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Surface Modification of Coal With Carbon Dioxide and Its Application to Advanced Coal Cleaning

Research Project

Project/Area Number 06453157
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 資源開発工学
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

TSUNEKAWA Masami  Hokkaido Univ., Fac.of Eng., Professor, 工学部, 教授 (40002026)

Co-Investigator(Kenkyū-buntansha) HIROYOSHI Naoki  Hokkaido Univ., Fac.of Eng., Instructor, 工学部, 助手 (50250486)
HIRAJIMA Tsuyoshi  Hokkaido Univ., Fac.of Eng., Associate Professor, 工学部, 助教授 (00175556)
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥7,400,000 (Direct Cost: ¥7,400,000)
Fiscal Year 1996: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1995: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1994: ¥5,700,000 (Direct Cost: ¥5,700,000)
KeywordsCoal / Carbon Dioxide / Surface Modification / Flotation / De-ashing / Wettability / Fine Grinding / 方解石 / ドロマイト / 分離効率 / 鉱物質 / 単体分離 / 粉砕
Research Abstract

Four coals from different localities (Datong, Wandoan, Illinois and Shenmu) were used in this study. Immersion time measurements were carried out to assess wettability of coal surface using 100-200 mesh coals. Flotation tests were conducted by introducing air, nitrogen and carbon dioxide gases, respectively. After sparging the gases into coal slurries, the slurries were chemically analyzed. For flotation and chemical analysis fine coals (mean particle size : about 30mum) were used. Some of the coals were treated with 0.6kgf/cm^2 of carbon dioxide gas prior to the experiments. The collectors used were kerosene for Datong and Shenmu coal, and heavy oil A for the other coals.
The hydrophobicity of four coals treated with carbon dioxide became slightly higher than that of untreated coal. When sparging carbon dioxide gas, the highest amounts of calcium and magnesium were dissolved from Datong and Wandoan coals and the amounts of bassanite and calcite in the coals were simultaneously decreased. By flotation with carbon dioxide, the maximum yield was obtained for the coals treated with carbon dioxide than the untreated coals. In the case of Shenmu coal containing calcite and dolomite, separation efficiency of combustibles from mineral matters became higher with decreasing pH.
Fine grinding of four coals were investigated. The ground product with a mean size of 2mum was obtained at a suitable operating conditions for all coals. The wear loss of the grinding media and vessel depended strongly on the amount of the hard minerals disseminated in coal, such as quartz, pyrite and iron oxide.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] 恒川昌美: "石炭の浮遊性と脱灰性に及ぼす二酸化炭素の影響-大同炭、ワンドワン炭、イリノイ炭の場合" 資源処理技術. 41. 18-27 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 恒川昌美: "石炭浮選における二酸化炭素の利用" 資源・素材'94. N-4. 13-16 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Masami TSUNEKAWA,Shin-ichi SEO and Tsuyoshi HIRAJIMA: "Influence of Carbon Dioxide on Flotation and Deashing Characteristics of Coal --On Datong, Wandoan and Illinois Coals--" Resources Processing. Vol.41. 18-27 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Masami TSUNEKAWA and Tsuyoshi HIRAJIMA: "Use of Carbon Dioxide in Coal Flotation" Shigen-Sozai'94. N-4. 13-16 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 恒川昌美: "石炭の浮遊性と脱灰性に及ぼす二酸化炭素の影響" 資源処理技術. 41. 18-27 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 恒川昌美: "石炭浮選における二酸化炭素の利用" 資源・素材関係学協会合同秋季大会分科研究会資料. N. 13-16 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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