| Project/Area Number |
06453117
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
工業物理化学
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| Research Institution | Nagasaki University |
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Principal Investigator |
KAGAWA Shuichi Faculty of Engineering, Professor, 工学部, 教授 (80037746)
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| Co-Investigator(Kenkyū-buntansha) |
MORIGUCHI Isamu Faculty of Engineering, Resaerch Associate, 工学部, 助手 (40210158)
TERAOKA Yasutake Faculty of Engineering, Associate Professor, 工学部, 助教授 (70163904)
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| Project Period (FY) |
1994 – 1996
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| Project Status |
Completed (Fiscal Year 1996)
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| Budget Amount *help |
¥7,300,000 (Direct Cost: ¥7,300,000)
Fiscal Year 1996: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1995: ¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 1994: ¥4,100,000 (Direct Cost: ¥4,100,000)
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| Keywords | Molecular film / Organic-inorganic nano-composite film / Nano level / Metal sulfide / Bimetallic sulfide / Metal selenide / Gold particulate / Third-order optical nonlinearity / Langmuir-Blodgett膜 / 二分子膜 / 量子サイズ / 有機-無機ナノ複合薄膜 / 無機ナノ物質 / 縮退4波混合 / 無機-有機ナノ複合薄膜 / 第三高調波発生 |
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| Research Abstract |
Exposure of metal ion-containing organized molecular assembly (OMA) films to H_2S gas resulted in the formation of size-quantized metal sulfides such as ZnS,CdS,PbS and Cu_2S in OMA films. When the metal sulfide-bearing composite films were subjected repeatedly to a set of immersion in aqueous solutions of the corresponding metal ions (I) and the exposure to H_2S gas (S), the growth of metal sulfides within a nano-order level was observed. The size of CdS formed in OMA films could be also controlled precisely by the occupied molecular area of OMA-constructing amphiphiles and the repetition number of the I-S cycle. Futhermore, synthesis of bimetallic sulfides in OMA films was also investigated. Mixed metal sulfides (M_zN_<1-z>S) were obtained by the sulfidation of salt-form Langmuir-Blodgett films containing both M and N ions, while Core (MS)-shell (NS) type binary metal sulfides ([MS]_x[NS]_y)were obtained by conbining I-S cycles for MS formation and those for NS formation in series. It was also found that the repeated cycle of intercalation of precursor ions and transformation of the precursor into inorganic compounds was applicable to synthesis of various organic-inorganic nano-composite systems, such as metal selenide- and Au particulate-bearing composite systems.
Nonlinear optical properties of the metal sulfide-bearing composite system was evaluated by third harmonic generation and degenerate four-wave mixing techniques. The third-order optical nonlinearity of PbS-bearing composite system was comparable to or even larger than hitherto reported systems and was optimized by the regulation of the amount and size of PbS.
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