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Co-operative Hydridization of Electron-Transfer Processes in Surface-Catalyst-Biochemical Systems

Research Project

Project/Area Number 06303010
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 有機工業化学
Research InstitutionNagoya University

Principal Investigator

SAWAKI Yasuhiko  Nagoya University, Faculty Enginering, Professor, 工学部, 教授 (30023120)

Co-Investigator(Kenkyū-buntansha) YOSHIDA Jun-ichi  Kyoto University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (30127170)
NONAKA Tsutomu  Tokyo Institute of Technology, Dept.of Electronic Chemistry, Professor, 大学院・総合理工学研究科, 教授 (00016528)
TANIGUCHI Isao  Kumamoto University, Faculty of Engineering, Professor, 工学部, 教授 (90112391)
UNEYAMA Kenji  Okayama University, Faculty of Engineering, Professor, 工学部, 教授 (00033150)
AIZAWA Masuo  Tokyo Institute of Technology, Faculty of Bioscience and Biotechnology, Professo, 生命理工学部, 教授 (00016742)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥10,400,000 (Direct Cost: ¥10,400,000)
Fiscal Year 1995: ¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1994: ¥5,400,000 (Direct Cost: ¥5,400,000)
KeywordsElectrochemistry / Electron Transfer / Modified Electrode / Biological Function / Catalysis / Organic Synthesis / 有機合成化学
Research Abstract

The present research project was organized to achieve the co-operative hybridization of electron-transfer processes by co-operative unions between researchers of various fields such as organic reaction and synthesis, electrochemistry catalysis, and biological functions. The researchers relating electron-transfer processes exchanged their concept with researchers of different fields. One meeting was the 18th EOC Symposium (Nagoya, June, 1995) and the other was the open symposium of present co-operative research (A) (Nagoya, November, 1995).
The present research is related to three projects : (1) developments of hybridized electron-transfer systems by surface modifications. (2) molecule transformations by catalyst-electrode composite systems, and (3) molecular transformations by combinations of biological and electrode reactions. These projects are related to electron transfer processes and their co-operative hybridization could lead to selective transformations and function amplifications. For example, highly selective transformations of substrates were achieved by electron transfer mediators such as metal complexes and aromatic compounds. Composite electrodes containing enzymes have been shown to be a good selective sensor. Controlles of electron transfer processes have been achieved considerably and a basic concept for co-operative hybridization could be developed.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (49 results)

All Other

All Publications (49 results)

  • [Publications] M. Aizawa, K. Nishiguchi, M. Imamura, et al.: "Integrated Molecular Systems for Biosensors" Sensors and Actuators. 24. 1-5 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Kimura, K. Kobayashi, Y. Sawaki: "Electrooxidative Pinacol-Type Rearrangement of β-Hydroxy Sulfides. Efficient C-5 Cleavage Mediated by Chloride Ion Oxidation" Tetrahedron. 52 (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A. Ohno, A. Tsutumi, Y. Kawai, N. Yamazaki, et al.: "NaD (P)^+ -NAD (P) H Models. 84. Stereochemistry Controlled by the Electronic Effect from a Sulfinyl Group" Heteroaton Chemsitry. 6. 51-56 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S. Ozaki, H. Matsushita, M. Emoto, H. Ohmori: "Indirect Electroreductive Sequential Radical Reaction Catalyzed by a Ni (II) Complex. One-step Preparation of Functionalized Cyclopentanes" Chem. Pharm. Bull.43. 1435-1440 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M. Atobe, T. Nonaka: "Ultrasonic Effects on Electroorganic Processes. Electroreduction of Benzaldehydes on Ultrasound-Vibrating Electrodes" Chemistry Letters. 669-670 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Takahashi, K. Umakoshi, A. Kikuchi, I. Taniguchi, et al.: "Spetroelectrochemical Study of Some Oxo-acetato Trinuclear Rhodium (III) and Iridium (III) Complexes." Z. Naurforsch.50b. 551-557 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S. Kashimura, Y. Murai, H. Masuda, T. Shono: "Cathodic Coupling of Aliphatic Esters. Useful Reactions for the Synthesis of 1, 2-Diketones and Acyloins" Tetrahedron Letters. 27. 4805-4808 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S. Arimori, H. Murakami, M. Takeuchi, S. Shinkai: "Sugar-controlled Association and Photoinduced Eletctron Transfer in Boronic-acid-appended Porphyrins" J. Chem. Soc., Chem. Commun.961-962 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H. Tanaka, Y. Nishioka, Y. Kameyama, S. Torii, et al.: "Synthesis of 2-exo-Methylenepenam by the Reductive 1, 2-Elimination and S-S Bond Fission in a PbBr_2/Al System" Chemitry Letters. 709-710 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Mikami, S. Matsumoto, A. Ishida, S. Fukuzumi, et al.: "Addition of Ketene Acetals to the Triplet Excited State of C_<60> via Photo-induced Electron Transfer Leading to the Fullereneacetates" J. Am. Chem. Soc.117. 11134-11141 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T. Chiba, H. Sakagami, M. Murata, M. Okimoto: "Electroytic Oxidation of Ketones in Ammonical Methanol in the Presence of Catalytic Amount of KI" J. Org. Chem.60. 6764-6770 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K. Nishiwaki, J. Yoshida: "Design, Synthesis, and Electrochemical Behavior of New Electron Donors Based on β-Effects of Group 14 Elements in Electron Transfer" Chemistry Letters. 171-172 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Aizawa, K.Nishiguchi, et al.: "Integrated Molecular Systems for Biosensors" Sensors and Actuators. 24. 1-5 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Kimura, K.Kobayashi, Y.Sawaki: "Electro-oxidative Pinacol-Type Rearrangements of beta-Hydroxy Sulfides. Efficient C-S Cleavage Mediated by Chloride Ion Oxidation." Tetrahedron. 52 (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A Ohno, A.Tsutumi, Y.Kawai, N.Yamazaki, et al.: "NaD (P) ^+-NAD (P) H Models. 84. Stereochemistry Controlled by the Electronic Effect from a Sulfinyl Group" Heteroatom Chemistry. 6. 51-56 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Ozaki, H.Matsushita, M.Emoto, H.Ohmori: "Indirect Electroreductive Sequential Radical Reaction Catalyzed by a Ni (II) Complex. One-step Preparation of Functionalized Cyclopentanes." Chem.Pharm.Bull.43. 1435-1440 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Atobe, T.Nonaka: "Ultrasonic Effects on Electroreduction of Benzaldehydes on Ultrasound-Vibrating Electrodes." Chemistry Letters. 669-670 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Takahashi, K.Umakoshi, A.Kikuchi, I.Taniguchi, et al.: "Spectroelectrochemical Study of Some Oxo-acetato Trinuclear Rhodium (III) and Iridium (III) Complexes." Z.Naurforsch.50b. 551-557 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Kashimura, Y.Murai, H.Masuda, T.Shono: "Cathodic Coupling of Aliphatic Esters. Useful Reactions for the Synthesis of 1,2-Diketones and Acyloins." Tetrahedron Letters. 27. 4805-4808 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] S.Arimori, H.Murakami, M.Takeuchi, S.Shinkai: "Sugar-controlled Association and Photo-induced Electron Transfer in Boronic-acid-appended Porphyrins." J.Chem.Soc., Chem.Commun.961-962 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] H.Tanaka, Y.Nishioka, Y.Kameyama, S.Torii, et al.: "Synthesis of 2-exo-Methylenepenam by the Reductive 1,2-Elimination and S-S Bond Fission in a PbBr_2/Al System." Chemistry Letters. 709-710 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Mikami, S.Matsumoto, A.Ishida, S.Fukuzumi, et al.: "Addition of Ketene Acetals to the Triplet Excited State of C_<60> via Photo-induced Electron Transfer Leading to the Fullereneacetates." J.Am.Chem.Soc.117. 11134-11141 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Chiba, H.Sakagami, M.Murata, M.Okamoto: "Electrolytic Oxidation of Ketones in Ammonical Methanol in the Presence of Catalytic Amount of KI." J.Org.Chem.60. 6764-6770 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Nishiwaki, J.Yoshida: "Design, Synthesis, and Electrochemical Behavior of New Electron Donors Based on beta-Effects of Group 14 Elements in Electron Transfer." Chemistry Letters. 171-172 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] M.Aizawa: "Integrated Molecular Systems for Biosensors" Sensors and Actuators B. 24. 1-5 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Sawaki: "Electrooxidative Pinacol-Type Rearrangement of β-Hydroxy Sulfides. Efficient C-S Cleavage Mediated by Chloride Ion Oxidation" Tetrahedrone. (in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] A.Ohno: "NAD(P)^+-NAD(P)H Models.84. Stereochemsitry Controlled by the Electronic Effect from a Sulfiny Group" Heteroatom Chemsittry. 6. 51-56 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Ohmori: "Indirect Electroreductive Sequential Radical Reaction Catalyzed by a Ni(II) Complex. One-Step Preparation of Functionalized (Methy lene) cyclopentanes" Chem.Pharm.Bull.43. 1435-1440 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Nonaka.: "Ultrasonic Effects on Electroorganic Processes. Electroreduction of Benzaldehydes on Ultrasound-Vivrating Electrodes" Chemsitry Letters. 669-670 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Tokuda: "Regioselective Synthesis of β,γ-Unsaturated Acids by the Electrochemiscal Carboxylation of Allylic Bromides Using a Reactive Metal Anode" Tetrahedron. 36. 3345-3348 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Kashimura: "Cathodic Coupling of Aliphatic Esters. Useful Reactions for the Synthesis of 1,2-Diketones and Acyloin" Tetrahedron Letters. 27. 4805-4808 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Shinkai: "Sugar-controlled Associaton and Photoinduced Electron Transfer in Boronic-acid-appended Porphyrins" J.Chem.Soc.,Chem.Commun.961-962 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] H.Tanaka: "Synthesis of 2-exo-Methylenepenam by the Reductive 1,2-Elimination and S-S Bond Fission in a PbBr_2/Al Bimetal System" Chemistry Letters. 709-710 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] S.Fukuzumi: "Addition of Ketene Acetals to the Triplet Excited State of C_<60> via Photoinduced Eletctron Transfer Leading to the Fullereneacetates" J.Amer.Chem.Soc.117. 11134-11141 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Chiba: "Electrolytic Oxidation of Ketones in Ammoniacal Methanol in the Presence of Catalytic Amount of KI" J.Org.Chem.60. 6764-6770 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Matsumura: "Enantioselective Synthesis of 2,3-Disubstituted Succinic Acids by Oxidative Homocoupling of Optically Active 3-acyl-2-oxazolidones" J.Org.Chem.60. 1100-1101 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] I.Taniguchi: "Novel Trends in Electro-Organic Sybthesis" Kodansha-Elsevier, 393-396 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Aizawa: "Molecular Interfacing for Protain Molecular Devises and Neurodevices" IEEE Ebg.Med.Biol,Feb/Mar,1994. 94-102 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.Uneyama: "Electrochemical Generation of Trifluoroacetal dehyde from its Hemiacetal and Aldol Reaction with Active Methylene Compounds" Denki Kagaku. 62. 1151-1153 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Kimura: "Electrocatalyzed Reduction of Aldehydes and Ketones with Trialkoxysilanes" Denki Kagaku. 62. 1119-1124 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.Matsuda: "Ultrasonic Effects on Electroorganic Prosesses.Product-selectivity in Electroreduction of Benzaldehydes" Chem.Lett.1619-1622 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] I.Taniguchi: "Polypeptide Modified Oxide Electrodes for Direct Electron Transfer of Ferredoxin" J.Chem.Soc.,Chem.Commun.953-954 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] J.Yoshida: "Anodic cyclization of Unsaturated α-Stannyl Ethers.Termination by Bromide Derived from Dibromomethane" J.Chem.Soc.,Chem.Commun.2361-2362 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Tokuda: "Electrochemical Carboxylation of Propargylic Halides by the Use of Reactive-metal Anode" Denki Kagaku. 62. 1144-1147 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Shono: "Diacylation of olefins Promoted by Electrochemically Generated NO_3." Tetrahedron Lett.35. 4161-4164 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y.Matsumura: "A New Reaction System for Efficient Electrochemical Oxidation of N-Methoxycarbony1-2,2,2-trifluoroethy lamines" Tetrahedron Lett.35. 1271-1274 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Fuchigami: "Electrocatalysis of a Self-assembled Thiol-modified Electrode Having Immobilized Dopamine for Oxidation of Reduced Nicotin amide Dinucleotide" Denki Kagaku. 62. 1251-1253 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.D.James: "Novel Photoinduced Electron-transfer Sensor for Saccharides Based on the Interaction of Boronic Acid and Amine" J.Chem.Soc.,Chem.Commun.477-478 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.Tanaka: "Palladium-catalyzed carbonylative [2+2]Cycloaddition for the Selective Synthesis of Either cis- or trans-3-alkenyl β-Lactams" J.Org.Chem.59. 3040-3046 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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