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MATERIAL STRENGTH STUDY ON GROWTH OF HIGH QUALITY BULK SINGLE CRYSTALS FOR ELECTRONIC/OPTICAL DEVICES

Research Project

Project/Area Number 06452152
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Materials/Mechanics of materials
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

MIYAZAKI Noriyuki  KYUSHU UNIVERSITY,DEPARTMENT OF CHEMICAL ENGINEERING,PROFESSOR, 工学部, 教授 (10166150)

Co-Investigator(Kenkyū-buntansha) IKEDA Toru  KYUSHU UNIVERSITY,DEPARTMENT OF CHEMICAL ENCINEERING,RESEARCH ASSOCIATE, 工学部, 助手 (40243894)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1995: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1994: ¥3,700,000 (Direct Cost: ¥3,700,000)
KeywordsELECTRONIC / OPTICAL DEVICES / SINGLE CRYSTAL / CZOCHRALSKI METHOD / DISLOCATION DENSITY / THERMAL STRESS / FINITE ELEMENT METHOD / HAASEN-SUMINO MODEL / QUALITY OF CRYSTAL
Research Abstract

1. A computer code was developed for for evaluating the dislocation density of Si, GaAs and InP bulk single crystals during the Czochralski growth using a dislocation kinetics model called the Haasen-Sumino model. The following are the research results obtained from the analyzes using this computer code. (1) The rate of dislocation multiplication is faster in the order of GaAs, InP and Si. Even in the case of Si, the dislocation density reaches a steady state value within a few seconds, and InP and GaAs have faster rate of dislocation multiplication by more than a hundred times and a thousand times, respectively. (2) InP and GaAs have larger dislocation density at a steady state than Si. (3) A continuous simulation for the CZ growth process gives a W-type distribution of dislocation density along a diameter of a bulk single crystal, which is observed in a real bulk single crystal. This verifies the computer simulation.
2. The following are results of the research on the relation between … More the thermal stress during the growth of a LiNbO_3 (LN) single crystal and its quality. (1) Thermal stress is higher in the a-axis pulling than in the c-axis pulling. This verifies the empirical fact that cracking is easier to occur in the a-axis pulling than in the c-axis pulling. (2) According to the thermal stress analysis, a single crystal grown in the a-axis direction has a wider region of low thermal stress in its internal part than a single crystal grown in the c-axis direction. This implies that the a-axis pulling gives a bulk single crystal with higher quality than the c-axis pulling. The examination of the quality of single crystals with the x-ray topograph reveals high quality of a single crystal grown in the a-axis pulling which has fewer subgrains than a single crystal grown in the c-axis direction. It is shown that the results of the thermal stress analysis give effective information on the growth method of a single crystal with high quality. (3) Failure of a LN Single crystal due to thermal stress occurs at the cleavage planes and may be dominated by the tensile stress normal to the cleavage planes. The failure stress shows the Weibull distribution. Less

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (11 results)

All Other

All Publications (11 results)

  • [Publications] N. MIYAZAKI: "Dislocation Density Analysis of Bulk Single Silicon Crystal Growth Using Dislocation Kinetics Model" Mechanics and Materials for Electronis Packaging. ASME AND Vol. 195. 59-64 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 宮崎 則幸: "CZ育成LN単結晶の熱応力解析" 日本結晶成長学会誌. 22. 39-42 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] N. MIYAZAKI: "Finite Element Analyses of Cracking in Lithium Niobate Single Crystal" Computational Mechanics '95. Vol. 1. 586-591 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] N.MIYAZAKI,H.UCHIDA,T.MUNAKATA,K.FUJIOKA and Y.SUGINO: "Dislocation Density Analysis of Bulk Single Silicon Crystal Using Dislocation Kinetics Model, Mechanics and Materials for Electronic Packaging." ASME. AMD-Vol.195. 59-64 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] N.MIYAZAKI: "Thermal Stress Analysis of LN Single Crystal during CZ growth." Journal of Japanese Association for Crystal Growth. Vol.22-No.1. 39-42 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] N.MIYAZAKI,H.UCHIDA and A.HATTORI: "Finite Element Analyzes of Cracking in Lithium Niobate" Computational Mechanics '95. Vol.1. 586-591 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] N. MIYAZAKI: "Dislocation Density Analysis of Bulk Single Silicon Crystal Growth Using Dislocation Kinetics Model" Mechanics and Materials for Electronics Packaging. ASME AMD-Vol.195. 59-64 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] 宮崎 則幸: "CZ育成LN単結晶の熱応力解析" 日本結晶成長学会誌. 22. 39-42 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] N. MIYAZAKI: "Finite Element Analyses of Cracking in Lithium Niobate Single Crystal" Computational Mechanics'95. Vol.1. 586-591 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] N.MIYAZAKI: "Dislocation Density Analysis of Bulk Single Silicon Crystal Crowth Using Dislocation Kinetics Model" Mecchanics and Materials for Electronic Packaging. ASME AMD-Vol.195. 59-64 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 宮崎則幸: "CZ育成LN単結晶の熱応力解析" 日本結晶成長学会誌. 22. 39-42 (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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