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Study on Negative Ion Implantation for the Surface Modification of Polymer Materials without Defects for Bio-compatibilty Control

Research Project

Project/Area Number 06452112
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Applied materials science/Crystal engineering
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

TSUJI Hiroshi  Kyoto Univ., Graduate School of Engineering.Res.Ass., 工学研究科, 助手 (20127103)

Co-Investigator(Kenkyū-buntansha) GOTOH Yasuhito  Kyoto Univ., Graduate School of Engineering.Res.Ass., 工学研究科, 助手 (00225666)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥7,400,000 (Direct Cost: ¥7,400,000)
Fiscal Year 1995: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1994: ¥4,900,000 (Direct Cost: ¥4,900,000)
KeywordsNegative-ion source / Negative-ion implantation / Polymers / Insulator / Charge-up free / Contact angle / Biocompatibility / Powders / 負イオン / 負イオンビーム注入 / 医用高分子 / 絶縁物 / 結晶性子 / 物性制御
Research Abstract

1.Development of Negative-Ion Source and Negative-Ion implanter :
We developed an intense RF plasma-sputter-type heavy negative-ion source (RFNIS) which can deliver hight-current negative-ion beams in a dc-mode with an intensity of several mA of various elements, such as Carbon, Silicon, Copper, Silver, Fluorine, and Oxygen. Besides, we also developed a medium-current type negative-ion implanter equipped a small-type RFNIS,of which a clean booth makes to implant ions in the clean condition as well as in the real implantation process.
2.Development of a Method to Measure Surface Potential of Insulators during Negative-Ion Implantation
We developed a new method to measure the charging voltage of insulator surface by the analysis of secondary electron energy distribution. It was found that the surface charging potential of negative-ion implanted insulators of polyethylene and polystirene plates was in the range form several to 10 volts negative. Besides, we proposed an electric double layr m … More odel as a low charging mechanism of insulators during negative-ion implantation.
3.Investigation of the Contact Angle of Polystirene Surface and Detection of Introduced functional groups
By the positive argon and oxygen ion implantation, the contact angle against pure water of the implanted polystirene decreased with an increase of the dose. On the contrary, by the carbon negative-ion implantation, the angle increased. a little. It was clear from the results of XPS measurements that several functional groups of C-O,C=0, and O=C-O were introduced in the implanted surface of polystirene. Then these functional groups resulted the decrease of contact angle for argon and oxygen implantation.. But in carbon ion implantation, it is considered that the increase of carbon atom at the surface will be affect to the increase of contact angle of polystirene surface.
4.Development of Non-Scattering Implantation Method into Powders
We clarified the scattering phenomenon of powders during implantation by theoretically and experimentally with a positive ion implantation. On the contrary, even in the negative-ion implantation with an energy of 20 keV,there was no scattering resulted. This shows the negative-ion implantation is non scattering implantation method. Less

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (74 results)

All Other

All Publications (74 results)

  • [Publications] Hiroshi Tsuji: "RF Plasma Sputter-Type DC-Mode Heavy Negative Ion Source" AIP Conf. Proc., Particles and Fields Serise. No.287. 530-539 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Negative-Ion Production Probability in RF Plasma Sputter-Type Heavy Negative Ion Source" Review of Scientific Instruments. 65. 1732-1736 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "スパッタリングを用いた二次負イオン放出における負重イオン生成効率の測定" アイオニクス. 第20巻. 19-27 (1994)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "連続動作大電流スパッタ型負重イオン源の開発" アイオニクス. 第20巻. 29-39 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "負重イオンビームの電子離脱断面積と二次電子放出比" アイオニクス. 第20巻. 41-50 (1994)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "負イオン注入による絶縁電極の帯電電位測定" アイオニクス. 第20巻. 57-64 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "絶縁物への負イオン注入における表面電位のイオン誘起二次電子分析による測定" アイオニクス. 第20巻. 71-76 (1994)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "イオン誘起二次電子による負イオン注入時の絶縁物基板の帯電測定" 真空. 第37巻. 139-142 (1994)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "200kV中電流負イオン注入装置の開発" 第5回粒子線の先端的応用技術に関するシンポジウム論文集. BEAMS1994. 23-26 (1994)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "粉末へのイオン注入による粒子飛散の基礎現象" 第5回粒子線の先端的応用技術に関するシンポジウム論文集. BEAMS1994. 185-188 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "負イオン注入における孤立電極の帯電電位モデルとその実験的検証" 第5回粒子線の先端的応用技術に関するシンポジウム論文集. BEAMS1994. 209-212 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "High Current RF-Plasma-Sputter-Type Heavy Negative-Ion Source for Negative-Ion Implantar" Ion Implantation Technology-94. IIT94. 495-498 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司: "RFプラズマスパッタ型負重イオン源における気体材料の負イオン生成" 真空. 第38巻 第3号. 218-220 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji, Junzo Ishikawa, Yoshio Okayama, Yoshitaka Toyota, and Yasuhito Gotoh: "High-Current RF-Plasma-Sputter-Type Heavy Negative-Ion Source for Negative-Ion Implantar" Ion Implantation Technology-94. IIT94. 495-498 (1995)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji, Junzo Ishikawa, Hajime Itoh, Yoshitaka Toyota and Yasuhito Gotoh: "Fundamental Study on Powder-Scattering in Positive-and Negative-Ion Implantation into Powder Materials" (to be published in Applied Surface Science in 1996). (4) (1996)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Junzo Ishikawa, Hiroshi Tsuji, Yoshitaka Toyota, Yasuhito Gotoh, Koji Matsuda, Masaya Tanjo, and Shigeki Sakai: "Negative-Ion Implantation Technique (Invited)" Nuclear Instruments and Methods B. Vol.B96. 7-12 (1995)

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    • Related Report
      1995 Final Research Report Summary
  • [Publications] Shigeki Sakai, Yasuhito Gotoh, Hiroshi Tsuji, Yoshitaka Toyota, Junzo Ishikawa, Masaya Tanjo, and Koji Matsuda: "The Charging Mechanism of Insulated Electrode in Negative-Ion Implantation" Nuclear Instruments and Methods B. Vol.B96. 43-47 (1995)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji, Yoshitaka Toyota, Junzo Ishikwa, Shigeki Sakai, Yoshio Okayama, Shoji Nagumo, Yasuhito Gotoh and Koji Matsuda: "Charging Voltage Measurement of an Isolated EIectrpde and Insulators during Negative-Ion Implantation" Ion Implantation Technology-94. IIT94. 612-615 (1995)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司、岡山芳央、富田哲生、豊田啓孝、後藤康仁、石川順三: "RFプラズマスパッタ型負重イオン源におけるガス物質の負イオン引き出し" 第4回負イオン源及び負イオンビームとその応用研究会 NIFS Proceedings Serise 1995. PROC24. 43-47 (1995)

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      「研究成果報告書概要(和文)」より
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      1995 Final Research Report Summary
  • [Publications] Yoshitaka Toyota, Hiroshi Tsuji, Yasuhito Gotoh and Junzo Ishikawa: "Energy Distribution and Yield Measurement of Secondary Electrons to Evaluate the Equilibrium Charging Voltage of an Isolated Electrode during Negative-Ion Implantation" Japanese Journal of Applied Physics. Vol.34. 6487-6491 (1995)

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      1995 Final Research Report Summary
  • [Publications] Yoshitaka Toyota, Hiroshi Tsuji, Shoji Nagumo, Yasuhito Gotoh and Junzo Ishikawa: "Charging Phenomenon of Insulators in Negative-Ion Implantation" (to be published in Applied Surface Science in 1996). (4) (1996)

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      「研究成果報告書概要(和文)」より
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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji, Junzo Ishikawa, Tetsuo Tomita and Yasuhito Gotoh: "Negtive-Ion Extraction of Gaseous Materials from RF Plasma-Sputter-Type Heavy Negative-Ion Source" (to be published in Review of Scientific Instruments,1996). (3) (1996)

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      1995 Final Research Report Summary
  • [Publications] Junzo Ishikawa, Hiroshi Tsuji, Takashi Takatori and Yasuhito Gotoh: "Study on the Energy Distribution of Heavy Negative Ion Beams Extracted from The Sputter-Type Negative-Ion Source" (to be published in American Institute of Physics, AIP Conference Series). (8) (1996)

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      「研究成果報告書概要(和文)」より
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      1995 Final Research Report Summary
  • [Publications] 辻 博司、岡山芳央、豊田啓孝、後藤康仁、石川順三: "高周波プラズマスパッタ型負重イオン源における気体材料の負イオン生成" 真空. 第38巻. 218-220 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 辻 博司、南雲正二、豊田啓孝、後藤康仁、石川順三: "イオン誘起二次電子分析による負イオン注入時のレジスト膜の帯電測定" 真空. 第38巻第3号. 221-223 (1995)

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      「研究成果報告書概要(和文)」より
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      1995 Final Research Report Summary
  • [Publications] 豊田啓孝、辻 博司、南雲正二、酒井滋樹、後藤康仁、石川順三、松田耕自: "負イオン注入における基板帯電モデルとその評価" 真空. 第38巻. 224-227 (1995)

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      1995 Final Research Report Summary
  • [Publications] 辻 博司、石川順三: "スパッタ法を用いた重負イオンの生成" アイオニクス. 第21巻第4号. 29-38 (1995)

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      「研究成果報告書概要(和文)」より
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      1995 Final Research Report Summary
  • [Publications] 石川順三、辻 博司、後藤康仁、酒井滋樹: "負イオン注入技術" アイオニクス. 第21巻. 63-76 (1995)

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      1995 Final Research Report Summary
  • [Publications] 辻 博司、伊藤 一、豊田啓孝、南雲正二、後藤康仁、石川順三: "負イオンビームによる粉末材料へのスキャッタレス・イオン注入" 電気化学協会第62回学術大会シンポジウム「粒子線を用いた次世代材料プロセス技術」. 55-63 (1995)

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      1995 Final Research Report Summary
  • [Publications] 辻 博司、富田哲生、豊田啓孝、後藤康仁、石川順三: "高周波プラズマスパッタ型負重イオン源におけるSF_6ガスからのフッ素負イオン引き出し" 真空. 第38巻. 769 (1995)

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      1995 Final Research Report Summary
  • [Publications] 豊田啓孝、本田広史、辻 博司、後藤康仁、石川順三: "負イオン注入における絶縁物からの放出二次電子の測定" 真空. 第38巻. 796 (1995)

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      1995 Final Research Report Summary
  • [Publications] 池田茂雄、豊田啓孝、辻 博司、後藤康仁、石川順三: "負イオン注入における放出二次電子の測定" 第6回粒子線の先端的応用技術関するシンポジウム論文集. BEAMS1995. 175-178 (1995)

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      1995 Final Research Report Summary
  • [Publications] 富田哲生、辻 博司、豊田啓孝、後藤康仁、石川順三: "PRプラズマスパッタ型負重イオン源からの酸素及びフッ素負イオン引き出し特性" 第6回粒子線の先端的応用技術関するシンポジウム論文集. BEAMS1995. 191-194 (1995)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "RF Plasma Sputter-Type DC-Mode Heavy Negative Ion Source" AIP Conf. Proc.No.287 Particles and Fields Series 53. 530-539 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Negative-Ion Production Probability in RF Plasma-Sputter-Type Heavy Negative Ion Source" Review of Scientific Instruments. Vol.65, No.5. 1732-1736 (1994)

    • Description
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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Measurement of Heavy Negative Ion Production Efficiencies in Secondary Negative Ion Emission by Sputtering" Ionics. Vol.20, No.1. 19-27 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Development of Intense Sputter-Type Heavy Negative-Ion Sources" Ionics. Vol.20, No.1. 29-39 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Electron Detachment Cross-Sections and Secondary-Electron Emission Factors for Heavy Negative-Ion Beams" Ionics. Vol.20, No.1. 41-50 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of Insulated Electrode by Negative-Ion Implantation" Ionics. Vol.20, No.1. 57-64 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of Negative-Ion-Implanted Insulators by Analyzing Secondary Electron Energy Distribution" Ionics. Vol.20, No.1. 71-76 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Surface Potential Measurement of the Insulator with Secondary Electron Caused by Negative-Ion Implantation" Journal of the Vacuum Society of Japan. Vol.37, No.3. 139-142 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Development of 200 keV Medium Current Negative-ion Implanter" Proc.of the 5th Symposium on Beam Engineering and Advanced Material Syntheses, BEAMS1994. 23-26 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Fudamental Study on Powder Scattering during Ion Implantation" Proc.of the 5th Symposium on Beam Engineering and Advanced Material Syntheses, BEAMS1994. 185-188 (1994)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Charging Voltage Model and Its Experimental Evaluation of Isolated Electrode in Negative-Ion Implantation" Proc.of the 5th Symposium on Beam Engineering and Advanced Material Syntheses, BEAMS1994. 209-212 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "High Current RF-Plasma-Sputter-Type Heavy Negative Ion Source for Negative-Ion Implanter" Ion Implantation Technology-94. IIT94. 495-498 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Charging Volatage Measurement of an Isolated Electrode and Insulators during Negative-Ion Implantation" Ion Implantation Technology-94. IIT94. 612-615 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Negative-Ion Implantation Technique" Nuclear Instruments and Methods. B96. 7-12 (1995)

    • Description
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    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Fundamental Study on Powder-Scattering in Positive- and Negative-Ion Implantation into Powder Materials" Applied Surface Science. (to be published). 4 (1996)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Charging Phenomenon of Insulators in Negative-Ion Implantation" Applied Surface Science. (to be published). 4 (1996)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Negative-ion Production of Gas Material in RF Plasma-Spuytter-Type Heavy Negative-Ion Source" Journal of the Vacuum Society of JApan. Vol.38, No.3. 218-220 (1995)

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  • [Publications] Hiroshi Tsuji: "Charging Potential Measurement of Photoresist Layr Surface during Negative-ion Implantation from Ion Induced Secondary Electron Analysis" Journal of the Vacuum Society of JApan. Vol.38, No.3. 221-223 (1995)

    • Description
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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Heavy Negative-Ion Production with Sputtering Process" Ionics. Vol.21, No.4. 29-38 (1995)

    • Description
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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Negative-Ion Implantation Technique" Ionics. Vol.21, No.4. 63-76 (1995)

    • Description
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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Negative-Ion Extraction of Gases from RF Plasma-Sputter-Type Heavy Negative-Ion Source" NIFS-Proceeding Series. NIFS-PROC 24. 43-47 (1995)

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      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "Non-Scattering Ion Implantation into Powder Materials by Using Negative-Ion Beams" Proceedings of the Symposium on the Future Material Fabrication Process with Particle Beams at the 62th Meeting of the Electrochemical Society of Japan.55-64 (1995)

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  • [Publications] Shigeo Ikeda, Hiroshi Tsuji: "Measurement of Secondary Electrons Emitted in Negative-Ion Implantation" Proc.of the 6th Symp.on Beam Engineering of Advanced Maternal Syntheses. BEAMS1995. 175-178 (1995)

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      1995 Final Research Report Summary
  • [Publications] Tetsuo Tomita, Hiroshi Tsuji: "Extraction Properties of Oxygen and Fluorine Negative Ions from RF Plasma-Sputter-type Heavy Negative-Ion Source" Proc.of the 6th Symp.on Beam Engineering of Advanced Maternal Syntheses. BEAMS1995. 191-194 (1995)

    • Description
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    • Related Report
      1995 Final Research Report Summary
  • [Publications] Hiroshi Tsuji: "High Current RF-Plasma-Sputter-Type Heavy Negative-Ion Source for Negative-Ion Implantar" Ion Implantation Technology-94. IIT94. 495-498 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hiroshi Tsuji: "Charging Voltage Mesurement of an Isolated Electrode and Insulators during Negative-Ion Implantation" Ion Implantation Technology-94. IIT94. 612-615 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hiroshi Tsuji: "Negative-Ion Implantation Technique" Nuclear Instruments and Methods in Physics Research B. Vol. B96. 7-12 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hiroshi Tsuji: "Fundamental Study on Powder-Scattering in Positive-and Negative-Ion Implantation into Powder Materials" (to be published in Applied Surface Science). (4) (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Hiroshi Tsuji: "Charging Phenomenon of Insulators in Negative-Ion Implantation" (to be published in Applied Surface Science). (4) (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 辻 博司: "イオン誘起二次電子分析による負イオン注入時のレジスト膜の帯電測定" 真空. 第38巻 第3号. 221-223 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 辻 博司: "負イオン注入における基板帯電モデルとその評価" 真空. 第38巻 第3号. 224-227 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 辻 博司: "負イオン注入技術" アイオニクス. 第21巻 第4号. 63-76 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 辻 博司: "負イオンビームによる粉末材料へのスキャッタレス・イオン注入" 電気化学協会第62回学術大会シンポジウム「粒子線を用いた次世代材料プロセス技術」論文集. 55-63 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 辻 博司: "負イオン注入における放出二次電子の測定" 第6回粒子線の先端的応用技術関するシンポジウム論文集. BEAM1995. 175-178 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 辻 博司: "負イオン注入における絶縁した電極表面の帯電電位のイオン電流密度依存性" 真空. 第37巻 第3号. 135-138 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 辻 博司: "イオン誘起二次電子による負イオン注入時の絶縁物基板の帯電測定" 真空. 第37巻 第3号. 138-142 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 辻 博司: "粉末へのイオン注入による粒子飛散の基礎現象" 第5回粒子線の先端的応用技術に関するシンポジウム論文集. BEAMS1994. 185-188 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hiroshi Tsuji: "High-Current RF-Plasma-Sputter-Type Heavy Negative-Ion Source for Negative-Ion Implanter" Ion Implantation Technology 94. (North-Holland)(to be published). 4 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Hiroshi Tsuji: "Charging Voltage Measurement of an Isolated Electrode and Insulators during Negative-Ion Implantation" Ion Implantation Technology 94. (North-Holland)(to be published). 4 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 辻 博司: "高周波プラズマスパッタ型負重イオン源における気体材料の負イオン生成(to be published)" 真空. 第38巻 第3号. 5 (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] 辻 博司: "イオン誘起二次電子分析による負イオン注入時のレジスト膜の帯電測定(to be published)" 真空. 第38巻 第3号. 4 (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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