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Development of Ceramic/Metal Mutual Nanocomposites with Superior Strength and Toughness

Research Project

Project/Area Number 06555195
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section試験
Research Field Composite materials/Physical properties
Research InstitutionOsaka University

Principal Investigator

NIIHARA Koichi  Prof., Osaka University, 産業科学研究所, 教授 (40005939)

Co-Investigator(Kenkyū-buntansha) NAWA Masahiro  Chief Res., Matsushita Electric Works, Co., 中央研究所, 主査(研究職)
CHOA Yong-Ho  Res.Assoc., Osaka University, 産業科学研究所, 助手 (10283805)
SEKINO Tohru  Res.Assoc., Osaka University, 産業科学研究所, 助手 (20226658)
NAKAHIRA Atsushi  Assoc.Prof., Kyoto Institute of Technology, 工芸学部, 助教授 (90172387)
UEDA Satoru  Lecturer, Osaka University, 産業科学研究所, 講師 (20029870)
大島 健司  ノリタケカンパニー(株)開発本部, 副主事
Project Period (FY) 1994 – 1996
Project Status Completed (Fiscal Year 1996)
Budget Amount *help
¥13,700,000 (Direct Cost: ¥13,700,000)
Fiscal Year 1996: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1995: ¥4,300,000 (Direct Cost: ¥4,300,000)
Fiscal Year 1994: ¥8,000,000 (Direct Cost: ¥8,000,000)
KeywordsNanocomposites / Nano-dispersions / Functional properties / Fracture toughness / Fracture strength / multual nanocomposites / Interface structure / Ceramic based composites / 破壊靱性 / セラミックス / ナノ複合材料 / 機械的性質 / 磁気的性質 / セラミックス複合材料
Research Abstract

Nanocomposites technology is well known to improve 2 to 4 times the fracture strength of ceramic materials even at high temperatures. The high-temperature creep rate is also improved 3 to 4 orders by this technology. The purpose of this project are to clarify the mechanisms of mechanical property improvements and to develop various kinds of multi-functional ceramic materials (Intermaterials) by applying this nanocomposite technology. The final target of this project is to propose the nano/cluster composite concept with better mechanical properties, based on the nanocomposite technology.
The main results obtained from this project is as follows : 1) In the ceramic/eramic and ceramic/metal nanocomposites, new processing to homogeneously disperse the nano-sized second phases were developed, and the mechanisms of mechanical property improvements by the nano-sized second phase dispersions were clarified. 2) Based on the above-mentioned informations, new ceramic materials, in which the fracture strength and toughness were simultaneously improved, were developed by the micro/nano hybrid concept in the ceramic/ceramic composite systems, and by the mutual nanocomposite concept in the ceramic/metal composite systems especially Zirconia/Mo nanocomposite system. 3) Furthermore, new material design to improve the mechanical properties of ceramic materials by the soft and week second phase dispersions was proposed. By applying this concept, significantly improved strength, toughness, thermal shock fracture resistance and chemical inertness were harmonized with the machinability like metals in the Si3N4/BN nanocomposite. In the BaTi03/Ni nanocomposite system, the high strength with the improved ferroelectricity was obtained. For example, the fracture strength was improved 2 to 3 times by dispersing the nano-sized Ni particulates, and the same level improvement was also observed for the dielectric constant.

Report

(4 results)
  • 1996 Annual Research Report   Final Research Report Summary
  • 1995 Annual Research Report
  • 1994 Annual Research Report
  • Research Products

    (41 results)

All Other

All Publications (41 results)

  • [Publications] K.Niihara: "In-situ Fabricatin of Tungsten Nanocrystal Encapsulated Carbon Ball in TEM" Materials Letters. .27. 121-124 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Nawa: "A New Type of Nanocomposite in Tetragonal Zirconia Polycrystal-Molybdenium System" Materials Letters. 20. 299-304 (1994)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 新原 晧一: "高次機能調和材料の開発-セラミックス系ナノコンポジットを中心にして-" エネルギー・資源. 18・31. 251-259 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Sekino: "Microstructural Characteristics and Mechanical Properties for A1203/Metal Nanocomposites" NanoStructured Materials. 6. 663-666 (1995)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Ohji: "Particle/matrix interface and its role in creep inhibition in alumina/silicon carbide nanocomposites" J.Am.Ceram.Soc.79. 33-45 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Sekino: "Mechanical and Magnetic Properties of Nickel Dispersed Alumina-Based Nanocomposite" Materials Letters. 29. 165-165 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] 新原 晧一: "Proceedings of NEPTIS-IV Nano-Sezed Powder and Related Composite Materails" NEPTIS-4委員会及び日精エンジニアリング, 83 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.HIRANO,A.NAKAHIRA,T.SEKINO and K.NIIHARA: "High Temperature Creep Behavior of Al203/SiC and Si3N4/SiC Nanocomposites." J.High Temp.Soc.21. 97-103 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.Kitayama, M.Inoue and K.Niihara: "Effects of absorbed species on microstructure and mechanical properties of Al203" Ceramic Transactions. 44. 435-444 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Sekino, A.Nakahira, K.Niihara: "Relationship between Microstructure and High-Temperature Mechanical Properties for Al203/W Nanocomposites" Advanced Materials '93, III. Vol.B. 1513-1516 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.NIIHARA,T.HIRANO,K.Izaki and F.WAKAI: "High Temperature Creep/Deformation of Si3N4/SiC Nanocomposites" Ceramic transactions. 42. 207-219 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Sekino and K.Niihara: "Microstructural Characteristics and Mechanical Properties for Al203/Metal Nanocomposites" Nanostruct.Mater.Vol.6, No.5-8. 663-6 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] X.pan, J.Mayr, M.Ruhle, K.Niihara: "Silicon nitride based ceramic nanocomposites" J.Am.Ceram.Soc.Vol.79, no.3. 585-90 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] H.J.Hwang, T.Sekino, K.Ota and K.Niihara: "Perovskite-type BaTi03 ceramics containing particulate SiC.Part I : Structure variation and phase transformation" J.Mater.Sci.vol.31, no.17. 4617-24 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Sekino, T.NAKAJIMA and K.NIIHARA: "Mechanical and Magnetic Properties of Nickel Dispersed Alumina-Based Nanocomposite" Materials Letters. Vol.29, Nos.1-3. 165-169 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Nawa, K.Yamazaki, T.Sekino, K.Niihara: "Microstructure and Mecancial Behavior of 3Y-TZP/Mo Nanocomposite Possessing a Novel Interpenetrated Intragranular Nicrostructure" J.Mat.Sci.Vol.31, No.11. 2849-2858 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] T.Ohji, T.Hirano, A.Nakahira, K.Niihara: "Particle/matrix interface and its role in creep inhibition in alumina/silicon carbide nanocomposites" J.Am.Ceram.Soc.vol.79, no.1. 33-45 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Niihara, T.sekino, A.Nakahira, T.Kamino, T.Yaguchi: "In-situ Fabrication of Tungsten Nanocrystal Encapsulated Carbon Ball in TEM" Materials Letters. Vol.27, No.3. 121-124 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] M.Nawa, S.Nakamoto, K.Yamazaki, T.Sekino, K.Niihara: "abrication and Mechcnical Properties of Ce02 Stabilized Tetragonal Zirconia Based Nanocomposites Incorporating Al203 Dispersions" J.of Japan Soc.of Powd.and Powder Metall.vol.43 [4]. 415-420 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Niihara, A.Nakahira, T.Sekino and Y.-H.Choa: "Development of Ceramic Based Nanocomposites with High Performance" J.of Japan Soc.of Powd.and Powd.Metall.44 [10]. 887-896 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1996 Final Research Report Summary
  • [Publications] K.Niihara: "In-situ Fabrication of Tungsten Nanocrystal Encapsulated Carbon Ball in TEM" Materials Letters. 27. 121-124 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Nawa: "A New Type of Nanocomposite in TGetragonal Zirconia Polycrystal-Molybdenium System" Materials Letters. 20. 299-304 (1994)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Nawa: "Microstructure and Mechanical Properties of Y203 Stabilized Tetragonal Zieconia based Nanocomposites Incorporating Metal Dispersions" Journal.of Jp.Powder and Powder Metallurgy. 41. 1220-1225 (1994)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Sekino: "Microstructural Characteristics and Mechanical Properties for Al203/Metal Nanocomposites" Nano Structured Materials. 6. 663-666 (1995)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Ohji: "Particle/matrix interface and its role in creep inhibition in alumina/silicon carbide nanocomposites" J.Am.Ceram.Soc.79. 33-45 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Sekino: "Mechanical and Magnetic Properties of Nickel Dispersed Alumina-Based Nanocomposite" Materials Letters. 29. 165-169 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 新原 晧一: "Proceedings of NEPTIS-IV Nano-Sized Powder and Related Composite Materails" NEPTIS-4委員会及び日精エンジニアリング, 83 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 新原 晧一: "エネルギー分野における新材料" 資源、エネルギー学会(印刷中),

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Sekino: "Interface Structure of Alunina/Hetal Nanoconposites" 13-oc.of 4th Japan International Sampe Symposium. 269-274 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Niihara: "Nanoccmposite Structural Ceramics with Advnced Properties" Prcc.ct 4th Japan InternationalSampe Symposium. 394-399 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.W.Chae: "Improvemeut in the meckanical prcperties of T.C by the dispersion offine Sic partides" Journal of Materials Science Letters. 14. 1332-1334 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.W.Chae: "Sintering of Al_2O_3 -T.C composite in the presence of liquid phrase" Jcunal of Ameriean Ceramic Society. 78. 257-259 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Hirano: "Microstructure and mechanicel preperties of S_<13>N_4-S_1C composites" Materials Letters. 22. 249-254 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] T.Ohji: "Porticle/matrix interface and its rotes in alumina/silrcon carbide nanocemposites" Jcunae of Ameriean Ceramic society. 79. 33-45 (1996)

    • Related Report
      1995 Annual Research Report
  • [Publications] K.Niihara: "Proc of 4th Nisshin Engineeringparticle Technolcgy Internatioral Seminar" Nisshin Engineering Co.Ltd.,andNEPTIS-IV Committee, 88 (1995)

    • Related Report
      1995 Annual Research Report
  • [Publications] M.Nawa 他3名: "A new type of nanocomrposite intetragonal zirconia-maybleram syste" Mater.Lett.20. 299-304 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] H.J.Hwang 他2名: "Investigation of structural variation in perovskite-type BaTiO_3-based ceramics byelasticpropety measurements" Mater.Lett.21. 179-183 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] 中平敦 他1名: "セラミックス分散Ti-Al基複合材料の製造と微細組織" 粉体および粉末治金. 41. 1367-1372 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Koyama 他2名: "Effecti of grain morphology and grain size on the mechanical properties of Al_2O_3 ceramics" J.Mater.Sci.29. 3946-3954 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] K.Niihara他2名: "Hightemperature creep/deformation of Si_3N_4/SiC nanocomposites" Ceramic Transaction.42. 207-219 (1994)

    • Related Report
      1994 Annual Research Report
  • [Publications] T.Ohji 他3名: "Tensile creep behavior of alumina/silicon carbide nanocomposite" J.Amer.Ceram.Soc,. 77. 3259-3262 (1994)

    • Related Report
      1994 Annual Research Report

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Published: 1994-04-01   Modified: 2016-04-21  

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