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Transfer Phenomena of Tritium on Ceramic Breeder Materials

Research Project

Project/Area Number 06453203
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear fusion studies
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

NISHIKAWA Masabumi  Kyushu University Dept.of Nucl.Eng., Professor, 工学部, 教授 (90026229)

Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥6,100,000 (Direct Cost: ¥6,100,000)
Fiscal Year 1996: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1995: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1994: ¥4,500,000 (Direct Cost: ¥4,500,000)
Keywordsceramic breeder / water adsorption / surface reaction / tritium inventory / water formation reaction / 粒子内拡散
Research Abstract

Present author has quantified the amount of water captured in various lithium ceramic breeder materials and compared the tritium inventory at the blanket due to sorption with that due to diffusion in the crystal grain. Tritium inventory at the blaket due to sorption is much larger than that due to diffusion in the crystal grain unless otherwise a large amount of swamping of H_2 or H_2O to the purge gas is applied in the high temperature blanket. Therefore, it can be considered that the diffusivity of tritium in the crystal grain obtained from the tritiated water release experiments gives the value including the mass transfer resistance at surface.
It is also found by the present work that formation of water in the lithium oxide bed occurs in the course of the isotope exchange reaction experiments using He sweep gas with hydrogen isotopes.
It is anticipated that behavior of tritium in the breeding blanket cycle is largely affected by existence of water. Accordingly, it is important to understand the water formation phenomenon occurs at addition of hydrogen to the blanket purge gas.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] Y.Kawamura: "Adsorption and desorption rate of water on the various ceramic breeder materials" Fusion Technology. 27. 25-35 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kawamura: "Formation of water in lithium ceramics bed at hydrogen addition to purge gas" Journal of Nuclear Materials. 230. 287-294 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kawamura and M.Nishikawa: "Adsorption and desorption rate of water on the various ceramic breeder materials" Fusion Technology. vol.27. 25-35 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kawamura, M.Nishikawa, T.Shiraishi and K.Okuno: "Formation of water in lithium ceramics bed at hydrogen addition to purge gas" Journal of Nuclear Materials. vol.230. 287-294 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] Y.Kawamura: "Formation of water in lithium ceramics bed at hydrogen addition to purge gas" Journal of Nuclear Materials. 230. 287-294 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Kawamura: "Adsorption Characteristics of water vapor on Li_2ZrO_3" J. Nucl. Mater. 218. 57-65 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kawamura: "Adsorption and Desorption Rate of Water on the Various Ceramic Breeder Materials" Fusion Technology. 27. 25-34 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M. Nishikawa: "Tritium inventory in ceramic breeder materials" Proc. 4th Int. Workshop on C. B. B. I. 15-23 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] Y.Kawamura: "Adsorption and Desorption Rate of Water on the Various Ceramic Breeder Materials" Fusion Technology. 27. 25-34 (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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