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EXERGY ENHANCEMENT AND REPRODUCTION THROUGH HYDROGEN PRODUCTION

Research Project

Project/Area Number 06246104
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionYokohama National University

Principal Investigator

OHYA Haruhiko  Yokohama National University, Department of Chemical Engineering, Professor, 工学部, 教授 (40017950)

Co-Investigator(Kenkyū-buntansha) MOROOKA Shigeharu  Kyusyu University, Graduate School of Engineering, Professor, 工学部, 教授 (60011079)
INUI Tomoyuki  Kyoto University, Graduate School of Engineering, Professor, 大学院・工学系, 教授 (60025989)
YOSHIDA Kunio  University of Tokyo, Graduate School of Engineering, Professor, 大学院・工学系, 教授 (70010808)
OCHI Kenji  Nihon University, Department of Industrial Chemical, Professor, 理工学部, 教授 (10059389)
TSUJIKAWA Shigeo  University of Tokyo, Graduate School of Engineering, Professor, 大学院・工学系, 教授 (20011166)
後藤 孝  東北大学, 金属材料研究所, 助教授 (60125549)
Project Period (FY) 1994 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥125,500,000 (Direct Cost: ¥125,500,000)
Fiscal Year 1997: ¥39,100,000 (Direct Cost: ¥39,100,000)
Fiscal Year 1996: ¥33,000,000 (Direct Cost: ¥33,000,000)
Fiscal Year 1995: ¥27,400,000 (Direct Cost: ¥27,400,000)
Fiscal Year 1994: ¥26,000,000 (Direct Cost: ¥26,000,000)
KeywordsExregy / Hydrogen Energy / Thermochemical cycle / Inorganic Separation Membrane / Cottosion Resistant / Second Virial Coefficient
Research Abstract

The representative results are summarized as :
(1) The reaction characteristics of solid-reactants for UT-3 process were improved by ultrasonic treatment and addition of graphite and lauric acid through the alkoxide method. Thermal and exergy efficiencies of the Process were calculated. Combination of the process with a nuclear reactor is considered, and the system to adjust electricity generation to match load fluctuation is proposed.
(2) Rapid synthesis of hydrogen and /or syngas by catalytic reforming of methane and a natural-gas-like mixture was investigated adopting our newly developed four-component catalyst (Ni-CeィイD22ィエD2OィイD23ィエD2-Pt-Rh). In this system, the exergy efficiency was estimated to be as high as 80%.
(3) Halogen corrosion behaviors of pure metal films, and Nimonic80A among Ni-base heat-resistant alloys were selected as corrosion-resistant materials at high temperature. It was found that Nimonic80A could be used as the structural material for the UT-3 process plant equi … More pment in all environment.
(4) MOCVD was applied to improve the corrosion resistance of Nimonic80A in HBr-HィイD22ィエD2O-NィイD22ィエD2 atmosphere at high temperature. Ir and/or YSZ coating on the alloy by MOCVD were effective to prevent the corrosion in the UT-3 condition at 1073K.
(5) Characteristics of zirconia-silica composite membrane prepared by the alkoxide method were investigated. Higher zirconia content in the zirconia-silica composite membranes showed the high permeance of HィイD22ィエD2, more than 10ィイD1-6ィエD1mol/(mィイD12ィエD1・Pa・s). The maximum separation factors for HィイD22ィエD2 over HィイD22ィエD2O and for HィイD22ィエD2 over HBr, 4.1 and 259.
(6) Amorphous silica-based membranes prepared by CVD method were modified so as to acquire HィイD22ィエD2-or HィイD22ィエD2O selectivity and applied to hydrogen recovery at 220-560℃ from HィイD22ィエD2-HィイD22ィエD2O-HBr mixture. Exergy losses for the hydrogen separation were calculated for plausible cases to be smallest for a two-stage separation system, where steam is separated from a HィイD22ィエD2-HィイD22ィエD2O-HBr mixture using a HィイD22ィエD2O-selective membrane before HィイD22ィエD2 separation. Less

Report

(5 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (92 results)

All Other

All Publications (92 results)

  • [Publications] 鶴岡 巧、横田雅志、桜井 誠、堤 敦司、吉田邦夫: "アルコキシド法によるCa(OH)2微粒子の生成-超音波照射の効果-"粉体工学会誌. 34(3). 165-169 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 峯雄知子、堤 敦司、吉田邦夫: "三相アルコキシド法によるTiO2単分散微粒子合成"粉体工学会誌. 34(3). 160-164 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Sato,R.Sasaki,K,Takeda et al.: "Preparation of Solid Reactants for UT-3 Thermochemiccal Hydrogen Production Cycle"4th Japan-Korea Joint Symposium '97 on Hydrogen Energy ,August29,1997. 107-111 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Matsumura,E.Bilgen, et al.: "Process Design of Solar-Power Thermochemical Hydrogen Production Using UT-3 Cycle"4th Japan-Korea Joint Symposium '97 on Hydrogen Energy ,August29,1997. 213-219 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 高平史郎、篠原 正、辻川茂男: "「Nimonic80Aの(H2O+O2+Br2)環境下での高温腐食挙動に対する合金元素の影響」"第44回材料と環境討論会講演集. 233-236 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 後藤 孝、佐々木拓也、平井敏雄: "ステンレス鋼、インコネルおよびインコロイ合金の臭素を含む雰囲気での高温腐食"日本金属学会誌. 61(5). 432-438 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Narushima,T.Goto,T,Hirai and Y.Iguchi: "High-Temperetue Oxidation of Silicon Carbide and Silicon Nitride Materials Transactions"J.I.M.. 38(10). 821-835 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 後藤 孝、小野 敬、平井敏雄: "MOCVDにより合成したIr-cコンポジット膜の微細構造と電気的性質"粉体および粉末冶金. 45(1). 20-24 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Goto: "High-Temprature Oxdation of CDV Silicon Carbide"9th Pacific Coast Regional Meeting and Basic Science Division Meeting of the American Ceramic Society,20th Richrad M. Fulrath Pacific Symposium. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 乾 智行: "天然ガスからの液体燃料合成"J.Jpn.Petrol.Inst.. 40(4). 243-251 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tomoyuki Inui: "Rapid Catalitic Process in reforming of Methane and Successive Synthesis of Methanol and its Derivatives"Appl.Surf.Sci.. 121/122. 26-33 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Tomoyuki Inui et al.: "Ultra-Rapid Synthesis of Syngas by the Catalytic Reforming of Methane Enhance by In-situ Heart Supply though Combusion"Korean J.Chem.Eng.. 14(6). 441-444 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Chiaki Yokoyama and Mitsuo Takahashi: "Viscosity of CHF3 in the critical region"International Jounal of Thermophysics. 18(6). 1369-1385 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Akibumi Kumagai et al.: "Falling capillary tube viscometer suitable for liquids at high pressure"Review of Scientific Instrument. 69(2). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Naomi Shibasaki-Kitagawa et al.: "Viscosity of HFC-134a(1,1,1,2-tetrafluoroethane) under high pressure"International Journal of Thermophysics. 19(5). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Och,K.and K.Kojima: "Second Virtual Coeffiicients for Systems Containing Br2,HBr and Water"The Second China-Korea Conference on Separation Science and Technology Qing*ao(China). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 天野忠昭 et al.: "予備酸化をしたNi-20Cr-1Si-0.5(La,Gd,Hf)合金のN2-H2O-HBr雰囲気における高温腐食"第44回材料と環境討論会. 231-232 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 吉田保之 et al.: "Ni-CrおよびNi-Si系合金のN2-H2O-HBrにおける高温腐食"日本MRS学術シンポジウム講演要旨集. 91 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 天野忠昭、吉田保之、関屋昭彦、西原克博、後藤孝、平井敏雄: "微量の活性元素を添加したNi-20Cr-3Si合金のN2-H2O-HBr雰囲気における高温腐食"Journal of Advanced Science. 10. to be published (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Zhongyan Li,K.KUSAKABE and Shigeharu MOROOKA: "Pore Structure and Permeance of Amorphous Si-C-O Membranes with Durability at Elevated Temperature"Sep.Sci.Technol.. 32(7). 1233-1254 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Bongkuk SEA,Kazuki ANDO,K.KUSAKABE and S.MOROOKA: "Formation of Hydrogen Permselective Hydrophobic Membrane in Macropores of a Phenyl-Substituted Ethoxysilanes with Cross-Flow Through a Porous Support Wall"Euromembrane97. 130(2). 263 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Bongkuk SEA,Kazuki ANDO,K.KUSAKABE and S.MOROOKA: "Pore Size Control and Gas Permeation Kinetics of Silica Membrane by Pyrolys of Phenyl-Substituted Tube by Chemical Vaper Desition"J.Menb.Sci.. 130(2). 41-52 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Onuki et al.: "Gas Permeation through CVD Modified Andic Alumina membrane"J.Chem.Eng.Jpn.. 30(2). 359-362 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Onuki et al.: "Thermochemical Water-Splitting for Hydrogen Production"Prc.8th International Topical Meeting on Nuclear Reactor Thermal-Hydraulics(NURETH-8),vol 3,Sep.30-Oct.4,1997,Kyoto. 1803-1808 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Ohya,H.Nakajima,H.Ohashi,M.Aihara: "Hydorogen Purification using Zirconia-Silica Composite Memberane for Themochemical process"Int.J.Hydrogen Energy. 22(5). 509-515 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Ohya,J.Fun,H.Hayakawa,K.Ito: "Methanation of Carbon dioxide by usuing membrane reactor integrated with water vapor permselective membtane and its analysis"J.Memb.Sci.. 131. 237-247 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 二川ら: "傾斜濃度Fe-Si合金の沸騰濃硫酸中耐食性試験"材料と環境. 46(10). 669-674 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Tsuruoka, M. Yokota, M. Sakurai, A. Tsutsumi and K. Yoshida: J. Soc. Powder Technol., Japan. vol.34, no.3. 165-169 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Mineo, A. Tsutsumi and K. Yoshida: J. Soc. Powder Technol., Japan. vol.34, no.3. 160-164 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Sato, T. Sasaki, K. Taked et al.: "Preparation of Solid Reactants for UT-3 Thermochemical Hydrogen Production Cycle"4ィイD1thィエD1 Japan-Korea Joint Symposium '97 on Hydrogen Energy, August 29,1997. 107-111 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y. Matsumura, E. Bilgen, et al: "Process Design of Solar-Powered Thermochemical Hydrogen Production Using UT-3 Cyclce"4ィイD1thィエD1 Japan-Korea Joint Symposium '97 on Hydrogen Energy, August 29,1997. 213-219 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Goto, T. Sasaki and T. Hirrai: "High temperature Corrosion of Stainless Steel, Inconel and Incoly Alloys in Bromine-Containing Atmosphere"J. Jpn. Inst. Metals. vol.61, No.5. 430-436 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Narushima. T. Goto, T. Hirai and Y. Iguchi: "High-Temperature Oxidation of Silicon Carbide and Silicon Nitride Materials"J.I.M.. vol.38, No.10. 821-835 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Goto: "High-Temperature Oxidation of CVD Silicon Carbide, 49ィイD1thィエD1 Pacific Coast Regional Meeting and Basic Science Division Meeting of the American Ceramic society"20ィイD1thィエD1 Richard M. Fulrath Pacific Symposium. (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Inui: J. Jpn. Petrol. Inst. vol.40, No.4. 243-251

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Inui: "Rapid Catalytic Process in Reforming of Methane and Successive Synthesis of Methanol and its Derivatives"Appl. Surf. Sci.. vol.121/122. 26-33 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T. Inui, et al: "Ultra-Rapid synthesis of Syngas by the Catalytic Reforming of Methane Enhanced by In-situ Heat Supply through Combusion"Korean J. Chem. Eng.. vol.14, no.6. 441-444 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] C. Yokoyama and M. Takahashi: "Viscosity of CHF3 in the critical region"International Journal of Thermophysics. vol.18, no.6. 13969-1385 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A. Kumagai et. al: "Falling capillary tube viscometer suitable for liquids at high pressure"Review of Scientific Instrument. vol.69, No.2. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N. Shibasaki et. al.: "Viscosity of HFC-134a (1,1,1,2-tetrafluoroethane) under high pressure"International Journal of Thermophysics. vol.19, No.5. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K. Ochi and K. Kojima: "Second Virial Coefficients for systems Containing Br2, HBr and Water, The Second China-Korea Conference on Separation and Technology"Qingdao(China). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Z. Li, K. Kusakabe and S. Morooka: "Pore Structure and Permeance of Amorphous Si-C-O Membranes witeh High Durability at Elevated Temperature"Sep. Sci.Technol.. vol.32, No.7. 1233-1254 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] B, Sea, K. Ando, K. Kusakabe and S. Morooka: "Pore Size Control and Permeation Kinetics of Silica Membranes by Pyrolysis of Phenyl-Substituted Ethoxysilanes with Cross-Row through a Porous Support Wall"J. Memb. Sci.. vol.130, No.1. 41-52 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K. Onuki et al.: "Gas Permeation through CBD Modified Anodic Alumina Membrane"J. Chem. Eng. Jpn.. vol.30, No.2. 359-362 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K. Onuki et al.: "Thermochemical Water-Splitting for Hydrogen Production"Proc. 8th International Topical Meeting on Nuclear_Reactor Thermal-Hydraulics(NURETH-8) Kyoto. vol.3. 1803-1808 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H. Ohya H. Nakajima, H. Ohashi et al.: "Hydrogen purification using Zirconia-Silica composite Membrane for Thremochemical process"Int. J. Hydrogen Energy. vol.22, No.5. 509-515 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H. Ohya J. Fun, H. Kawamura, K. Itoh: "Methanation of Carbon dioxide by using membrane reactor integrated with water vapor permselective membrane and its analysis"J. Memb. Sci.. vol.131. 237-247

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 鶴岡 巧、横田雅志、桜井 誠、堤 敦司、吉田邦夫: "アルコキシド法によるCa(OH)2微粒子の生成-超音波照射の効果-" 粉体工学会誌. 34(3). 165-169 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 峯尾知子、堤 敦司、吉田邦夫: "三相アルコキシド法によるTiO2単分散微粒子合成" 粉体工学会誌. 34(3). 160-164 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Sato, R.Sasaki, K.Takeda, et.al: "Preparation of Solid Reactants for UT-3 Thermochemical Hydrogen Production Cycle" 4th Japan-Korea Joint Symposium^'97 on Hydrogen Energy,August 29,1997,. 107-11 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Matsumura, E.Bilgen, et.al: "Process Design of Solar-Powered Thermochemical Hydrogen Production Using UT-3 Cycle" 4th Japan-Korea Joint Symposium^'97 on Hydrogen Energy,August 29,1997,. 213-219 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 高平史郎、篠原 正、辻川茂男: "「Nimonic80Aの(H2O+O2+Br2)環境下での高温腐食挙動に対する合金元素の影響」" 第44回材料と環境討論会講演集. 233-236 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 後藤 孝、佐々木拓也、平井敏雄: "ステンレス鋼、インコネルおよびインコロイ合金の臭素を含む雰囲気での高温腐食" 日本金属学会誌. 61(5). 432-438 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Chiaki Yokoyama and Mitsuo Takahashi: "Viscosity of CHF3 in the critical region" International Journal of Thermophysics. 18(6). 1369-1385 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Akibumi Kumagai et.al.: "Falling capillary tube viscometer suitable for liquids at high pressure" Review of Scientific Instrument. 69(2). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Naomi Shibasaki-Kitagawa et.al: "Viscosity of HFC-134a(1,1,1,2-tetrafluoroethane)under high pressure" International Journal of Thermophysics. 19(5). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Ochi,K.and K.Kojima: "Second Virial Coefficients for Systems Containing Br2,HBr and Water" The Second China-Korea Conference on Separation Science and Technology Qingdao(China). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 天野忠昭 et.al.: "予備酸化をしたNi-20Cr-1Si-0.5(La,Gd,Hf)合金のN2-H2O-HBr雰囲気における高温腐食" 第44回材料と環境討論会. 231-232 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 吉田保之 et.al: "Ni-CrおよびNi-Si系合金のN2-H2O-HBr雰囲気における高温腐食" 日本MRS学術シンポジウム講演要旨集. 91- (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Narushima, T.Goto, T.Hirai and Y.Iguchi: "High-Temperetue Oxidation of Silicon Carbide and Silicon Nitride Materials Transactions" J.I.M.38(10). 821-835 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 後藤 孝,小野 敬,平井敏雄: "MOCVDにより合成したIr-Cコンポジット膜の微細構造と電気的性質" 粉体および粉末治金. 45(1). 20-24 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Goto: "High-Temperature Oxidation of CVD Silicon Carbide" 49th Pacific Coast Regional Meeting and Basic Science Division Meeting of the American Ceramic Society,20th Richard M.Fulrath Pacific Symposium. (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 乾 智行: "天然ガスからの液体燃料合成" J.Jpn.Petrol.Inst.40(4). 243-251 (1997)

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      1997 Annual Research Report
  • [Publications] Tomoyuki Inui: "Rapid Catalytic Process in Reforming of Methane and Successive Synthesis of Methanol and its Derivatives" Appl.Surf.Sci.121/122. 26-33 (1997)

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      1997 Annual Research Report
  • [Publications] Tomoyuki Inui et.al: "Ultra-Rapid Synthesis of Syngas by the Catalytic Reforming of Methane Enhanced by In-situ Heart Supply though Combustion" Korean J.Chem.Eng.14(6). 441-444 (1997)

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      1997 Annual Research Report
  • [Publications] 天野忠昭,吉田保之,関屋昭彦,西原克博,後藤孝,平井敏雄: "微量の活性元素を添加したNi-20Cr-3Si合金のN2-H2O-HBr雰囲気における高温腐食" Journal of Advanced Science. 10. to be published (1998)

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      1997 Annual Research Report
  • [Publications] Zhongyan LI,K.KUSAKABE and Shigeharu MOROOKA: "Pore Structure and Permeance of Amorphous Si-C-O Membranes with High Durability at Elevated Temperature" Sep.Sci.Technol.32(7). 1233-1254 (1997)

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  • [Publications] Bongkuk SEA,Kazuki ANDO,K.KUSAKABE and S.MOROOKA: "Formation of Hydrogen Permselective Hydrophobic Membrane in Macropores of a Porous Alumina Tube by Chemical Vapor Deposition" Euromembrane 97. 263- (1997)

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      1997 Annual Research Report
  • [Publications] Bong-Kuk SEA,K.KUSAKABE and Shigeharu MOROOKA: "Pore Size Control and Gas Permeation Kinetics of Silica Membranes by Pyrolys is of Phenyl-Substituted Ethoxysilanes with Cross-Flow through a Porous Support Wall" J.Memb.Sci.130(1). 41-52 (1997)

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      1997 Annual Research Report
  • [Publications] K.Onuki et al.: "Gas Permeation through CVD Modified Anodic Alumina Membrane" J.Chem.Eng.Jpn.30(2). 359-362 (1997)

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      1997 Annual Research Report
  • [Publications] K.Onuki et al.: "Thermochemical Water-Splitting for Hydrogen Production" Proc.8th International Topical Meeting on Nuclear Reactor Thermal-Hydraulics(NURETH-8),vol.3,Sep.30-Oct.4,1997,Kyoto. 1803-1808 (1997)

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  • [Publications] H.Ohya, H.Nakajima, H.Ohashi, M.Aihara: "Hydrogen purification using Zirconia-Silica Composite Membrane for Thermochemical process" Int.J.Hydrogen Energy. 22(5). 509-515 (1997)

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  • [Publications] H.Ohya, J.Fun, H.Kawamura, K.Itoh: "Methanation of carbon dioxide by using membrane reactor integrated with water vapor permselective membrane and its analysis" J.Memb.Sci.131. 237-247 (1997)

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  • [Publications] 二川ら: "傾斜濃度Fe-Si合金の沸騰濃硫酸中耐食性試験" 材料と環境. 46(10). 669-674 (1997)

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  • [Publications] M.Sakurai: "Adiabatic UT-3 thermochemical process for hydrogen production" Int.J.Hydrogen Energy. 21. 865-870 (1996)

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      1996 Annual Research Report
  • [Publications] M.Sakurai: "Analysis of a reaction mechanism in the UT-3 thermochemical hydrogen production cycle" Int.J.Hydrogen Energy. 21. 871-875 (1996)

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      1996 Annual Research Report
  • [Publications] H.Ohya: "Characteristics of Zirconia Composite membrane fabricated by Lazer firing method" Journal of Membarne Science. 110. 249-252 (1996)

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      1996 Annual Research Report
  • [Publications] J.-L.Li: "Doping Effect of Potassium Permanganate on the Performance of a Copper/Zinc/Aluminum Catalyst for Methanol Formation" Appl.Catal.A. 139. 97-106 (1996)

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      1996 Annual Research Report
  • [Publications] S.Morooka: "Separation of Hydrogen from an H2-H2O-HBr System with an SiO2 Membrane Formed in Macropores of an a-Alumina Support Tube" Int.J.Hydrogen Energy. 21. 183-188 (1996)

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      1996 Annual Research Report
  • [Publications] K.Onuki: "Gas permeation through CVD modified anodic alumina memb rane" J.Chem.Eng.Jpn. (in press). (1997)

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      1996 Annual Research Report
  • [Publications] K.Yoshida: "Solar Hydrogen Production by UT-3 Thermochemical Cycle" IONICS(アイオニクス). 21. 65-68 (1995)

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      1995 Annual Research Report
  • [Publications] M.Sakurai: "Improvement of Ca-Pellet Reactivity in UT-3 Thermochemical Hydrogen Production Cycle" Int. J. Hydrogen Energy. 20. 279-301 (1995)

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      1995 Annual Research Report
  • [Publications] H.Ohya: "Characteristics of Zirconia Composite membrane fabricated by Lazer firing method" Journal of Membarne Science. in press. (1996)

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      1995 Annual Research Report
  • [Publications] T.Goto: "Prepareation of Iridium Clusters by MMOCVD and Their Elictrochemical Proparties" Mat. Sci. Eng. A. in press. (1996)

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      1995 Annual Research Report
  • [Publications] S.Morooka: "Formation fo hydrogen-permselective SiO2 membrane in macropores of α-alumina support tube by tehrmat decompositon of TEOS" Journal of Membarne Science. 101. 89-98 (1995)

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      1995 Annual Research Report
  • [Publications] K.Onuki: "Studies on Water Splitting Hydrogen Production" Proc. 3rd JAERI Symposium on HTGR Technologies. (in press). (1996)

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      1995 Annual Research Report
  • [Publications] M.Sakurai: "Analysis of a Reaction Mechanism in the UT-3 Thermochemical Hydrogen Production Cycle" Hydrogen Energy Progress X. 2. 813-820 (1994)

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      1994 Annual Research Report
  • [Publications] H.Ohya: "Hydrogen Purification Using Zirconia-Silica Composite Membranes for Thermochemical Process" Hydrogen Energy Progress X. 2. 911-920 (1994)

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      1994 Annual Research Report
  • [Publications] S.Morooka: "Formation of Hydrogen-Permselective SiO_2 Membrane in Macropores of α Alumina Support Tube by Thermal Decomposition of TEOS" Journal of Membarne Science. (in press).

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      1994 Annual Research Report
  • [Publications] R.Vargas: "Epitaxial Growth of Irdium and Platinum Films on Sapphire by Metalorganic Chemical Vapor Deposition" Appl.Phys.Lett.65. 1094-1096 (1994)

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      1994 Annual Research Report
  • [Publications] J.R.Vargas-Garica: "Iridium and Platinum Films On Stainless Steel Deposited by Metalorganic Chemical Vapor Deposition and their Corrosion Resistance in a Br_2-O_2-Ar Atmosphere" Proc.Int.Symp.on Environmental Issues on Ceramics,Sapporo. (in press).

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      1994 Annual Research Report
  • [Publications] H.Nakajima: "Hydrogen Production by Iodine-Sulfur Process for Thermochemical Decomposition of Water" Proc.Int.Hydrogen and Clean Energy Symposium '95,Tokyo. 251-254 (1995)

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      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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