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Development of a Non-Catalytic System for Reducing Nitric Oxide in Diesel Exhaust Using Methylamine as the reductant

Research Project

Project/Area Number 06555063
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionRITSUMEIKAN UNIVERSITY

Principal Investigator

YOSHIHARA Yoshinobu  Ritsumeikan University, Faculty of Engineering and Science, Professor, 理工学部, 教授 (30174999)

Co-Investigator(Kenkyū-buntansha) KITO Shigehiro  TAKUMA Co., Ltd., R & D Department, Manager, 第2研究室, 室長
ADACHI Masahiro  HORIBA Ltd., Engine Measurement R & D,Supervisor, 自動車計測部, 主任
NISHIWAKI Kazuie  Ritsumeikan University, Faculty of Engineering and Science, Professor, 理工学部, 教授 (20025969)
Project Period (FY) 1994 – 1995
Project Status Completed (Fiscal Year 1995)
Budget Amount *help
¥5,900,000 (Direct Cost: ¥5,900,000)
Fiscal Year 1995: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1994: ¥4,600,000 (Direct Cost: ¥4,600,000)
KeywordsSNCR / Nitric Oxide / Diesel Engine / Exhaust Gas Treatment / Methylamine
Research Abstract

Selective non-catalytic system for reducing nitric oxide in diesel engine exhaust using methylamine (CH_3NH_2) as the reductant has been developed. The results obtained at the experiments for a part of diesel exhaust using a electrically heated quartz flow reactor show that more than 80% NO reduction ratio is achieved in the reactor temperature range of 673 K to 800 K with a molar ratio [CH_3NH_2] / [NO] of 1.0. Experiments targetting whole diesel exhaust has also been carried out. In those experiments, high speed, single cylinder, water cooled, naturally aspirated, four cycle, DI diesel engine having 876 cc of stroke volume was used as a test engine and 40% water solved methylamine was injected at a exhaust manifold using an electrically controlled gasoline injector. The results show that about 70% of NO reduction ratio is achieved at the molar ratio of 3.0 without the leak of ammonia and methylamine. It is further shown that more than 80% NO reduction ratio at the molar ratio of 1.0 can be attained bythe complete mixing of methylamine and exhaust.

Report

(3 results)
  • 1995 Annual Research Report   Final Research Report Summary
  • 1994 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] 吉原・西脇・舩木: "メチルアミンによるディーゼル排ガスの無触媒脱硝" 日本機械学会講演論文集. 940-30. 374-376 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 吉原・田中: "メチルアミン添加によるディーゼル排気中の窒素酸化物の分解" 日本機械学会論文集. 61-582. 408-413 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 吉原・西脇・中西: "ディーゼル排気NOの無触媒分解" 日本機械学会全国大会講演論文集. 95-10. 212-213 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 吉原・西脇・中西: "ディーゼル排気NOの無触媒分解(続報:NO低減率の改善)" 日本機械学会関西支部定期講演会講演論文集. 964-1. 134-135 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Yoshihara, K.Nishiwaki and K.Funaki: "Non-Catalytic Reduction of Nitrogen Oxide in a Diesel Exhaust by Using Methylamine" Proceedings of The 72th JSME Fall Annual Meeting. 940-30. 374-376 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Yoshihara and T.Tanaka: "Reduction of Oxides of Nitrogen in Diesel Exhaust with Addition of Methylamine" Transactions of JSME,Series B. 61-582. 408-413 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Yoshihara, K.Nishiwaki and Y.Nakanishi: "Non-Catalytic Reduction in Nitrogen Oxide in a Diesel Exhaust" Proceedings of The 73th JSME Fall Annual Meeting. 95-10. 212-213 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] Y.Yoshihara, K.Nishiwaki and Y.Nakanishi: "Non-Catalytic Reduction in Nitrogen Oxide in a Diesel Exhaust : Improvement in NO Reduction Ratio" Proceedings of The 71th JSME Kansai Branch Annual Meeting. 964-1. 134-135 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1995 Final Research Report Summary
  • [Publications] 吉原・西脇・船木: "メチルアミンによるディーゼル排ガスの無触媒脱硝" 日本機械学会講演論文集. 940-30. 374-376 (1994)

    • Related Report
      1995 Annual Research Report
  • [Publications] 吉原・田中: "メチルアミン添加によるディーゼル排気中の窒素酸化物の分解" 日本機械学会論文集. 61-582. 408-413 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 吉原・西脇・中西: "ディーゼル排気NOの無触媒分解" 日本機械学会全国大会講演論文集. 95-10. 212-213 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] 吉原・西脇・中西: "ディーゼル排気NOの無触媒分解(続報:NO低減率の改善)" 日本機械学会関西支部定期講演会講演論文集. (発表予定). (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] 吉原・西脇・舩木: "メチルアミンによるディーゼル排ガスの無触媒脱硝" 日本機械学会講演論文集. 940-30. 374-376 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 吉原・田中: "メチルアミン添加によるディーゼル排気中の窒素酸化物の分解" 日本機械学会論文集. 61-582. 408-413 (1995)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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