenes by Use of an Arc Discharge in a closed chamber" J.Phys.Soc.Jpn.62. 4146-4147 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Mieno: "Continuous Production of fulkerenes by Evaporation of Carbon Powder and Carbon Chips in an Arc Discharge" Proc.3rd IUMRS Int.Conf.Advanced Materials,Tokyo,1993. (出版予定). P.4 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] N.Sato: "Production of C_<60> Plasma." Proc.NATO Advanced Res.Workshop,France,1993. (出版予定). (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] Y.Miyauchi: "Measurement of Production Rate of C_<60> in Case of an Arc Discharge in a Closed Chamber" Proc.6th Sympo.Plasma Sci.for Materials. SPSM-6. 107-112 (1993)

    • Related Report
      1993 Annual Research Report
  • [Publications] T.Mieno: "Ionization of Buckminsterfullerene C_<60> in a Noble Gas Plasma" Rep.Faculty of Science,Shizuoka Univ.28. 25-29 (1994)

    • Related Report
      1993 Annual Research Report
  • [Publications] 三重野 哲: "第6回C_<60>総合シンポジウム講演要旨集" 日本化学会C_<60>研究会, 258(4) (1994)

    • Related Report
      1993 Annual Research Report

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Published: 1993-04-01   Modified: 2016-04-21  

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