| Project/Area Number |
06303004
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| Research Category |
Grant-in-Aid for Co-operative Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Okazaki National Research Institute |
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Principal Investigator |
YOSHIKAWA Yuzo Okazaki National Research Institutes, Coordination Chemistry Laboratories, 分子科学研究所, 教授 (30022643)
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| Co-Investigator(Kenkyū-buntansha) |
NAKAMURA Akira Faculty of Science, Osaka University, 理学部, 教授 (80029404)
YASUI Takaji Faculty of Science, Kochi University, 理学部, 教授 (20028161)
UTSUNO Shunnji Faculty of Science, Shizuoka University, 理学部, 教授 (40021935)
FUKUDA Yutaka Faculty of Science, Ochanymizu oniversity, Department of Chemistry, 理学部, 教授 (30021950)
KAIZAKI Sumio Faculty of Science, Osaka University, Department of Chemistry, 理学部, 教授 (20089874)
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| Project Period (FY) |
1994 – 1995
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| Project Status |
Completed (Fiscal Year 1995)
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| Budget Amount *help |
¥8,300,000 (Direct Cost: ¥8,300,000)
Fiscal Year 1995: ¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 1994: ¥4,500,000 (Direct Cost: ¥4,500,000)
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| Keywords | Metal Complex / Stereochemistry / Functionality / Stereochemical Control / Enzyme Model |
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| Research Abstract |
Each research member carried out mainly the following study and presented it on two-time symposiums (1994,1995).
Stereospecific control and thermochroism of dinuclear metal complexes (Yutaka Fukuda)
Stereospecific control through intermolecular hydrogen-bonding in metal complexes (sumio Kaizaki)
Discrimination mechanism of chirality in metal complex diastereomers (Yoshihiko Kushi)
Circular dichroism spectra induced in propeller-type metal complexes Shunji Utsuno)
Poli-nucleatio reaction and photo-isomerization of chiral sulfur-containing metal complexes (Takaji Yasui)
Cobalt (III) complexes with atoropisomeric chirality (Yoshiharu Nakano)
Coordination stereochemistry and reactivity of highly-strained zinc complexes (Yuki Fujii)
Function of activatio of enzyme molecules by metal complexes (Yuzo Nishida)
Stereoselsctive formation of chromium (III) complexes containing amino acids (Hisaya Oki)
Synthesis and characterization of new phthatocyaminatometal complexes (Kuninobu Kasuga)
Optically active sulfur-containing bridged cluster complexes (TakashiShibahara)
Synthesis and reactivity of transition metal cpmplexes with chelate rings containing heterocyclic ring (Masafumi Goto)
Chirality discrimination and electron transfer reaction of metal complexes (Katsuhiko Miyoshi)
Stereochemistry of metal coordination compounds containing multiple chiral centers (Kenichi Okamoto)
Synthesis of metal complexes of multidentate ligands containing chiral phosphorus (Kazuo Kashiwabara)
Synthesis of linearly-controlled metal clusters (Akira Nakamura)
Photo-irradiated linkage and geometrical isomerization of cobalt (III) commplexes (Masaaki Kojima)
Migration reaction of transition-metal fragment with metal-metal bond cleavage (Hiroshi Nakazwa)
Further details can be seen in the article papers published or to be published.
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