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Dynamics of the low-energy ion impact on the vander Warls thin films

Research Project

Project/Area Number 06453019
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionYamanashi University

Principal Investigator

HIRAOKA Kenzo  Yamanashi Univ.Fac.Eng.Professor, 工学部, 教授 (80107218)

Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 1996: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1995: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1994: ¥2,200,000 (Direct Cost: ¥2,200,000)
Keywordslow-energy ion impact / ion impact / vander Waals thin film / reflection TOFMS / 低エネルギーイオン衝撃 / イオン衝突 / リフレクトロン型TOF / 多体効果 / イオン-固体衝突 / イオン-分子反応 / 飛行時間型質量分析計
Research Abstract

The study on the interactions between the low-energy ions and solid surface is of fundamental importance in the field of plasma technology and ion-beam technology. In this study, the dynamics of the low-energy ion impact on the van der Waals thin films were studied in detail. The newly designed reflectron-type TOF mass spectrometer was installed in the ultra-high vacuum chamber. The pulsed ion beam was injected into the van der Waals thin film deposited on the cold head of the cryocooler at 7 K.
When the film was bombarded by the He^+ ions, the cluster ions were hardly observed. Instead, fragment ions are formed with strong intensities. This is due to the fact that the kinetic energy of the small-size He^+ ion is mainly dissipated by the electronic excitation in the ion-solid collision events. In contrast, much more efficient momentum transfer takes place in the collision of Ne^+ with the solid films. The efficient momentum transfer in the collision events leads to the shock wave formation in the ion track. This results in the abundant cluster ion formation.
In sum, the holes and excitons formed in the matrix play very important roles in the secondary ion formatin.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] 平岡賢三: "高速粒子による衝突活性化" J.Mass Spectrom.Soc.Jpn. 44. 577-624 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka,M.Nasu: "Bond energy oscillation in the cluster ion NO^+(NO)n" J.Chem. phys. 105. 9068-9071 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka,M.Nasu: "Gas-phase stahihity and structure of the clusxer ion CF_3^+(CO)n" J. Phys. Chem.100. 5245-5251 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka,A.Shimizu: "Gas,phase stahihity of clustir ions SFm^+(SF_6)n with m=0-5and n=1-3" Am Soc Mass Spectron. 6. 1137-1142 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka,S.Fukesawa: "Gas-phase positive and negativeion moleaule reactions in NF_3" J. phys. chem. 99. 15822-15829 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka,H.Fukasawa: "High flow liguid chromatography mass spectrometry interface" Rapid Commun.Mass Spetrom.9. 1349-1355 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka: "Collisional activation by fast atom fombardment" J.Mass Spectrom Soc.Jpn. 44. 577-624 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka, M.Nasu: "Bond energy asullition in the chorton ion NO^+ (NO) n" J.Chem.Phys.105. 9068-9071 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka, M.Nasu: "Gas-phase sfafility and structure of the cluster ion CF_3^+ (CO) n" J.Phys.Chem.100. 5245-5251 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka, A.Shimizu: "gas-phase sfafility of chuster ions SFm^+ (SF6) n with m=0-5 and n=1-3" Am.Soc.Mass Spectroml. 6. 1137-1142 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka, F.Fukasawa: "gas-phese positine and megafine ion moleaule reactions in NF_3" J.Phys.Chem.99. 15822-15829 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Hiraoka, H.Fukasawa: "High-flow bjoid chromatograply mass spectrometry in ferface" Ropid Commun Maes Speatron. 9. 1349-1355 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 平岡賢三: "高速粒子による衝突活性化" J.Mass Spectrom.Soc.Jpn. 44. 577-624 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Hiraoka,M.Nasu: "Bond energy oscillation in the cluster ion NO^+(NO)n" J.Chem.Phys.105. 9068-9071 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Hiraoka,M.Nasu: "Gas-phase stability and structure of the cluster ions CF_3^+(CO)n" J.Phys.Chem.100. 5245-5251 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Hiraoka,A.Shimizu: "Gas-phase stability of cluster ions SF_m^+(SF_6)n with m=0-5 and n=1-3" Am.Soc.Mass Spectrom. 6. 1137-1142 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Hiraoka,S.Fujimaki: "Gas-phase positive and negative ion mo/eale reactions in NF_3" J.Phys.Chem.99. 15822-15829 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] K.Hiraoka,H.Fukasawa: "High-flow liquid chromatography/maosspeotromety intaface" Rapid Commun.Mass Spectrom. 9. 1349-1355 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] K. Hiraoka: "Gas-phase positive and negative ion-nwlcaile reactions in NF3" J. Phys. Chem.99. 15822-15829 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Hiraoka: "High-flow liguid chrom stography/Mass spectrometry interface using a parallel ion spray" Rapid Communic. Mass Spectrom.9. 1349-1355 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Hiraoka: "Application of 10.6μm CO_2 laser to the electrospray and ion spray LC/MS interface" J. Mass Spectrom Soc. Japan. 43. 265-277 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Hiraoka: "Weak ion-molacule complexes of F^-(CF_4)n and CF_3^-(CF_4)n" Chem. Phys. Lett.245. 14-18 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Hiraoka: "The small finding energies of the negative cluster ions: SF_5^-(SF_6)_1 and F^-(SF_6)n(n=1and2)in the gas phase" Chem. Phys. Lett.241. 623-626 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K. Hiraoka: "Do the electrospray mass spectre reflact the ion concentrations in sample solution?" J. Mass Spectrom. Soc. Japan. 43. 127-138 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.HIRAOKA,A.YAMASHITA: "Ammonia fruaticn fron the reactions of H a foms with N afcns Habed in the solid Ne matrix at 10-30K" AsHophyiccl Journa. (in press). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.HIRAOKA,I,KUDAKA: "gas-phase saluation of O_2^+,O_4^+,andO_6^+ uich Ar" Journal of Mass Spectrimity Souity of Japan. (in press). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.HIRAOKA,K,AIZAWA: "Elecpscal Nduction and highlg-seusifnie Analysis M ioclinc in olictsspruy msss ssectromitug" Journal of Mass Spectrimity Souity of Japan. (in press). (1995)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y,IIJIMA,K,HIRAOKA: "Low-energy Ar rcuhal lcam etchmig methad for X-ray Phslcsbcthon Spectroscopy" Gusfau and ln Lufau Analpis. 21. 778-784 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Y,IIJIMA,K,HIRAOKA: "Analysis of polyethyleneterephthalgte,film surfacc sputterd with Ar neutral and Ar beams" Japanese J.Appl.Phy.33. 6325-6330 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.HIRAOKA,S,YAMABE: "Frofion-conHolKd structcue of the gas-phracA^±(CS_2)n cluales,A^±=S_2^±,CC_2^±" Journal of Dhysical Chemistry. 98. 1802-1809 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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