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Development of High Performance Metallic Materials through Nano-crystalline Structure Control

Research Project

Project/Area Number 06044019
Research Category

Grant-in-Aid for international Scientific Research

Allocation TypeSingle-year Grants
SectionJoint Research
Research InstitutionTohoku University

Principal Investigator

FUJIIMORI Hiroyasu  Institute for Materials Research, Tohoku University, Professor, 金属材料研究所, 教授 (60005866)

Co-Investigator(Kenkyū-buntansha) 琴 榮和  韓国科学技術研究院(KIST), 研究院
文 仁ごう  韓国科学技術研究院(KIST), 研究員
金 喜中  韓国科学技術研究院(KIST), 研究員
盧 秦ふちん  韓国科学技術研究院(KIST), 研究員
SHIMA Toshiyuki  Institute for Materials Research, Tohoku University, 金属材料研究所, 助手 (50261508)
HANADA Shyuzi  Institute for Materials Research, Tohoku University, 金属材料研究所, 教授 (10005960)
MASUMOTO Tuyoshi  The Research Institute of Electric and Magnetic Materials, 所長 (20005854)
CHANG J.Y  Division of Metals, Korea Institute of Science and Technology
MOON I.G  Division of Metals, Korea Institute of Science and Technology
KIM H.S  Division of Metals, Korea Institute of Science and Technology
NOH T.H  Department of Metallurgical Engineering, Andong National University
鄭 榮薫  韓国科学技術研究所(KIST), 研究員
盧 泰ふちん  韓国科学技術研究所(KIST), 研究員
姜 日求  韓国科学技術研究所(KIST), フェロ
盧 泰ふぁん  KIST, 研究員
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥5,400,000 (Direct Cost: ¥5,400,000)
Fiscal Year 1996: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1995: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1994: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsHigh Strength Al Base Alloy / High Temperature Nb_3 Al Compound / Nano-crystalline Material / Structural Control / High Mechanical Strength / Ductility / Soft Magnet / Hard Magnet / 新素材 / アモルファス / 人口格子 / 強強度アルミ合金 / ナノ組織制御 / 強靭性 / 超強度 / メカニカル グライディング / 液体超急冷
Research Abstract

We investigated the effect of nano-crystalline structural control on mechanical, magnetic and electrical properties of various types of metallic materials. The results obtained are as follows :
1) The methods for nano-crystalline structural control : The methods ; a mechanical alloying followed by consolidation by HIP for Nb_3 Al based nano-crystalline intermetallic compounds, a crystallization of amorphous metal followed by consolidation for Al based nano-crystalline bulk alloys, a N or O reactive sputtering for Fe based nano-crystalline or granular alloys thin films, were investigated, respectively. The alloy compositions were also investigated. Through these investigations, the following properties were obtained.
2) Nb_3 Al based nano-crystalline intermetallic compounds : Mechanically very strong and ductile properties, typical in about 60% elongation, were obtained.
3) Al based nano-crystalline bulk alloys : A nano-crystalline bulk Material of Al_<92>Mn_6Ce_2 Al_<94.5>Cr_3Ce_1Co_<1.5> and a nano-structurally mixed amorphous-crystalline bulk material of Al_<94>V_4Fe_2 were found to show mechanically very strong and ductile properties. In addition, a strong effect of rare earth elements on the formation of nano-crystalline state was found in the Al-Si based alloys.
4) Fe based nanocrystalline magnetic alloys : It was found to show high magnetic flux density and high permeability in nano-crystalline thin Fe- (Hf, Zr, Nb) -C-N alloys, high electrical resistivity and giant magnetoresistace in metal-insulator nano-granular thin films of a Fe-MgO system, high coercivity in structurally nano-columnar FeNdB/Cr multilayred thin films, and permanent magnetic properties with high magnetic flux density in nano-crystalline bulk materials of Fe-Nd-B alloys.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (57 results)

All Other

All Publications (57 results)

  • [Publications] H.Fujimori: "Tunnel-type GMR in Co-Al-O insulated granular system -Its oxygen-concentration dependence" Journal of Magnetism and Magnetic Materials. 156. 311-314 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Mitani: "Spin-dependent tunneling phenomena in insulating granular systems" Journal of Magnetism and Magnetic Materials. 165. 141-148 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 大沼繁弘: "Co-Al-O系 グラニュラー構造膜の高周波軟磁気特性" 日本応用磁気学会誌. 20. 489-492 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 小林伸聖: "Fe-X-O(X=Y,Nd,Sm,Gd,Tb,Dy)系高電気抵抗膜の軟磁気特性" 日本応用磁気学会誌. 20. 469-472 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 小林伸聖: "Fe-X-O(X=Y,Nd,Sm,Gd,Tb,Dy)系薄膜の磁気特性に及ぼすNi,Pd,Ptの添加効果" 日本応用磁気学会誌. 20. 473-476 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Ohnuma: "High-Frequency magnetic properties in metal-nonmetal granular films (invited)" Journal of Applied Physics. 79. 5130-5135 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Wada: "High Temperature Deformation of Nb_3Al/Nb Alloys" Materials Science Forum. 233-234. 311-318 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "Soft and Hard Magnetic Properties of Nanocrystalline Fe-M-B (M=Zr,Nd) Base Alloys Containing Intergranular Amorphous Phase" Science Report RITU. A41. 143-156 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "Formation and High strength of Nanoamorphous Structure in Rapidly Solidified Al-Cr-Co-Ce and Al-V-Fe Alloys" International Journal of Rapid Solidification. 103-120 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "High Mechanical Strength of Al- (V,Cr,Mn) - (Fe,Co,Ni) Quasicrystalline Alloys Prepared by Rapid Solidification" Materials Transactions,JIM. 37. 1287-1292 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "Synthesis and high mechanical strength of Al-based alloys consisting mainly of nanogranular amorphous particles" Materials Science and Engineering. A217/218. 401-406 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Fujimori: "Tunnel-type GMR in Co-Al-O insulated granular system -Its oxygen-concentration dependence" Journal of Magnetism and Magnetic Materials. 156. 311-314 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Mitani: "Spin-dependent tunneling phenomena in insulating granular systems" Journal of Magnetism and Magnetic Materials. 165. 141-148 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Ohnuma: "Soft Magnetic Properties at High Frequency of Co-Al-O Films with Granular Structure" Journal of Magnetic Society of Japan. 20. 489-492 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Kobayashi: "Soft Magnetic Properties of Highly Electrically Resistive Fe-X-O (X=Y,Nd, Sm, Gd, Tb, Dy) Films" Journal of Magnetic Society of Japan. 20. 469-472 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] N.Kobayashi: "Effect of Ni, Pd, or Pt Addition on the Magnetic Properties of Fe-X-O (X=Y,Nd, Sm, Gd, Tb, Dy) Films" Journal of Magnetic Society of Japan. 20. 473-476 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] S.Ohnuma: "High-frequency magnetic properties in metal-nonmetal granular films (invited)" Journal of Applied Physics. 79. 5130-5135 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Wada: "High Temperature Deformation of Nb_3Al/Nb Alloys" Materials Science Forum. 233-234. 311-318 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "Soft and Hard Magnetic Properties of Nanocrystalline Fe-M-B (M=Zr, Nd) Base Alloys Containing Intergranular Amorphous Phase" Science Report.RITU. A42. 143-156 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "Formation and High Strength of Nanoamorphous Structure in Rapidly Solidified Al-Cr-Co-Ce ad Al-V-Fe Alloys" International Journal of Rapid Solidification. 103-120 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "High Mechanical Strength of Al- (V,Cr, Mn) - (Fe, Co, Ni) Quasicrystalline Alloys Prepared by Bapid Solidification" Materials Transactions. JIM. 37. 1287-1292 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] A.Inoue: "Synthesis and high mechanical strength of Al-based alloys consisting mainly of nanogranular amorphous particles" Materials Science and Engineering. A217/218. 401-406 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Fujimori: "Tunnel-type GMR in Co-Al-O insulated granular system-Its oxygen-concentration dependence" Journal of Magnetism and Magnetic Materials. 156. 311-314 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Mitani: "Spin-dependent tunneling phenomena in insulating granular systems" Journal of Magnetism and Magnetic Materials. 165. 141-148 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 大沼繁弘: "Co-Al-O系グラニュラー構造膜の高周波軟磁気特性" 日本応用磁気学会誌. 20. 489-492 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 小林伸聖: "Fe-X-O(X=Y,Nd,Sm,Gd,Tb,Dy)系高電気抵抗膜の軟磁気特性" 日本応用磁気学会誌. 20. 469-472 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 小林伸聖: "Fe-X-O(X=Y,Nd,Sm,Gd,Tb,Dy)系薄膜の磁気特性に及ぼすNi,Pd,Ptの添加効果" 日本応用磁気学会誌. 20. 473-476 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Ohnuma: "High-frequency magnetic properties in metal-nonmetal granular films (invited)" Journal of Applied Physics. 79. 5130-5135 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Wada: "High Temperature Deformation of Nb_3Al/Nb Alloys" Materials Science Forum. 233-234. 311-318 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Inoue: "Soft and Hard Magnetic Properties of Nanocrystalline Fe-M-B (M=Zr,Nd) Base Alloys Containing Intergranular Amorphous Phase" Science Report RITU. A42. 143-156 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Inoue: "Formation and High strength of Nanoamorphous structure in Rapidly Solidified Al-Cr-Co-Ce and Al-V-Fe Alloys" International Journal of Rapid Solidification. 103-120 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Inoue: "High Mechanical Strength of Al- (V,Cr,Mn) - (Fe,Co,Ni) Quasicrystalline Alloys Prepared by Ropid Solidification" Materials Transactions,JIM. 37. 1287-1292 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] A.Inoue: "Synthesis and high mechanical strength of Al-based alloys consisting mainly of nanogranular amorphous particles" Materials Science and Engineering. A217/218. 401-406 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Fujimori: "Structure and 100MHz soft magnetic properties in multilayers and granular thin films" Scripta Met. Mater.33. 1625-1636 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S. Mitani,H. Fujimori,S. Furukawa and S. Ohnuma: "High electrical resistivity and Mossbauer effect of soft magnetic Fe-SiO2 granular alloys" J. Magn. Magn. Mater.140-144. 429-430 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H. Fujimori,S. Mitani and S. Ohnuma: "Tunnel-type GMR in metal-nonmetal granular alloy thin films" Mater. Sci. Eng.B31. 219-223 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S. Ohnuma,H. Fujimori,S. Furukawa S. Mitani and T. Masumoto: "Co-(N or O) based granular thin films their magnetic properties" J. Alloys and Compounds. 222. 167-172 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] A. Kojima,H, Horikiri,Y. Kawamura,A. Inoue,A. Makino,T. Masumoto: "Soft-magnetic properties of nanocrystalline bcc Fe-(Nb,Zr)-B bulk alloys consolidated by warm extrusion" Materials Transactions,JIM. 36. 945-951 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] A. Makino,J. Park,A. Makino,T. Masumoto: "Nanocrystalline mixed structure prepared by crystallization of Cu-Ag-La amorphous alloys" Materials Transactions,JIM. 36. 697-704 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y. Abe,S. Hanada,S. Saito,K. Hirano and N. Kobayashi: "Composition at Nb_3Al phase boundaries 1873K in the Nb-Al binary phase diagram" Scripta Met. Mater.32. 27-30 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Oikawa,S. Hanada,T. Sakai and S. Watanabe: "Dynamic evolution of microstructures in superplastic Ni_3Al" Mater. Trans. ,JIM. 36. 1140-1148 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y. Abe,S. Saito and S. Hanada: "Fabrication and high temperature strength of Nb_3Al by a modified reactive sintering process" Mater. Manufact. Processes,. 10. 1153-1167 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S. Hanada,T. Tabaru and R. Gnanamoorthy: "Processing and properties of Nb_3Al" Acta Metall. Sinica,. 8. 477-487 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] R. Gnanamoorthy and S. Hanada: "Microstructure and strength of binary and tantalum alloyed two-phase Nb_<ss>/Nb_3Al base alloys" Mater. Sci. Eng. ,in press.

    • Related Report
      1995 Annual Research Report
  • [Publications] T. Shima,E. Aoyagi and H. Fujimori: "Effect of Sm Addition on Magnetostriction and Microstructure of Fe-Co Alloys," J. Korean Magnetic Society. 5. 726-729 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Dong-Wha Kum et. al: "Determination of Ti solubility in alpha-Aluminnum During High Energy Ball Milling" Scripta Metall & Mater. ,. (in press.).

    • Related Report
      1995 Annual Research Report
  • [Publications] 嶋敏之: "Fe-Co合金の多層化による磁歪の制御" 日本応用磁気学会誌. 18. 403-406 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Shima: "Magnetostriction and coercivity of Fe-Co-RE alloys prepared by a high rate sputtering method" Materials Science and Engineering. A181/A182. 962-965 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Makino: "Microstructure of nanocrystalline bcc Fe-M-B(M=Nb,Hl)soft magnetic alloys" Materials Science and Engineering. A179/A180. 495-500 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] A.Makino: "Magnetic properties and microstructure of nanocrystaloline bcc Fe-M-B(M=Zr,Hf,Nb)alloys" J. of Magnetism and Magnetic Materials. 133. 329-333 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.Suzuki: "The role of boron in nanocrystalline Fe-Zr-B soft magnetic alloys" Matcrials Science and Engineering. A179/A180. 501-505 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Abe: "Compositions at Nb3Al phase boundary at 1879K in the Nb-Al binary phase diagram" Scripta Metallurgica et Materialia. 32. 27-30 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Hanada: "High-temperature deformation ofNb3Al alloys" Intermetallics. 2. 155-165 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] G.Moon: "Improvement of superplastic properties of an Al-Cu-Li-Mg-Zr alloy by a modified thermalmechnanical processing" Materials Sceience Forum. 170/172. 255-260 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.S.Shin: "The effects of Ag addition on the structure and mechanical properties of aluminium-lithium alloys" Korean J. of Materials Research22GD09:4. 556 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.Y.Kim: "Magnetic properties behavior in Fe_<88>Zr_7B_4Cu_1 nano-crystalline alloy prepared by different postanneal cooling rates" J. of Applied Physics. 75. 6943-6945 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] J.S.Lee: "Soft magnetic properties of Fe-B-M-Cu(M=Hf,Zr,Nb)alloys with nanocrystalline and amorphous hybrid structure21GC11:IEEE Transactions on Magnetics" 30. 4845-4847 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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