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Elementary Analysis of a single Metallic Atom on Si Wafer Surface by STM/STS

Research Project

Project/Area Number 06452160
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 機械工作・生産工学
Research InstitutionOsaka University

Principal Investigator

ENDO Katsuyoshi  Osaka Univ., Fac.of Eng., Associate Professor, 工学部, 助教授 (90152008)

Co-Investigator(Kenkyū-buntansha) YAMAUCHI Kazuto  Osaka Univ., Fac.of Eng., Associate Professor, 工学部, 助教授 (10174575)
MORI Yuzo  Osaka Univ., Fac.of Eng., Professor, 工学部, 教授 (00029125)
KATAOKA Toshihiko  Osaka Univ., Fac.of Eng., Professor, 工学部, 教授 (50029328)
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,200,000 (Direct Cost: ¥7,200,000)
Fiscal Year 1996: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1995: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1994: ¥4,400,000 (Direct Cost: ¥4,400,000)
KeywordsSTM / STS / Ab-inito MO / H-terminated Si surface / First principle MD / Local density of states / Si (001) 2*1 surface / Elementary analysis / Si wafer / Si(001)2×1表面 / 走査型トンネル顕微鏡 / 走査型トンネル分光 / 水素終端化 / 走査型トンネル分光法 / シリコンウェーハ / 金属汚染物 / 表面分析 / 電子構造
Research Abstract

In this work, we have developed a Scanning Tunneling Microscope (STM) /Scanning Tunneling Spectroscope (STS) system. This system can observe both STM image and STS data of the surface simultaneously. Typical STM images of the surfaces of Highly Oriented Pyrolytic Graphite (HOPG), Si wafer and EEM product are also observed. The HOPG image shows that the difference of electronic structure between alpha-site and beta-site. Electronic structure of the surface of Si wafer contaminated by metallic atoms is calculated by Ab-initio MO.According to the results which is different from the results of H-terminated Si wafer, we have shown the possiblility of atomic-order elementary analysis. We have found that the significant difference of STS data between H-terminated Si Wafer and Cu-contaminated Si wafer may occur by the spatial distribution of wave function in Ab-initio MO.Because of DHF treatment, dihydride is dominant on the surface of H-terminated Si (001) wafer. Tmie-dependent stability of the surface is confirmed by FTIR-ATR.Local density of states (LDOS) have been calculated on Si (001) 2*1 surface and Cu-contaminated Si (001) surface. STM/STS scanning is also performed on Si (001) 2*1 surface and Al- or Cu-contaminated Si (001) surfaces in UHV chamber. The results show the differences of LDOS data and some issues of the measurement.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] 平野 均 他: "非経験的分子軌道法を用いた窒化物セラミックス薄膜形成における窒素分子と金属の反応解析" 精密工学会誌. 62. 1024-1028 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K. Endo et al.: "Observation of Metal Atoms Adsorbed on H-terminated Si (001) Surfaces by STM/STS" Proceedings of 1996 JCBSAME. 141-146 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K. Endo et al.: "Observation of Metal Atoms Adsorbed on H-Terminated Si (001) Surfaces by STM/STS and its Consideration Based on Ab-Initio Molecular Orbital Calcuations" Proceedings of MRS-J. 189 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y. Mori et al.: "The Auger Electron Spectroscopy by using STM Peobe" Proceedings of 1996 JCBSAME. 131-135 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K. Inagaki et al.: "Investigation of Surface States on Si (001) anf Si (111) Surfaces-Photo-Reflectance Measurement and Ab-initio Calcuation-" Proceedings of MRS-J. 189 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Hirano et al.: "Reaction Analysis of Nitrogen Molecules and Metals in the Fabrication of the Nitride Ceramic Thin Film using ab initio Molecular Orbital Method" J.Japan Soc.Prec.Eng.62(7). 1024-1028 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Endo et al.: "Observation of Metal Atoms Adsorbed on H-terminated Si (001) Surfaces by STM/STS" Proc.of 1996 JCBSAME. 141-146 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Endo et al.: "Observation of Metal Atoms Adsorbed on H-Terminated Si (001) Surfaces by STM/STS and its Consideration Based on Ab-Initio Molecular Orbital Calculations" Proc.of MRS-J. 189 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Mori et al.: "The Auger Electron Spectroscopy by using STM Probe" Proc.of 1996 JCBSAME. 131-135 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] "Investigation of Surface States on Si (001) anf Si (111) Surfaces -Photo-Reflectance Measurement and Ab-initio Calculation-" Proc.of MRS-J. 189 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 遠藤勝義 他: "STM/STSによるSi表面の金属原子の観察" 1997年度精密工学会春季大会学術講演会講演論文集. L05 (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] 平野均 他: "非経験的分子軌道法を用いた窒化物セラミックス薄膜形成における窒素分子と金属の反応解析" 精密工学会誌. 62(7). 1024-1028 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Endo et al.: "Observation of Metal Atoms Adsorbed on H-terminated Si (001) Surfaces by STM/STS" Proc.of 1996 JCBSAME. 141-146 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Mori et al.: "The Auger Electron Spectroscopy by using STM Probe" Proc.of 1996 JCBSAME. 131-135 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Endo et al.: "Observation of Metal Atoms Adsorbed on H-Terminated Si (001) Surfaces by STM/STS and its Consideration Based on Ab-Initio Molecular Orbital Calculations" Proc.of MRS-J. (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Inagaki et al.: "Investigation of Surface States on Si (001) and Si (111) Surfaces-Photo-Reflectance Measurement and Ab-initio Calculation-" Proc.of MRS-J. (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 遠藤勝義 他: "STM/STSによるSiウェーハ表面の観察" 1995年度精密工学会春季大会学術講演会講演論文集. 611-612 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 遠藤勝義 他: "STM/STSによるSiウェーハ表面の金属汚染物の極微量元素分析" 精密工学会1995年度関西地方定期学術講演会講演論文集. 89-90 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 遠藤勝義他: "STM(Scanning Tunneling Microscopy)によるSiウェーハ表面の観察-各種洗浄面の観察-" 精密工学会1994年度関西地方定期学術講演会講演論文集. 1-2 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 遠藤勝義他: "STM/STSによるSiウェーハ表面の観察" 1995年度精密工学会春季大会発表予定. (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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