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Synthetic research on a model compound of organic high-tenperature superconductors

Research Project

Project/Area Number 06453039
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionHIROSHIMA UNIVERSITY

Principal Investigator

OTSUBO Tetsuo  Hiroshima Univ., Fac.of Rng., Prof., 工学部, 教授 (80029884)

Co-Investigator(Kenkyū-buntansha) TAKIMIYA Kazuo  Hiroshima Univ., Fac.of Eng., Assist., 工学部, 助手 (40263735)
ASO Yoshio  Hiroshima Univ., Fac.of Eng., Assoc.Prof., 工学部, 助教授 (60151065)
小倉 文夫  広島大学, 工学部, 教授 (90028150)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥6,100,000 (Direct Cost: ¥6,100,000)
Fiscal Year 1995: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1994: ¥4,400,000 (Direct Cost: ¥4,400,000)
Keywordsorganic conduction / organic suporconductor / molecular complex / X-ray structural analysis / 超伝導
Research Abstract

Double-layred tetrathiafulvalenophanes consisting dimeric TTF units might be regarded as suitable model compounds for k-type of TTF complexes showing high-temperature superconductivities. In addition, they are interesting as potential electron donors, which have some advantages in the formation of charge-transfer complexes, e, g., possibilities of controlled stoichiometry and assembly. Many overlapped types of the two TTF units may be considered in the designs of such layred TTF phanes. In this regard, we have studied novel several tetrathiafulvalenophanes with different stacking modes, which include four double-bridged types (cis-cis) , (cis-trans) , (trans-trans, parallel) , and (trans-trans, twist) and two quadruple-bridged types (parallel) and (crisscross). They behaved as good electron donors forming conductive molecular complexes, some of which corresponded to organic metals

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (19 results)

All Other

All Publications (19 results)

  • [Publications] Kazuo Takimiya: "Crisscross-Overlapped Tetrathiafulvalenophanes" Tetrahedron Letters. 36. 5045-5048 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Kazuo Takimiya: "Double-Bridged Tetrathiafulvelenophanes as Novel Electron Donors : Syntheses, Structures, and Properties of Three Structural Isomers" Chemistry Letters. 735-736 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Koji Matsuno: "Double-Layered Tetrathiafulvalene as a Novel Electron Donor" Chemistry Letters. 523-524 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Atsusi Bitoh: "Syntheses and Properties of 2, 5-Bis[2-(tetrathiafulvalen-2-yl)ethenyl thiophene and Related Compounds as Novel Dumbbell-type Electron Donors" Synthetic Metals. 70. 1123-1124 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Tetsuo Otsubo: "Dimeric Tetrathiafulvalenes and-Related Compounds as a New Class of Electron Donors" Advanced materials. (in press). (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Takimiya: "Crisscross-Overlapped Tetrathiafulvalenes" Tetrahedron Lett.36(28). 5045-5048 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Takimiya: "Double-Bridged Tetrathiafulvalenophanes as Novel Electron Donors : Syntheses, Structures, and Properties of Threee Structural Isomers" Chem.Lett.(8). 735-736 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] K.Matsuo: "Double-Layred Tetrathiafulvalene as Novel a Electron Donor" Chem.Lett.(7). 523-524 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] A.Bitoh: "Syntheses and Properties of 2,5-Bis [2- (tetrathiafulvalen-2-yl) -ethenyl] thiophene and Related Compounds as Novel Dumbbell-Type Electron Donors" synthetic Metals. 70(1-3). 1123-1124 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] T.Otsubo: "Dimeric Tetrathiafulvalenes and Related Compounds as a New Class of Electron Donors" Adv.Mater.(3) (in press). (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Kazuo Takimiya: "Crisscross-Overlapped Tetrathiafulvalenophanes" Tetrahedron Letters. 36. 5045-5048 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Kazuo Takimiya: "Double-Bridged Tetrathiafulvelenophanes as Novel Electron Donors:Syntheses, Structures, and Properties of Three Structural Isomers" Chemistry Letters. 735-736 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Koji Matsuo: "Double-Layered Tetrathiafulvalene as a Novel Electron Donor" Chemistry Letters. 523-524 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Atsushi Bitoh: "Syntheses and Properties of 2,5-Bis[2-(tetrathiafulvalen-2-yl)ethenyl]thiophene and Related Compounds as Novel Dumbbell-type Electron Donors" Synthetic Metals. 70. 1123-1124 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Tetsuo Otsubo: "Dimeric Tetrathiafulvalenes and Related Compounds as a New Class of Electron Donors" Advanced materials. (in press). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] Kazuo Takimiya: "Naphtho〔1,8-bc:5,4-b′c′〕dithiophene:A new heteroarene" Journal of Chemical Society,Chemical Communications. 1859-1860 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Shu Yoshida: "Novel electron acceptors bearing a heteroquinonoid system.4.Syntheses,Properties,and Charge-Transfer Complexes" Journal of Organic Chemistry. 59. 3077-3081 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Tetsuo Otsubo: "Syntheses and properties of novel dimeric tetrathiafulvalenes linked with an ethenylene or ethynylene spacer" Chemistry Letters. 2047-2050 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] Kazuo Takimiya: "Highly conductive 1:1 radical cation salts of anthra[1,9-cd:4,10-c′d′]bis[1,2]dichalcogenoles" Bulletin of Chemical Society of Japan. 67. 766-772 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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