| Project/Area Number |
06453188
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | University of Tokyo |
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Principal Investigator |
SHIBASAKI Masakatsu University of Tokyo, Fac.of Pharm., Professor, 薬学部, 教授 (30112767)
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| Co-Investigator(Kenkyū-buntansha) |
SASAI Hiroaki University of Tokyo, Fac.of Pharm., Associate Professor, 薬学部, 助教授 (90205831)
中田 雅久 東京大学, 薬学部, 助手 (50198131)
袖岡 幹子 東京大学, 薬学部, 助手 (60192142)
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| Project Period (FY) |
1994 – 1995
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| Project Status |
Completed (Fiscal Year 1995)
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| Budget Amount *help |
¥7,300,000 (Direct Cost: ¥7,300,000)
Fiscal Year 1995: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1994: ¥3,800,000 (Direct Cost: ¥3,800,000)
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| Keywords | Asymmetrtic Catalyst / Heck Reaction / Palladium / 触媒的不斉合成 / 海洋天然物 / 鎮痛剤 |
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| Research Abstract |
We have developed a catalytic asymmetric construction of benzylic quarternary carbons. The strategy utilizes an asymmetric Heck reaction. By using this method, we have achieved catalytic asymmetric syntheses of bioactive molecules such as eptazocine, capnellene and halenaquinol.
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