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Basic Research on the Conversion of CO_2 to Methanol by using a Solar-Laser and Photocatalyst.

Research Project

Project/Area Number 06452429
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field エネルギー学一般・原子力学
Research InstitutionMIYAZAKI UNIVERSITY (1996)
Kyoto University (1994-1995)

Principal Investigator

WADA Kazuhiro  Miyazaki University ; Engineering ; Professor, 工学部, 教授 (50025996)

Co-Investigator(Kenkyū-buntansha) YAMANAKA Masanobu  Osaka Universitiy, Laser Enginering ; Assistant Professor, レーザー核融合研究センター, 助教授 (10029118)
YABUSHITA Shin  Kyoto University ; Engineering ; Professor, 大学院・工学研究科, 教授 (60025921)
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,300,000 (Direct Cost: ¥7,300,000)
Fiscal Year 1996: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1995: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1994: ¥4,100,000 (Direct Cost: ¥4,100,000)
KeywordsSolar laser / Solar cell / Laser diode / Up-conversion / CO_2 / conversion to methanol / Photoreduction / Photocatalyst / 二酸化炭素 / 触媒
Research Abstract

This research consists of three parts : developement of the solar laser, characterization of catalysts, and investigation of the fundamental process of CO_2 photoreduction. The result obtained is follows : (1) The generation of laser beam from a solar laser composed of a solar cell and a laser diod was demonstrated, (2) Days and nights continuous operation of solar laser by a circuit equiped with batteries was shown, (3) Near infrared light from a laser diode was converted to green light by up-conversion process with an Er doped silicate fiber, (4) Infrared absorption spectra and gas absorption properties were measured on such catalysts as Fe_2O_3, CuO and TiO_2 as well as some Zeorites, and (5) Observation of methanol generation from a sample of CO_2 and H_2O solidified on a MgF_2 substrate at 11 K by irradiating a UV light from a Xe Excimer lamp.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] 和田 一洋: "太陽電池と半導体レーザーによるソーラーレーザーの発振" レーザー研究. 23・3. 244-248 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 和田 一洋: "レーザー干渉法によるマトリクス試料の厚さと吸光係数測定" レーザー研究. 23・8. 667-675 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 綱脇 恵章: "TEA CO_2レーザー発振の単一モード化" レーザー研究. 23・8. 684-689 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Kiriyama: "High-Sensitivity Two-Dimensional Observation of Thermal Birefringence Compensation in Laser-Diode Pumped Nd:Glass Laser Rods" Optical Review. 3・1. 14-16 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 桐山 博光: "LD励起固体レーザー材料における2次元熱複屈折分布測定とその補償" レーザー研究. 24・3. 343-352 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 和田 一洋: "レーザーによる食物品質管理" レーザー研究. 26・1. 87-89 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 山中 正宣 (分担): "図解 光デバイス辞典" オプトロニクス社, 332 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] WADA,Kazuhiro: "A Solar Laser Consisting of a Solar Cell and a Laser Diode" The Review of Laser Engineering. Vol.23, No.3. 244-248 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] WADA,Kazuhiro: "Measurement of the Thickness and the Absorption Coefficient of Matrix samples by Laser Interferometry" The Review of Laser Engineering. Vol.23, No.8. 667-675 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Tsunawaki, Yoshiaki: "TEA CO_2 Laser Oscillation by Using a Fox-Smith Mode Selector with a Fabry-Perot Etalon" The Review of Laser Engineering. Vol.23, No.8. 684-689 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kiriyama, Hiromitsu: "High-Sensitivity Two-Dimensional Observation of Thermal Birefringence Compensation in Laser-Diode Pumped Nd : Glass Laser Rods" Optical Reniew. Vol.3, NO.1. 14-16

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Kiriyama, Hiromitsu: "Measurement of the Two-Dimensional Distribution of Thermal Birefringence in Laser-Diode Pumped Solid Laser Materials" The Review of Laser Engineering. Vol.24, No.3. 343-352 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] WADA,Kazuhiro: "Quality Control of Foods by Lasers" The review of Laser Engineering. Vol.26, No.1. 87-89 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Yamanaka, Masanobu: "Illustrated Dictionary of Optical Devices" OPTORONICS Co. 332 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 和田一洋: "太陽電池と半導体レーザーによるソーラーレーザーの発振" レーザー研究. 23・3. 244-248 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] 和田一洋: "レーザー干渉法によるマトリクス試料の厚さと吸光係数測定" レーザー研究. 23・8. 667-675 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] 綱脇恵章: "TEA CO_2レーザー発振の単一モード化" レーザー研究. 23・8. 684-689 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kiriyama: "High-Sensitivity Two-Dimensional Observation of Thermal Birefringence Compensution in Laser-Diode Pumped Nd : Glass Laser Rods" Optical Review. 3・1. 14-16 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 桐山博光: "熱複屈折補償型LD励起Nd:ガラスレーザーの開発研究" 信学技報. LQE96-4. 19-23 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 桐山博光: "LD励起固体レーザー材料における2次元熱複屈折分布測定とその補償" レーザー研究. 24・3. 343-352 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 山中正宣(分担): "図解 光デバイス辞典" オプトロニクス社, 332 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 和田一洋: "レーザー干渉法によるマトリクス試料の厚さと吸光係数測定" レーザー研究. 23. 667-675 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 和田一洋: "TEA CO_2レーザー発振の単一モード化" レーザー研究. 23. 684-689 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 和田一洋: "太陽電池と半導体レーザーによるソーラーレーザーの発振" レーザー研究. 23. 244-248 (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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