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Studies on Growth and Dissolution Mechanisms of Natural Crystals in Atomic Level

Research Project

Project/Area Number 06402021
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

AOKI Yoshikazu  Kyushu Univ.Fac.of Sci.Prof., 理学部, 教授 (00037277)

Co-Investigator(Kenkyū-buntansha) UEHARA Seiichiro  Kyushu Univ.Fac.of Sci.Res.Ass., 理学部, 助手 (70158773)
NAKAMUTA Yoshihiro  Kyushu Univ.Fac.of Sci.Res.Ass., 理学部, 助手 (80128058)
MATSUI Masanori  Kyushu Univ.Fac.of Sci.Ass.Prof., 理学部, 助教授 (90125097)
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥28,100,000 (Direct Cost: ¥28,100,000)
Fiscal Year 1996: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1995: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1994: ¥24,500,000 (Direct Cost: ¥24,500,000)
Keywordsdiamond / CVD method / carbon whisker / graphene / chondrite / plagioclase thermometer / phlogopite / epitaxial growth / 気相成長 / グラファイト / カーボンナノチューブ / 炭素質コンドライト / 生成温度 / 赤鉄鉱 / 方解石
Research Abstract

1. A large number of diamond crystals were obtained when a tungsten thin plate was used as the substrate of hot-filament-assisted chemical vapor deposition. In this case, the substrate was covered by hexagonal tungsten carbide (WC) thin films and subsequently diamond crystals grew on them by facing its own (111) to the substrate. The sites of carbon atoms on (111) of diamond are in good accord with those on (0001) of WC.Hence WC microcrystals provided nucleation sites for subsequent diamond growth. Namely on (0001) of WC,(111) of diamond grew epitaxially, constructing the coincidence site lattice.
2. Habit modification of carbon synthesized by hot-filament CVD was investigated. Carbon, excepting for diamond, changed their morphology from ball-like aggregate, carbon whisker, thin-film carbon to carbon tube with decreasing substrate temperature. These habit modification depends on the structural connection of graphene with temperature.
3. The maximum temperatures for H6, L6, and LL6 chondrites obtained by using the relation diagram between [2rheta (131)-2rheta (131)] and equilibration temperature of plagioclase were 755,840, and 830゚C,respectively. These temperatures correspond to the temperatures at which plagioclase crystallized from pre-existing glass during the progressive alteration processes in parent body.
4. In the alteration experiments of phlogopite with acid solutions, the dissolution of phlogopite occurred incongruently, and the priority in the dissolution was in the order, K>Fe>Mg, Al>Si. Vermiculite and interstratified mica/vermiculite were formed depending on the release rate of K from phlogopite.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (46 results)

All Other

All Publications (46 results)

  • [Publications] Aoki,Y.: "Formation of tetrapod-like crystals of diamond formed by hot-filament chemical vapor deposition." J.Cryst.Growth. 147. 77-82 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 古川哲二: "熱フィラメントCVD法で合成した炭素質物質のTEM/SEM観察" Ann.Rep.,HVEM LAB.Kyushu Univ.No.20. 85-86 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 平澤桂一: "天草陶石中の粘土鉱物の電顕観察" Ann.Rep.,HVEM LAB.Kyushu Univ.No.19. 75-76 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 桑原義博: "UTW-EDC分析電子顕微鏡による合成混合層鉱物の研究" Ann.Rep.,HVEM LAB.Kyushu Univ.No.18. 67-68 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kuwahara,Y.: "Dissolution process of phlogopite in acid solutions." Clay & Clay Miner.43. 39-50 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 桑原義博: "金雲母の溶解速度論的研究" Ann.Rep.,HVEM LAB.Kyushu Univ.No.19. 77-78 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 桑原義博: "分析電子顕微鏡による合成したバ-ミキュライト混合層鉱物の化学組成" 粘土科学. 35. 176-187 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Matsui,M.: "A transferable interatomic potential model for crystals and melts in the system CaO-MgO-Al_2O_3-SiO_2." Mineral.Mag.58A. 571-572 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Matsui,M.: "Molecular dynamics simulation of structures,bulk moduli,and volume thermal expansivities of silicate liquids in the system CaO-MgO-Al_2O_3-SiO_2." Geophys.Res.Lett.23. 395-398 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Matsuoka,K.: "Yamato-86789 : A heated CM-like carbonaceous chondrite." Proc.NIPR Symp.Antarctic Meteorites. No.9. 20-36 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Nakamura,T.: "X-ray study of PCP from Murchison CM carbonaceous chondrite." Proc.NIPR Symp.Antarctic Meteorites. No.9. 37-50 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 中牟田義博: "プロファイルフィッティング法によるX線粉末データの精密解析" ゼオライト. 11. 171-179 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Nakamuta,Y.: "Metamorphic temperature estimation for equilibrated ordinary chondrites by a plagioclase thermometer." Lunar & Planet.Sci.27. 931-932 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Uehara,S.: "Antigorite with a large subcell from Sasaguri,Oita Prefecture." Canad.Mineral.32. 93-103 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 上原誠一郎: "高分解能電子顕微鏡によるアンチゴライトの超構造の分類" Ann.Rep.,HVEM LAB.Kyushu Univ.No.19. 49-50 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 上原誠一郎: "TEM,SEM,AFMを用いたCVD合成グラファイトの形態および微細組織観察" Ann.Rep.,HVEM LAB.,Kyushu Univ.No.20. 83-84 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Aoki, Y.et al.: "Formation of tetrapod-like crystals of diamond formed by hot-filament chemical vapor deposition." J.Cryst.Growth. 147. 77-82 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Furukawa, T.et al.: "TEM and SEM studies of carbon materials synthesized by hot-filament-assisted CVD method." Ann.Rep., HVEM LAB.Kyushu Univ.No.20. 85-86 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Hirasawa, K.et al.: "Transmission electron microscopic obervation of Amakusa pottery stone." Ann.Rep., HVEM LAB.Kyushu Univ.No.19. 75-76 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kuwahara, Y.et al.: "Synthetic interstratified minerals studied by AEM with ultra thin window type EDS." Ann.Rep., HVEM LAB.Kyushu Univ.No.18. 67-68 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kuwahara, Y.et al.: "Dissolution process of phlogopite in acid solutions." Clay & Clay Miner.43. 39-50 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kuwahara, Y.et al.: "Study for dissolution kinetics of phlogopite." Ann.Rep., HVEM LAB.Kyushu Univ.No.19. 77-78 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kuwahara, Y.et al.: "Chemical composition of synthetic interstratified mica/vermiculite by analytical electron microscopy." J.Clay Sci.Soc.Japan. 35. 176-187 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Matsui, M.: "A transferable interatomic potential model for crystals and melts in the system CaO-MgO-Al_2O_3-SiO_2." Mineral.Mag.58A. 571-572 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Matsui, M.: "Molecular dynamics simulation of structures, bulk moduli, and volume thermal expansivities of silicate liquids in the system CaO-MgO-Al_2O_3-SiO_2" Geophys.Res.Lett.23. 395-398 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Matsuoka, K.et al.: "Yamato-86789 : A heated CM-like carbonaceous chondrite." Proc.NIPR Symp.Antarctic Meteorites. No.9. 20-36 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Nakamura, T.et al.: "X-ray study of PCP from Murchison CM carbonaceous chondrite." Proc.NIPR Symp.Antarctic Meteorites. No.9. 37-50 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Nakamuta, Y.: "Precise analyzes of X-ray powder data by using a profile fitting technique." Zeolite. 11(4). 171-179 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Nakamuta, Y.et al.: "Metamorphic temperature estimation for equilibrated ordinary chondrites by a plagioclase thermometer." Lunar & Planet.Sci.27. 931-932 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Uehara, S.: "Antigorite with a large subcell from Sasaguri, Oita Prefecture." Canad.Mineral.32. 93-103 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Uehara, S.: "A HRTEM study of antigorite superstructure" Ann.Rep., HVEM LAB.Kyushu Univ.No.19. 49-50 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Uehara, S., et al.: "Morphology and fine-texture of CVD graphite studied by TEM,SEM,and AFM." Ann.Rep., HVEM LAB.Kyushu Univ.No.20. 83-84 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 桑原義博: "分析電子顕微鏡による合成したバ-ミキュライト混合層鉱物の化学組成" 粘土科学. 35. 176-187 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 上原誠一郎: "TEM,SEM,AFMを用いたCVD合成グラファイトの形態および微細組織観察" Annual Reports,HVEM LAB.,Kyusyu Univ.No.20. 83-84 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 古川哲二: "熱フィラメントCVD法で合成した炭素物質の研究" Annual Reports,HVEM LAB.,Kyusyu Univ.No.20. 85-86 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Nakamuta,Y.: "Metamorphic temperature estimation for equilibrated ordinary chondritesby a plagioclase thermometer." Lunar and Planetary Science. 27. 931-932 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Nakamura,T.: "X-ray study of PCP from Murchison CM carbonaceous chondrite" Proc.NIPR Symposium on Antarctic Meteorites.No.9. 37-50 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Matsuoka,K.: "Yamato-86789:A heated CM-Like carbonaceous chondrite" Proc.NIPR Symposium on Antarctic Meteorites.No.9. 20-36 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y. Kuwahara: "Dissolution process of phlogopite in acid colution." Clays and Clay Minerals. 43. 39-50 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 平澤桂一: "天草陶石中の粘土鉱物の電顕観察" Annual Reports, HVEM LAB., Kyushu Univ.No. 19. 75-76 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 桑原義博: "金雲母の溶解速度論的研究" Annual Reports, HVEM LAB., Kyushu Univ.No. 19. 77-78 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 上原誠一郎: "高分解能電子顕微鏡によるアンチゴライトの超構造の分類" Annual Reports, HVEM LAB., Kyushu Univ.No. 19. 49-50 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Aoki: "Formation of tetrapod-like crystals of diamond formed by hot-filament chemical vapor deposition." Journal of Crystal Growth. 147. 77-82 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] M.Matsui: "Comparison between the lattice dynamics and molecular dynamics methods:calculation results for MgSiO_3 perovskite." Geophysical Research Letters. 21. 1659-1662 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 中牟田,義博: "プロファイルフィッティング法によるX線粉末データの精密解析" ゼオライト. 11. 171-179 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] S.Uehara: "Antigorite with a large supercell from Saganoseki,Oita Prefecture,Japan" The Canadian Mineralogist. 32. 93-103 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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