• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Studies on the Establishment of the Central Dogma for Heteroatom Chemistry

Research Project

Project/Area Number 06303002
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionUniversity of Tsukuba

Principal Investigator

FURUKAWA Naomichi  Tsukuba Advanced Research Alliance Center, 先端学際領域研究センター, 教授 (80015966)

Co-Investigator(Kenkyū-buntansha) YOSHIFUJI Masaaki  Department of Science, Tohoku University, 理学部, 教授 (90011676)
TAMAO Kohei  Institute for Chemical Research, Kyoto University, 化学研究所, 教授 (60026218)
SUZUKI Hitomi  Department of Science, Kyoto University, 理学部, 教授 (50025342)
AKIBA Kinya  Department of Science, Hiroshima University, 理学部, 教授 (20011538)
OKAZAKI Renji  Graduate School of Science, The University of Tokyo, 大学院・理学系研究科, 教授 (70011567)
吉良 満夫  東北大学, 理学部, 助教授 (40004452)
佐藤 瀏  岩手大学, 工学部, 教授 (00003872)
安藤 亘  筑波大学, 化学系, 教授 (30008429)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥10,800,000 (Direct Cost: ¥10,800,000)
Fiscal Year 1995: ¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 1994: ¥5,600,000 (Direct Cost: ¥5,600,000)
KeywordsHeteroatom compound / Central Dogma / Low coodinate bond / Bulky substituent / High coodinate bond / Higher periodic compound / Pseudo rotation / Active species / ヘテロ原子間結合 / 高配位化合物 / 擬回転 / 配位子カップリング反応 / 多種結合化合物 / カチオンラジカル / ジカチオン
Research Abstract

The purpose of this research intended to manifest the concepts to be commonly applied for the chemical-bondings of the organo-heteroatom compounds (the elements belonging to the groups 14 to 17 in the periodic table) and also establish the commonly acceptable concepts called the new "central dogma" by elucidating the nature of the chemical bondings in the heteroatom chemistry. Major results obtained are in the following, 1) Theoretical MO-calculations of the bondings involving the Si derivatives revealed their characteristic properties. In the case of groups 15 and 16 elements, those belonging to the higher periodic derivatives are stabilized more and by the development of the theoretical and experimetal studies, molecular designs, synthesis, and structural determination have become possible. The detailed experiments on the pseudo-rotation and ligand-coupling reactions of the compounds of groups 15 and 16 elements have been undergone. 2) The multiple-bonds in the Si and P compounds are stabilized both by the bulky and electron-rich substituents attached to the central elements. Furthermore, polysilicon compounds such as two- and three dimensional and highly strained molecules have been synthesized. 3) Organic synthesis and generation of active species using the high-coordinate compounds belonging to groups 15-17 have been tried and these investigations successfully developed the field of heteroatom compounds

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] Kohei Tamao: "Remarkably Facile Thermal Generation of Silylene from a Pentacoordinate Alkoxydisilane and Its Trapping as a Pentacoordinate 1,2-Disilacyclobut-3-ene" J.Am.Chem.Soc.117. 11592-11593 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Masaaki Yoshifuji: "Preparation and Structure of Dichloropalladium (II) Complexes of Sterically Protected Diphosphinidenecyclobutenes and Their Synthetic Application as Homogeneous Catalyst" Chemistry Letters. 221-222 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Naomichi Furukawa: "Fist Isolation and Crystal Structure of Heavier Chalcogenium Cations (R-Se+,R-Te+) Stabilized by Two Neighboring Amino GroupS" J.Am.Chem.Soc.117. 10153-10154 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Renji Okazaki: "Reaction of a Stannylene with Carbon Disulfide : Formation of a Novel Tin-Containing 1,3-Dipole and Its Reactivity" Organometallics. 14. 3620-3622 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hitomi Suzuki: "Hypervalent Bond Formation in Halogeno (2-acyphenyl) bismuthanes" Organometallics. 14. 3848-3854 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Kinya Akiba: "First Stereochemical Characterization of Configurationally Stable Diasterecomers of Hypervalent Stiboranes (10-Sb-5) and Acceleration of Intramolecular Permutation by Donor Solvents" Organometallics. 14. 1928-1937 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 古川尚道: "First X-ray Crystallographic Structure Determination of 2,2′-Biphenylylene-2-biphenylylphenoxytellurane (〔10-Te-4(C3O)〕 Formed during the Ring Opening Reaction of Bis (2,2′-biphenylylene) tellurane (〔10-Te-4(C4)〕) with Phenols." Organometallics. 13. 3393-3395 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 安藤亘: "Synthesis and Reactions of a 2,5-Dithia-3,4-disilatitanacyclopentane" Chemistry Letters. 1395-1398 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 佐藤瀏: "First Systematic Synthesis and Electrochemical Oxidation of 4,7-Diisopropyl-1,2,3-benzotrichalcogenoles Containing Both Sulfur and Selenium Atoms" Tetrahedron Letters. 35. 5469-5472 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 吉藤正明: "2,4-di-t-butyl-6-methoxyphenyldithioxophosphorane as a Probe for the Mechanistic Studies of Lawesson's Reagent" Tetrahedron Letters. 35. 4379-4382 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 吉良満夫: "Stable Tetrakis (trialkylsilyl) disilenes ; Synthesis,X-Ray Structures,and UV/VIS Spectra" Angewandte Chemie. 1489-1491 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 岡崎廉治: "Synthesis,Structure,and Thermolysis of a Tetracoordinate 1,2λ^4-Oxathietane" Angewandte Chemie. 33. 2094-2095 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Naomichi, Furukawa: "Fist Isolation and Crystal Structure of Heavier Chalcogenium Cations (R-Se+, R-Te+) Stabilized by Two Neighboring Amino Groups" J.Am.Chem.Soc.117. 10153-10154 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Naomichi Furukawa: "First X-ray Crystallographic Structure Determination of 2,2'-Biophenylylene-2-biophenylylphenoxytellurane ([10-Te-4(C3O)]) Formed during the Ring Opening Reaction of Bis (2,2'-biphenylylene) tellurane ([10-Te-4(C4)]) with Phenols." Organometallics. 13. 3393-3395 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Renji Okazaki: "Reaction of a Stannylene with Carbon Disulfide : Formation of a Novel Tin-Containing 1,3-Dipole and its Reactivity" Organometallics. 14. 3620-3622 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Renji Okazaki: "Synthesis, Struture, and Thermolysis of a Tetracoordinate 1,2lambda^4-Oxathietane" Angewandte Chemie. 33. 2094-2095 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Masaaki Yoshifuji: "Preparation and Structure of Dichloropalladium (II) Complexes of Sterically Protected Diphosphinidenecyclobutenes and Their Synthetic Application as Homogeneous Catalyst" Chemistry Letters. 221-222 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Masaaki Yoshifuji: "2,4-Di-t-butyl-6-methoxyphenyldithioxophosphorane as a Probe for the Mechanistic Studies of Lawesson's Reagent" Tetrahedron Letters. 35. 4379-4382 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Kohei Tamao: "Remarkably Facile Thermal Generation of Silylene from a Pentacoodinate Alkoxydisilane and Its Trapping as a Pentacoordinate 1,2-Disilacyclobut-3-ene" J.Am.Chem.Soc.117. 11592-11593 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hitomi Suzuki: "Hypervalent Bond Formation in Halogeno(2-acyphenyl) bismuthanes" Organometallics. 14. 3848-3854 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Kinya Akiba: "First Stereochemical Charactrization of Configurationally Stable Diasterecomers of Hypervalent Stiboranes (10-Sb-5) and Acceleration of Intramolecular Permutation by Donor Solvents" Organometallics. 14. 1928-1937 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Wataru Ando: "Synthesis and Reactions of a 2,5-Dithia-3,4-disilatitanacyclopentane" Chemistry Letters. 1395-1398 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Ryu Sato: "First Systematic Synthesis and Electrochemical Oxidation of 4,7-Disopropyl-1,2,3-benzotrichalcogenoles Containing Both Sulfer and Selenium Atoms" Tetrahedron Letters. 35. 5469-5472 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Mitsuo Kira: "Stable Tetrakis (trialkylsilyl)disilenes ; Synthesis, X-Ray Structures, and UV/VIS Spectra" Angewandte Chemie. 1489-1491 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Kohei Tamao: "Remarkably Facile Thermal Generation of Silylene from a Pentacoordinate Alkoxydisilane and Its Trapping as a Pentacoordinate 1, 2-Disilacyclobut-3-ene" J.Am.Chem.Soc.117. 11592-11593 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Masaaki Yoshifuji: "Preparation and Structure of Dichloropalladium(II)Complexes of Sterically Protected Diphosphinidenecvclobutenes and Their Synthetic Application as Homogeneous Catalyst" Chemistry Letters. 221-222 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Naomichi Furukawa: "Fist Isolation and Crystal Structure of Heavier Chalcogenium Cations (R-Se+,R-Te+) Stabilized by Two Neighboring Amino Groups" J. Am. Chem. Soc.117. 10153-10154 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Renji Okazaki: "Reaction of a Stannylene with Carbon Disulfide : Formation of a Novel Tin-Containing 1, 3-Dipole and Its Reactivity" Organometallics. 14. 3620-3622 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hitomi Suzuki: "Hypervalent Bond Formation in Halogeno (2-acyphenyl) bismuthanes" Organometallics. 14. 3848-3854 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Kinya Akiba: "First Stereochemical Characterization of Configurationally Stable Diasterecomers of Hypervalent Stiboranes (10-Sb-5) and Acceleration of Intramolecular Permutation by Donor Solvents" Organometallics. 14. 1928-1937 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 古川尚道: "First X-ray Cystallographic Structure Determination of 2,2′-Biphenylylene-2-biphenylylphenoxytellurane ([10-Te-4(C30)] Formed during the Ring Opening Reaction of Bis (2,2′-biphenylylene) tellurane [10-Te-4(C4)]) with Phenols." Oranometallics.13. 3393-3395 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 安藤 亘: "Synthesis and Reactions of a 2,5-Dithia-3,4-disilatitanacyclopentane" Chemistry Letters. 1395-1398 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 佐藤 瀏: "First Systematic Synthesis and Electrochemical Oxidation of 4,7-Diisopropyl-1,2,3-benzotrichalcogenoles Containing Both Sulfur and Selenium Atoms" Tetrahedron Letters. 35. 5469-5472 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 吉藤正明: "2,4-Di-t-butyl-6-methoxypenyldithioxophosphorane as a Probe for the Mechanistic Studies of Lewesson's Reagent" Tetrahedron Letters. 35. 4379-4382 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 吉良満夫: "Stable Tetrakis (trialkylsilyl) disilenes; Synthesis, X-Ray Structures, and UV/VIS Spectra" Angewandte Chemie. 1489-1491 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 岡崎廉治: "Synthesis, Structure, and Thermolysis of a Tetracoordinate 1,2λ^4-Oxathietane" Angewandte Chemie. 33. 2094-2095 (1994)

    • Related Report
      1994 Annual Research Report

URL: 

Published: 1994-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi